Journal of Thermal Analysis and Calorimetry

, Volume 95, Issue 1, pp 247–251 | Cite as

bis(N,N-diethylnicotinamide) p-chlorobenzoate complexes of Ni(II), Zn(II) and Cd(II)

Synthesis and characterization
  • D. A. Köse
  • G. Gökçe
  • S. Gökçe
  • İ. Uzun


Three novel mixed ligand complexes of Ni(II), Zn(II) and Cd(II) with p-chlorobenzote and N,N-diethylnicotinamide were synthesised and characterized on the basis of elemental analysis, FTIR spectroscopic analysis, solid state UV-Vis spectrometric and magnetic susceptibility data. The thermal behavior of the complexes was studied by simultaneous TG-DTA methods in static air atmosphere and the mass spectra data were recorded.

According to microanalytical results, formulas of complexes are C34H40N4O8ClNi, C34H40N4O8ClZn and C34H44N4O10ClCd. The complexes contain two moles of coordination waters, two moles p-chlorobenzoate and two mole N,N-diethylnicotinamide (dena) ligands per formula unit. In these complexes, the p-chlorobenzoate and N,N-diethylnicotinamide behave as monodentate ligand through acidic oxygen and nitrogen of pyridine ring. The decomposition pathways and the stability of the complexes are interpreted in the terms of the structural data. The final decomposition products were found to be as metal oxides.


p-chlorobenzoate N,N-diethylnicotinamide mixed ligand complexes thermal decomposition transition metal complexes 


