Journal of Thermal Analysis and Calorimetry

, Volume 86, Issue 2, pp 541–546 | Cite as

Thermodynamic studies of (R)-BINOL-menthyl dicarbonates

  • X.-C. Lv
  • Z.-C. Tan
  • Z.-A. Li
  • Y.-S. Li
  • J. Xing
  • Q. Shi
  • L.-X. Sun


The (R)-BINOL-menthyl dicarbonates, one of the most important compounds in catalytic asymmetric synthesis, was synthesized by a convenient method. The molar heat capacities C p,m of the compound were measured over the temperature range from 80 to 378 K with a small sample automated adiabatic calorimeter. Thermodynamic functions [H TH 298.15] and [S TS 298.15] were derived in the above temperature range with a temperature interval of 5 K. The thermal stability of the substance was investigated by differential scanning calorimeter (DSC) and a thermogravimetric (TG) technique.


adiabatic calorimeter low-temperature heat capacity (R)-BINOL-menthyl dicarbonates thermal analysis 


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Copyright information

© Springer-Verlag 2006

Authors and Affiliations

  • X.-C. Lv
    • 1
  • Z.-C. Tan
    • 1
  • Z.-A. Li
    • 1
  • Y.-S. Li
    • 2
  • J. Xing
    • 1
  • Q. Shi
    • 1
  • L.-X. Sun
    • 1
  1. 1.Thermochemistry Laboratory, Dalian Institute of Chemical PhysicsChinese Academy of ScienceDalianChina
  2. 2.College of Environmental Science and EngineeringDalian Jiaotong UniversityDalianChina

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