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Synthesis, characterization and thermal decomposition of thiourea complexes of antimony and bismuth triiodide

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Abstract

The thiourea complexes of antimony and bismuth triiodide were synthesized by a direct reaction of antimony and bismuth triiodide with thiourea powder at room temperature. The formula of the complex is MI3[SC(NH2)2]3(M=Sb, Bi). The crystal structure of the complexes belongs to monoclinic system and the lattice parameters are a=1.4772 nm, b=1.6582 nm, c=2.0674 nm and β=90.81° for SbI3(SC(NH2)2)3 and a=1.4009 nm, b=2.0170 nm, c=2.0397 nm and β=90.84° for BiI3[SC(NH2)2]3. The infrared spectra reveal that the trivalent antimony or bismuth ion is coordinated by the nitrogen atom, not the sulfur atom of the thiourea. Thermal analysis shows that there are two times structure rearrangements or phase transformation in the complexes from 100 to 170°C.

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Authors and Affiliations

  1. College of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang, P. R. China, 621010

    Zhong G. Q.

  2. Department of Chemistry, Yancheng Teacher’s College, Yancheng, P. R. China, 224002

    Wang P.

  3. Department of Chemistry, Nanyang Teacher’s College, Nanyang, P. R. China, 473061

    Guo Y. C.

  4. Department of Chemistry, East China University of Science and Technology, Shanghai, P. R. China, 200237

    Luan S. R., Chen Y. R. & Jia Y. Q.

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  1. Zhong G. Q.
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  2. Luan S. R.
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  3. Wang P.
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  4. Guo Y. C.
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  5. Chen Y. R.
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  6. Jia Y. Q.
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Correspondence to Jia Y. Q..

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Zhong, G.Q., Luan, S.R., Wang, P. et al. Synthesis, characterization and thermal decomposition of thiourea complexes of antimony and bismuth triiodide. J Therm Anal Calorim 86, 775–781 (2006). https://doi.org/10.1007/s10973-005-6959-2

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  • DOI: https://doi.org/10.1007/s10973-005-6959-2

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