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  1. 1.
    R. Bakhtiar and E. I. Ochiai, General Pharmacology, 32 (1999) 525.CrossRefGoogle Scholar
  2. 2.
    A. Hossaini, J. J. Larsen and J. C. Larsen, Food Chem. Toxicology, 38 (2000) 19.CrossRefGoogle Scholar
  3. 3.
    K. B. Diehl, Am. Fam. Physician, 54 (1996) 1687.Google Scholar
  4. 4.
    D. Russell and A. D. Russell, J. Infect., 24 (1992) 333.CrossRefGoogle Scholar
  5. 5.
    J. R. J. Sorensen and H. Sigel, Metal Ions in Biological Systems, Marcel Dekker, New York, 14 (1982) 77.Google Scholar
  6. 6.
    M. Kato and Y. Muto, Coord. Chem. Rev., 92 (1988) 45.CrossRefGoogle Scholar
  7. 7.
    R. Nagar, J. Inorg. Biochem., 40 (1990) 349.CrossRefGoogle Scholar
  8. 8.
    G. Cavigiolio, L. Benedetto, E. Boccaleri, D. Colangelo, I. Viano and D. Osella, Inorg. Chim. Acta, 305 (2000) 61.CrossRefGoogle Scholar
  9. 9.
    U. Brühlmann and E. Hayon, J. Am. Chem. Soc., 96 (1974) 6169.CrossRefGoogle Scholar
  10. 10.
    M. R. Sundberg, R. Uggla and R. Kivekas, Inorg. Chim. Acta, 232 (1995) 1.CrossRefGoogle Scholar
  11. 11.
    T. Hökelek and H. Necefoǧlu, Anal. Sci., 15 (1999) 1043.CrossRefGoogle Scholar
  12. 12.
    N. N. Hoang, F. Valanch and M. Melnik, Z. Kristalogr., 208 (1999) 27.CrossRefGoogle Scholar
  13. 13.
    T. Hökelek and H. Necefoǧlu, Acta Cryst., C53 (1997) 187.Google Scholar
  14. 14.
    H. Necefoǧlu, W. Clegg and A. J. Scott, Acta Cryst., E57 (2001) 462.Google Scholar
  15. 15.
    D. A. Köse, Russ. J. Inorg. Chem., 52 (2007) 1384.CrossRefGoogle Scholar
  16. 16.
    W. Wolodkiewicz, J. Coord. Chem., 55 (2002) 727.CrossRefGoogle Scholar
  17. 17.
    W. Wolodkiewicz and T. Glowiak, J. Coord. Chem., 56 (2003) 563.CrossRefGoogle Scholar
  18. 18.
    T. S. Khodashova, M. A. Poray-Koshits, B. Ya., Rubinchik, L. A. Butman and G. V. Tsintzade, Koord. Khim., 4 (1978) 1753.Google Scholar
  19. 19.
    M. A. Poray-Koshits, B. Ya. Rubinchik, L. A. Butman, G. V. Tsintzade and V. S. Segienko, Koord. Khim., 4 (1978) 1760.Google Scholar
  20. 20.
    F. Bigoli, A. Braibanti, M. A. Pellinmghelli and A. Tiripicchio, Acta Cryst., B28 (1972) 962.Google Scholar
  21. 21.
    V. N. Shurkina, T. S. Khodashova, M. A. Poray-Koshits, G. V. Tsintzade and V. S. Segienko, Koord. Khim., 6 (1980) 1606.Google Scholar
  22. 22.
    E. F. Öztürkkan, D. A. Köse, H. Necefoǧlu and I. Uzun, Asian J. Chem., 19 (2007) 4880.Google Scholar
  23. 23.
    D. A. Köse, H. İçbudak and H. Necefoǧlu, Hacettepe J. Biol. Chem., 35 (2007) 123.Google Scholar
  24. 24.
    H. Icbudak, H. Olmez, O. Z. Yesilel, F. Arslan, P. Naumov, G. Jovanovski, A. R. Ibrahim, A. Usman, H. K. Fun, S. Chantrapromma and S. W. Ng, J. Mol. Struct., 657 (2003) 255.CrossRefGoogle Scholar
  25. 25.
    H. Icbudak, V. T. Yilmaz and H. Ölmez, J. Thermal Anal., 53 (1998) 843.CrossRefGoogle Scholar
  26. 26.
    O. Şahin, O. Büyükgüngör, D. A. Köse, E. F. Ozturkkan and H. Necefoǧlu, Acta Cryst., C63 (2007) m243.Google Scholar
  27. 27.
    W. Wolodkiewicz and W. Brzyska, J. Therm. Anal. Cal., 55 (1999) 639.CrossRefGoogle Scholar
  28. 28.
    J. Skorsepa, E. Godocikova and J. Cernak, J. Therm. Anal. Cal., 75 (2004) 773.CrossRefGoogle Scholar
  29. 29.
    W. Brzyska and W. Wolodkiewicz, Thermochim. Acta, 242 (1994) 131.CrossRefGoogle Scholar
  30. 30.
    D. A. Köse, A. Kaya and H. Necefoǧlu, Russ. J. Coord. Chem., 33 (2007) 422.CrossRefGoogle Scholar
  31. 31.
    E. Regulska, M. Samsonowicz, R. Swisłocka and W. Lewandowski, J. Mol. Struct., 744 (2005) 353.CrossRefGoogle Scholar
  32. 32.
    D. A. Köse, B. Zümreoglu-Karan, O. Şahin and O. Büyükgüngör, J. Mol. Struct., 789 (2006) 147.CrossRefGoogle Scholar
  33. 33.
    W. Wolodkiewicz and W. Brzyska, Pol. J. Chem., 72 (1998) 2366.Google Scholar
  34. 34.
    H. Icbudak, Z. Heren, D. A. Köse and H. Necefoglu, J. Therm. Anal. Cal., 76 (2004) 837.CrossRefGoogle Scholar
  35. 35.
    K. Györyova, E. Szunyogova, J. Kovarova, D. Hudecova, D. Mudronova and E. Juhaszova, J. Therm. Anal. Cal., 72 (2003) 587.CrossRefGoogle Scholar
  36. 36.
    J. Zsakó, G. Pokol, Cs. Novák, Cs. Várhelyi, A. Dobó and G. Liptay, J. Therm. Anal. Cal., 64 (2001) 843.CrossRefGoogle Scholar
  37. 37.
    R. Kupriel-Gorgol and W. Bryzyska, Pol. J. Chem., 59 (1985) 345.Google Scholar
  38. 38.
    M. Sarı, G. Gökçe, S. Gökçe, E. Şahin and H. Necefoǧlu, Acta Cryst., E63 (2007) m2191.Google Scholar
  39. 39.
    M. Olczak-Kobza, R. Czylkowski and J. Karolak-Wojciechowska, J. Therm. Anal. Cal., 74 (2003) 895.CrossRefGoogle Scholar
  40. 40.
    W. Ferenc and B. Bocian, J. Therm. Anal. Cal., 74 (2003) 521.CrossRefGoogle Scholar
  41. 41.
    B. R. Srinivasan and S. C. Sawant, Thermochim. Acta, 402 (2003) 45.Google Scholar
  42. 42.
    P. Kokkonen, L. H. J. Lajunen, A. Jaakola and H. Ruotsalainen, Thermochim. Acta, 79 (1984) 289.CrossRefGoogle Scholar
  43. 43.
    G. A. M. Hussein, H. M. Ismail and S. A. S. Mansour, J. Anal. Appl. Pyrolysis, 36 (1996) 17.CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC. 2009

Authors and Affiliations

  • D. A. Köse
    • 1
    • 2
  • G. Gökçe
    • 2
  • S. Gökçe
    • 2
  • İ. Uzun
    • 3
  1. 1.Department of ChemistryHacettepe UniversityAnkaraTurkey
  2. 2.Faculty of Art and Science, Department of ChemistryKafkas UniversityKarsTurkey
  3. 3.Department of Mechanical Engineering, Faculty of EngineeringKýrýkkale UniversityKýrýkkaleTurkey

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