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Oscillatory diffuse X-ray scattering from lead chalcogenides

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Abstract

Diffuse X-ray scattering from lead chalcogenides (PbS, PbSe, and PbTe) was measured at 15 and 294 K. The increase of the diffuse scattering intensities with the temperature was explained by the thermal correlation effects among thermal displacements of second nearest neighboring Pb–Pb atoms. The contribution from the second nearest neighboring atoms to the diffuse scattering was clearly confirmed.

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References

  1. Sakuma T, Basar K, Shimoyama T, Hosaka D, Xianglian, Arai M. Static and dynamic structure in solid state ionics. In: Sakuma T, Takahashi H, editors. Physics of solid state ionics. India: Research Signpost Pub; 2006. p. 323–46.

    Google Scholar 

  2. Arai M, Sakuma T, Atake T, Kawaji H. Phase transition of CuITe. J Therm Anal Calorim. 2002;69:905–8.

    Article  CAS  Google Scholar 

  3. Basar K, Shimoyama T, Hosaka D, Xianglian, Sakuma T, Arai M. Diffuse scattering of superionic phase of CuAgSe. J Therm Anal Calorim. 2005;81:507–10.

    Article  CAS  Google Scholar 

  4. Thazin A, Arai M, Sakuma T, Ishi Y. Oscillatory diffuse neutron scattering from β-AgI. In: Chowdari BVR, editor. Solid state ionics. Singapore: World Scientific Pub; 2002. p. 777–84.

    Google Scholar 

  5. Sakuma T, Nakamura Y, Hirota M, Murakami A, Ishii Y. Diffuse neutron scattering from AgBr: application to Rietveld refinements. Solid State Ion. 2000;127:295–300.

    Article  CAS  Google Scholar 

  6. Sakuma T, Shimoyama T, Basar K, Xianglian, Takahashi H, Arai M, et al. Correlation effects between thermal displacements of atoms in copper halides. Solid State Ion. 2005;176:2689–93.

    CAS  Google Scholar 

  7. Nakamura K, Ihata K, Yokoyama Y, Nomura K, Kobayashi M. Particle correlation in superionic conductors. Ionics. 2001;7:178–81.

    Article  CAS  Google Scholar 

  8. Noda Y, Matsumoto K, Ohba S, Saito Y, Toriumi K, Iwata Y, et al. Temperature dependence of atomic thermal parameters of lead chalcogenides, PbS, PbSe and PbTe. Acta Cryst. 1987;43:1443–5.

    Article  Google Scholar 

  9. Chandra A, Singh PK, Chandra S. Semiconductor-dispersed polymer electrolyte composites. Solid State Ion. 2002;154–155:15–20.

    Article  Google Scholar 

  10. Wei SH, Zunger A. Electronic and structural anomalies in lead chalcogenides. Phys Rev B. 1997;55:13605–10.

    Article  CAS  Google Scholar 

  11. Shalvoy RB, Fisher GB, Stiles PJ. Bond ionicity and structural stability of some average-valence-five materials studied by X-ray photoemission. Phys Rev B. 1977;15:1680–97.

    Article  CAS  Google Scholar 

  12. Sajadi SAA, Alamolhoda AA, Hashemian SJ. Study of thermal behavior of α-PbO2, using TG and DSC. J Therm Anal Calorim. 2008;92:917–20.

    Article  Google Scholar 

  13. Izumi F, Ikeda T. A rietveld-analysis programm RIETAN-98 and its applications to zeolites. Mater Sci Forum 2000;198:321–324.

    Google Scholar 

  14. Sakuma T. Diffuse scattering of α-AgI. J Phys Soc Jpn. 1992;61:4041–8.

    Article  CAS  Google Scholar 

  15. Beni G, Platzman PM. Temperature and polarization dependence of extended X-ray absorption fine-structure spectra. Phys Rev B. 1976;14:1514–8.

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors wish to express their thanks to Collaborative Project among Ibaraki University, Hitachi Ltd., and Ibaraki Prefecture for financial support. This research was partially supported by the Ministry of Education, Science, Sports and Culture, Grant-in-Aid for Scientific Research (C), 21540314, 2009.

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Authors and Affiliations

  1. Institute of Applied Beam Science, Ibaraki University, Mito, 310-8512, Japan

    Xianglian & T. Sakuma

  2. College of Physics and Electronics Information, Inner Mongolia University for the Nationalities, Tongliao, 028043, China

    Xianglian

  3. Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Bandung, 40132, Indonesia

    K. Basar

  4. Institute of Applied Beam Science, Ibaraki University, Hitachi, 316-8511, Japan

    H. Takahashi

Authors
  1. Xianglian
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  2. T. Sakuma
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  3. K. Basar
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  4. H. Takahashi
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Correspondence to T. Sakuma.

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Xianglian, Sakuma, T., Basar, K. et al. Oscillatory diffuse X-ray scattering from lead chalcogenides. J Therm Anal Calorim 99, 65–69 (2010). https://doi.org/10.1007/s10973-009-0481-x

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  • DOI: https://doi.org/10.1007/s10973-009-0481-x

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