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Thermally induced rings formation in aluminosilicate structures

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Abstract

In the present study, we performed an investigation of phase transformation of zeolite Na-GIS in temperature interval from room temperature up to 1300°C. The collapse of S4R and S8R (secondary building units in zeolite Na-GIS) and the forming of pure sodium nepheline phase, consists of S6R, was examined. During the thermal transformation of Na-GIS zeolite symmetry of rings was changed and their deformation increases. The irregularity of rings causes the appearance of defect modes in the IR spectra of amorphous precursors. Investigated phases were characterized by XRPD, IR, NMR and DSC methods. A semiempirical method AM1 was used for calculation of vibrational spectrum of nepheline.

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Authors and Affiliations

  1. Institute of Technical Sciences, Serbian Academy of Sciences and Arts, Belgrade, Serbia and Montenegro, 11001, Knez Mihailova 35/IV

    Marković S.

  2. Faculty of Physical Chemistry, Belgrade, Serbia and Montenegro, 137, Studentski Trg 12–16

    Dondur Vera

  3. Faculty of Mining and Geology, Department of Crystallography, Belgrade, Serbia and Montenegro, Djušina 7

    Dimitrijević R.

  4. Department of Biochemistry, Mayo Foundation, Rochester, USA, Minnesota

    Macura S.

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  1. Marković S.
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  2. Dondur Vera
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  3. Dimitrijević R.
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  4. Macura S.
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Marković, S., Dondur, V., Dimitrijević, R. et al. Thermally induced rings formation in aluminosilicate structures. J Therm Anal Calorim 84, 253–258 (2006). https://doi.org/10.1007/s10973-005-7161-2

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  • DOI: https://doi.org/10.1007/s10973-005-7161-2

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