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New praseodymium(III) and d-electron metals tungstates of the formula MPr2W2O10 (M=Mn, Co, Cd)

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Abstract

Three new compounds MPr2W2O10 (M=Mn, Co, Cd) were prepared by the solid-state reaction. They are isostructural and crystallize in the orthorhombic system. MPr2W2O10 (M=Mn or Co) melt incongruently above 1150°C and the solid product of melting is Pr2W2O9. The CdPr2W2O9 compound starts decomposing in the solid-state at 1156°C to Pr2W2O9 and CdO.

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Authors and Affiliations

  1. Department of Inorganic and Analytical Chemistry, Szczecin University of Technology, Al. Piastów 42, 71-065, Szczecin, Poland

    E. Tomaszewicz

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  1. E. Tomaszewicz
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Tomaszewicz, E. New praseodymium(III) and d-electron metals tungstates of the formula MPr2W2O10 (M=Mn, Co, Cd). J Therm Anal Calorim 93, 711–715 (2008). https://doi.org/10.1007/s10973-008-9133-9

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