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Journal of Thermal Analysis and Calorimetry

, Volume 95, Issue 1, pp 247–251 | Cite as

bis(N,N-diethylnicotinamide) p-chlorobenzoate complexes of Ni(II), Zn(II) and Cd(II)

Synthesis and characterization
  • D. A. Köse
  • G. Gökçe
  • S. Gökçe
  • İ. Uzun
Article

Abstract

Three novel mixed ligand complexes of Ni(II), Zn(II) and Cd(II) with p-chlorobenzote and N,N-diethylnicotinamide were synthesised and characterized on the basis of elemental analysis, FTIR spectroscopic analysis, solid state UV-Vis spectrometric and magnetic susceptibility data. The thermal behavior of the complexes was studied by simultaneous TG-DTA methods in static air atmosphere and the mass spectra data were recorded.

According to microanalytical results, formulas of complexes are C34H40N4O8ClNi, C34H40N4O8ClZn and C34H44N4O10ClCd. The complexes contain two moles of coordination waters, two moles p-chlorobenzoate and two mole N,N-diethylnicotinamide (dena) ligands per formula unit. In these complexes, the p-chlorobenzoate and N,N-diethylnicotinamide behave as monodentate ligand through acidic oxygen and nitrogen of pyridine ring. The decomposition pathways and the stability of the complexes are interpreted in the terms of the structural data. The final decomposition products were found to be as metal oxides.

Keywords

p-chlorobenzoate N,N-diethylnicotinamide mixed ligand complexes thermal decomposition transition metal complexes 

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Copyright information

© Springer Science+Business Media, LLC. 2009

Authors and Affiliations

  • D. A. Köse
    • 1
    • 2
  • G. Gökçe
    • 2
  • S. Gökçe
    • 2
  • İ. Uzun
    • 3
  1. 1.Department of ChemistryHacettepe UniversityAnkaraTurkey
  2. 2.Faculty of Art and Science, Department of ChemistryKafkas UniversityKarsTurkey
  3. 3.Department of Mechanical Engineering, Faculty of EngineeringKýrýkkale UniversityKýrýkkaleTurkey

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