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Journal of Thermal Analysis and Calorimetry

, Volume 90, Issue 2, pp 587–595 | Cite as

Thermodynamic properties of binary mixtures formed by cyclic ethers and chloroalkanes

  • I. Giner
  • A. Villares
  • M. Haro
  • I. Gascón
  • C. Lafuente
Regular papers Thermodynamics

Abstract

Densities, speeds of sound and refractive indices of the binary mixtures 1,3-dioxolane or 1,4-dioxan+1-chloropentane or 1-chlorohexane have been measured at the temperatures of 298.15 and 313.15 K. Excess molar volumes, isentropic compressibilities, isentropic compressibility deviations and refractive index deviations have been obtained from experimental data. Excess molar volumes, isentropic compressibility and refractive index deviations have been fitted to a Redlich-Kister equation. Excess molar volumes, speeds of sound and isentropic compressibilities have been estimated at 298.15 K using the Prigogine-Flory-Patterson theory.

Keywords

chloroalkane cyclic ether density PFP theory refractive index speed of sound 

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Copyright information

© Springer Science+Business Media, LLC. 2007

Authors and Affiliations

  • I. Giner
    • 1
  • A. Villares
    • 1
  • M. Haro
    • 1
  • I. Gascón
    • 2
  • C. Lafuente
    • 1
  1. 1.Departamento de Química Orgánica-Química Físaica, Facultad de CienciasUniversidad de Zaragoza, Ciudad UniversitariaZaragozaSpain
  2. 2.Departmento de Química Orgánica-Química FísicaEscuela Politécnica SuperiorHuescaSpain

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