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Journal of Thermal Analysis and Calorimetry

, Volume 91, Issue 1, pp 279–284 | Cite as

Thermal properties of tetraethylammonium tetrachloro-, bromotrichloro-and tribromochloroferrates(III)

  • D. Wyrzykowski
  • Agnieszka Pattek-Janczyk
  • T. Maniecki
  • Katarzyna Zaremba
  • Z. Warnke
Regular Papers Complexes

Abstract

Thermal decomposition of tetraethylammonium tetrachloro-, bromotrichloro-and tribromochloroferrates(III), of general formula [(C2H5)4N][FeBr4−nCln] (n=1, 3, 4), has been studied using the TG-MS, DTA and DTG techniques. The measurements were carried out in an argon atmosphere over the temperature range 293–1073 K. Solid products of the thermal decomposition were identified by Mössbauer spectroscopy.

Keywords

Mössbauer spectroscopy tetrahalogenoferrates(III) thermal decomposition 

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Copyright information

© Springer Science+Business Media, LLC. 2007

Authors and Affiliations

  • D. Wyrzykowski
    • 1
  • Agnieszka Pattek-Janczyk
    • 2
  • T. Maniecki
    • 3
  • Katarzyna Zaremba
    • 2
  • Z. Warnke
    • 1
  1. 1.Faculty of ChemistryUniversity of GdańskGdańskPoland
  2. 2.Faculty of ChemistryJagiellonian UniversityCracowPoland
  3. 3.Institute of General and Ecological ChemistryTechnical University of ŁódźŁódźPoland

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