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Thermochemistry of the binary system nitrocellulose+N-nitrodiethanolamine dinitrate

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Abstract

The melting and mixing enthalpy of the binary system nitrocellulose and N-nitrodiethanolamine dinitrate (DINA) was determined by DSC. The mixing enthalpy H Mmax = 1.95 kJ mol−1 had maximum at mass fraction x wDINA=0.46. The influence of samples storing on glass and endothermic transitions were studied. The temperature range of glass transition broadened with x wDINA what proved the increase of samples heterogeneity. For x wDINA≤0.750 no influence of samples storing on the phase changes was observed. The heat capacity change decreased and temperature range of glass transition increased for x wDINA≤0.500 what indicated the reduction of glass phase fraction in studied samples.

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Authors and Affiliations

  1. Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664, Warsaw, Poland

    A. Książczak, M. Ostrowski & W. Tomaszewski

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  1. A. Książczak
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  2. M. Ostrowski
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  3. W. Tomaszewski
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Correspondence to A. Książczak.

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Książczak, A., Ostrowski, M. & Tomaszewski, W. Thermochemistry of the binary system nitrocellulose+N-nitrodiethanolamine dinitrate. J Therm Anal Calorim 94, 275–279 (2008). https://doi.org/10.1007/s10973-007-8943-5

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  • DOI: https://doi.org/10.1007/s10973-007-8943-5

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