Skip to main content
SpringerLink
Log in

Synthesis and thermal decomposition kinetics of two lanthanide complexes with cinnamic acid and 2,2′-Bipyridine

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

The two complexes of [Ln(CA)3bipy]2 (Ln = Tb and Dy; CA = cinnamate; bipy = 2,2′-bipyridine) were prepared and characterized by elemental analysis, infrared spectra, ultraviolet spectra, thermogravimetry and differential thermogravimetry techniques. The thermal decomposition behaviors of the two complexes under a static air atmosphere can be discussed by thermogravimetry and differential thermogravimetry and infrared spectra techniques. The non-isothermal kinetics was investigated by using a double equal-double steps method, the nonlinear integral isoconversional method and the Starink method. The mechanism functions of the first decomposition step of the two complexes were determined. The thermodynamic parameters (ΔH ≠, ΔG ≠ and ΔS ≠) and kinetic parameters (activation energy E and the pre-exponential factor A) of the two complexes were also calculated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Yan B. Sol–gel preparation and luminescence of silica/polymer hybrid material incorporated with terbium complex. Mater Lett. 2003;57:2535–9.

    Article  CAS  Google Scholar 

  2. Ci YX, Li YZ, Chang WB. Fluorescence reaction of terbium(III) with nucleic acids in the presence of phenanthroline. Anal Chim Acta. 1991;248:589–94.

    Article  CAS  Google Scholar 

  3. Scott LK, Horrocks WD. Lanthanide ion luminescence as a probe of DNA structure. 2. Non-guanine-containing oligomers and nucleotides. J Inorg Biochem. 1992;46:193–205.

    Article  Google Scholar 

  4. Siqueira AB, Bannach G, Rodrigues EC, Carvalho CT, Ionashiro M. Solid-state 2-methoxybenzoates of light trivalent lanthanides synthesis, characterization and thermal behaviour. J Therm Anal Cal. 2008;91:897–902.

    Article  CAS  Google Scholar 

  5. Locatelli JR, Rodrigues EC, Siqueira AB, Ionashiro EY, Bannach G, Ionashiro M. Synthesis characterization and thermal behaviour of solid-state compounds of yttrium and lanthanide benzoates. J Therm Anal Cal. 2007;90:737–46.

    Article  CAS  Google Scholar 

  6. Li Y, Zheng FK, Liu X, Zou WQ, Guo GC, Lu CZ, et al. Crystal structures and magnetic and luminescent properties of a series of homodinuclear lanthanide complexes with 4-cyanobenzoic ligand crystal structures and magnetic and luminescent properties of a series of homodinuclear lanthanide complexes with 4-cyanobenzoic ligand. Inorg Chem. 2006;45:6308–16.

    Article  CAS  Google Scholar 

  7. Li GQ, Li Y, Zou WQ, Chen QY, Zheng FK, Guo GC. Synthesis and crystal structure of a new Lanthanum(III) 4-cyanobenzoate complex. Chin J Struct Chem. 2007;26:575–9.

    CAS  Google Scholar 

  8. Lam AWH, Wang W, Gao TS, Wen GH, Zhang XX. Synthesis, crystal structure, and photophysical and magnetic properties of dimeric and polymeric lanthanide complexes with benzoic acid and its derivatives. Eur J Inorg Chem 2003;2003:149–63.

    Article  Google Scholar 

  9. Ferenc W, Dziewulska-Kuaczkowska A, Sarzyski J, Paszkowska B. 4-Chloro-2-methoxybenzoates of heavy lanthanides(III) and yttrium(III) Thermal spectral and magnetic behaviour. J Therm Anal Cal. 2008;91:285–92.

    Article  CAS  Google Scholar 

  10. Ionashiro EY, Bannach G, Siqueira AB, de Carvalho CT, Rodrigues EC, Ionashiro M. 2-Methoxybenzylidenepyruvatewith heavier trivalent lanthanides and yttrium(III) synthesis and characterization. J Therm Anal Cal. 2008;92:953–9.

    Article  CAS  Google Scholar 

  11. Tian L, Ning Ren, Zhang JJ, Sun SJ, Ye HM, Bai JH, et al. Synthesis, crystal structure, and thermal decomposition kinetics of the complex of dysprosium benzoate with 2, 2′-bipyridine. J Chem Eng Data. 2009;54:69–74.

    Article  CAS  Google Scholar 

  12. Xu XL, Zhang JJ, Yang HF, Ren N, Zhang HY. Synthesis, crystal structure and thermal decomposition of a dysprosium(III) p-fluorobenzoate 1, 10-phenanthroline complex. J Chem Sci. 2007;62b:51–4.

    Google Scholar 

  13. Zhang HY, Zhang JJ, Ren N, Xu SL, Tian L, Bai JH. Synthesis, crystal structure and thermal decomposition mechanism of the complex [Sm(p-BrBA)3bipy·H2O]2·H2O. J Alloy Compd. 2008;464:277–81.

    Article  CAS  Google Scholar 

  14. Zhang JJ, Ren N, Bai JH, Xu SL. Synthesis and thermal decomposition reaction kinetics of complexes of [Sm2(m-ClBA)6(phen)2]·2H2O and [Sm2(m-BrBA)6(phen)2]·2H2O. J Chem Kinet. 2007;39:67–74.

