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Journal of Thermal Analysis and Calorimetry

, Volume 94, Issue 1, pp 45–51 | Cite as

The growth and characterization of 2,4-dinitro phenyl hydrazone of benzophenone and mixed crystals

  • G. Madhurambal
  • P. Ramasamy
  • P. AnbuSrinivasan
  • M. Suganthi
  • G. Vasudevan
  • S. C. Mojumdar
Article

Abstract

Good quality benzophenone (BP) crystals were grown by solution technique using CHCl3 as solvent by adopting slow evaporation method at room temperature. The grown crystals were subjected to various characterization studies to analyze its purity and applications. The condensation product 2,4-dinitro phenyl hydrazone of benzophenone (DNPBP) was prepared by adopting standard procedure. Then mixed crystal of BP and DNPBP was also grown by solution growth. Both the condensation product and mixed crystals were characterized by UV, FTIR, 1H NMR spectra. Thermal (TG and DTA) studies have proved to be very useful techniques not only to study the thermal properties of BP, DNPBP and mixed crystal but also to study their purity. Second harmonic generation (SHG) efficiency of the grown crystals was determined.

Keywords

benzophenone characterization DTA mixed crystal SHG efficiency solution growth TG 

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Copyright information

© Springer Science+Business Media, LLC. 2008

Authors and Affiliations

  • G. Madhurambal
    • 1
  • P. Ramasamy
    • 2
  • P. AnbuSrinivasan
    • 3
  • M. Suganthi
    • 3
  • G. Vasudevan
    • 3
  • S. C. Mojumdar
    • 4
    • 5
  1. 1.ADM College for WomenNagapattinamTamil NaduIndia
  2. 2.Crystal Growth CenterChennaiTamil NaduIndia
  3. 3.AVC CollegeMayiladuthuraiTamil NaduIndia
  4. 4.Department of Chemical Engineering and Applied ChemistryUniversity of TorontoToronto, ONCanada
  5. 5.University of New BrunswickSaint John, NBCanada

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