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The stability of inclusion compounds under heating

Part 2. Inclusion compounds of layered zinc camphorate, linked by linear N-donor ligands

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Abstract

The thermal decomposition of three inclusion compounds: [Zn2(camph)2dabco]·DMF·H2O, [Zn2(camph)2bipy]·3DMF·H2O and [Zn2(camph)2bpe]·5DMF·H2O was studied in the inert atmosphere. TG and DTG curves confirm multi-step decomposition process, the dehydration being the first step. Thermogravimetric data (obtained at different rates of linear heating) were processed with computer program (with ‘Model-free’ approach). Kinetic parameters of decomposition were calculated for the DMF multi-step removal, the processes are described by Avrami–Erofeev equations. The connection between the kinetic parameters and structural features of the host frameworks (ligand linker lengths and porous-free volumes) are discussed.

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Acknowledgements

The authors are grateful to Netzsch Geraetebau GmbH for the possibility to work with computer program “NETZSCH Thermokinetics 2” and RFBR for the financial support (Grants 07-03-00436 and 07-03-91208).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Ac. Lavrentyev Ave. 3, 630090, Novosibirsk-90, Russia

    V. Logvinenko, D. Dybtsev, V. Fedin, V. Drebushchak & M. Yutkin

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  1. V. Logvinenko
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  2. D. Dybtsev
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  3. V. Fedin
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  4. V. Drebushchak
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  5. M. Yutkin
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Correspondence to V. Logvinenko.

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Logvinenko, V., Dybtsev, D., Fedin, V. et al. The stability of inclusion compounds under heating. J Therm Anal Calorim 100, 183–189 (2010). https://doi.org/10.1007/s10973-009-0444-2

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  • DOI: https://doi.org/10.1007/s10973-009-0444-2

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