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Acid properties of semicrystalline zeolitic mesoporous UL-ZSM-5 materials

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Abstract

UL-ZSM-5 materials have been prepared by templated solid-state crystallization of zeolites starting from the amorphous mesostructured aluminosilicate Al-Meso. Microcalorimetry and FTIR have been employed to characterize their surface acidity. In good agreement with 27Al MAS NMR data, UL-ZSM-5 displayed an improved density and strength of Brönsted acid sites, as compared to Al-Meso, owing to the incorporation of aluminium in a tetrahedral environment similar to that of zeolite ZSM-5. Moreover, they showed an enhanced Brönsted/Lewis relative acid ratio. However, Al-Meso showed the highest concentration of strong Lewis acid sites due to its largest amount of aluminium in extraframework positions.

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Authors and Affiliations

  1. Department of Chemical Engineering, Laval University, Ste Foy, Québec, Canada, G1K 7P4

    A. Ungureanu, H. V. Thang, D. Trong On & S. Kaliaguine

  2. Laboratory of Catalysis, Technical University of Iasi, Iasi, Romania, 6600, 71 D. Mangeron

    A. Ungureanu & E. Dumitriu

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  1. A. Ungureanu
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  2. H. V. Thang
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  3. D. Trong On
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  4. E. Dumitriu
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  5. S. Kaliaguine
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Correspondence to S. Kaliaguine.

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Ungureanu, A., Thang, H.V., Trong On, D. et al. Acid properties of semicrystalline zeolitic mesoporous UL-ZSM-5 materials. J Therm Anal Calorim 87, 417–422 (2007). https://doi.org/10.1007/s10973-006-6891-0

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  • DOI: https://doi.org/10.1007/s10973-006-6891-0

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