    Article  Google Scholar 

  15. Tian L, Ren N, Zhang JJ, Liu HM, Bai JH, Ye HM, et al. Synthesis, crystal structure luminescence and thermal decomposition kinetics of Eu(III) complex with 2, 4-dichlorobenzoic acid and 2, 2′-bipyridine. Inorg Chim Acta. 2009;362:3388–94.

    Article  CAS  Google Scholar 

  16. Guo DF, He J, Zeng ZZ. Studies on interaction between ternary rare earth complexes of cinnamic acid and phenanthroline with DNA by spectroscopy. J Chin Rare Earth Soc. 2004;22:55–60.

    CAS  Google Scholar 

  17. Carvalho Filho MAS, Fernandes NS, Leles MIG, Mendes R, Ionashiro M. Preparation and thermal decomposition of solid-state cinnamates of lighter trivalent lanthanides. J Therm Anal Cal. 2000;59:669–74.

    Article  Google Scholar 

  18. Xie XM, Zeng ZZ. Syntheses, anti-inflammatory action and XPS of Ln (III) -1, 10-phenanthroline-cinnamic acid complexes. J Lanzhou Univ (Nat Sci). 2003;39:64–7.

    CAS  Google Scholar 

  19. Zhang JJ, Ren N. A new kinetic method of processing TA data. Chin J Chem. 2004;22:1459–62.

    CAS  Google Scholar 

  20. Vyazovkin S, Dollimore D. Linear and nonlinear procedures in isoconversional computations of the activation energy of nonisothermal reactions in solids. J Chem Inf Comp Sci. 1996;36:42–5.

    CAS  Google Scholar 

  21. Starink MJ. The determination of activation energy from linear heating rate experiments: a comparison of the accuracy of isoconversion methods. Thermochim Acta. 2003;404:163–76.

    Article  CAS  Google Scholar 

  22. Gao Z, Nakada M, Amasski I. A consideration of errors and accuracy in the isoconversional methods. Thermochim Acta. 2001;369:137–42.

    Article  CAS  Google Scholar 

  23. Hu RZ, Gao SL, Zhao FQ, Shi QZ, Zhang TL, Zhang JJ. Thermal Analysis Kinetics. 2nd ed. Beijing: Science Press; 2008. p. 151.

    Google Scholar 

  24. Wang RF, Jin LP, Wang MZ, Huang SH, Chen XT. Synthesis, crystal structure and luminescence of coordination compound of europium p-methylbenzoate with 2, 2′-Dipyridine. Acta Chim Sin. 1995;53:39–45.

    CAS  Google Scholar 

  25. Shi YZ, Sun XZ, Jiang YH. Spectra and Chemical Identification of Organic Compounds. Nanjing: Science and Technology Press; 1988. p. 98.

    Google Scholar 

  26. Deacon GB, Phillips RJ. Relationships between the carbon-oxygen stretching frequencies of carboxylato complexes and the type of carboxylate coordination. Coord Chem Rev. 1980;33:227–50.

    Article  CAS  Google Scholar 

  27. An BL, Gong ML, Li MX, Zhang JM. Synthesis, structure and luminescence properties of samarium(III) and dysprosium(III) complexes with a new tridentate organic ligand. J Mol Struct. 2004;687:1–6.

    Article  CAS  Google Scholar 

  28. Lu ZR, Ding YC, Xu Y, Li BL, Zhang Y. TA Study on four-one-dimensional chain copper complexes with benzoylacetone or 1, 1, 1-trifluoro-3-(2-thenoyl)-acetone bridged through azobispyridine ligands. Chin J Inorg Chem (in Chinese). 2005;21:181–5.

    Google Scholar 

  29. Straszko J, Olstak-Humienik M, Mozejko J. Kinetics of thermal decomposition of ZnSO4·7H2O. Thermochim Acta. 1997;292:145–50.

    Article  CAS  Google Scholar 

  30. Olstak-Humienik M, Mozejko J. Thermodynamic functions of activated complexes created in thermal decomposition processes of sulphates. Thermochim Acta. 2000;344:73–9.

    Article  Google Scholar 

Download references

Acknowledgements

This project was supported by the National Natural Science Foundation of China (No. 20773034), the Natural Science Foundation of Hebei Province (No. B2007000237, No. E2009000307) and Education Department Scientific Research Fund from Hebei Province (2008469).

Author information

Authors and Affiliations

  1. Experimental Center, Hebei Normal University, Shijiazhuang, 050016, People’s Republic of China

    L. Tian, J. J. Zhang, S. J. Sun & H. M. Ye

  2. College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang, 050016, People’s Republic of China

    L. Tian, S. J. Sun, H. M. Ye & K. Z. Wu

  3. Department of Chemistry, Handan College, Handan, 056005, People’s Republic of China

    N. Ren

  4. College of Chemistry and Pharmacy Engineering, Hebei University of Science and Technology, Shijiazhuang, 050018, People’s Republic of China

    H. M. Liu

Authors
  1. L. Tian
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. Ren
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. J. Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. H. M. Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. J. Sun
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. H. M. Ye
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. K. Z. Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to J. J. Zhang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tian, L., Ren, N., Zhang, J.J. et al. Synthesis and thermal decomposition kinetics of two lanthanide complexes with cinnamic acid and 2,2′-Bipyridine. J Therm Anal Calorim 99, 349–356 (2010). https://doi.org/10.1007/s10973-009-0272-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-009-0272-4

Keywords

Search

Navigation