• Original Paper: Functional coatings, thin films and membranes (including deposition techniques)
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Apparent relaxation of in-plane residual stress of sol–gel-derived crystalline and glass oxide thin films

Abstract

Crystalline or glass oxide thin films with thickness of ca. 50–210 nm and porosity of ca. 5–17% were prepared on Si(100) wafers by the sol–gel method. The films were left standing at room temperature in dry and humid atmosphere as well as in water for varying periods of time. We measured the in-plane residual stress of the films as a function of time during storing at room temperature by measuring the radius of curvature of the substrate surface. The anatase, silica, and ceria films had tensile in-plane residual stress when fired at 1000 °C, 600 °C, and 800 °C, respectively. Such tensile stress was found to decrease with time, finally becoming constant, at room temperature, where the rate and extent of stress reduction were larger in the order, “in water” > “in humid atmosphere” > “in dry atmosphere.” On the other hand, the silica films had compressive in-plane residual stress when fired at 1000 °C. Such compressive stress was stable, not decreasing with time, at room temperature. The ceria film, after showing a decrease in tensile stress in humid atmosphere, exhibited an increase in stress when heated at 300 °C. When stored again at room temperature in humid atmosphere, the film showed a decrease in stress with time over again. Then we excluded the structural relaxation as the origin of the tensile stress reduction at room temperature, considering the stability of the compressive stress and the reversibility of the tensile stress. The ceria films showed a decrease in tensile stress even when stored in acetone and n-heptane vapors, suggesting that the film expansion resulting from the vapor-molecule adsorption may be the origin of the decrease in tensile stress. Yttria-stabilized zirconia films fired at 1000 °C also had tensile stress. The stress, however, was constant with time at room temperature, the reason for which is unknown, and further studies should be made.

Sol–gel-derived oxide thin films undergo a reduction of tensile in-plane stress at room temperature via adsorption of vapor molecules.

Highlights

  • Tensile residual in-plane stress in sol–gel-derived crystalline and glass oxide thin films was demonstrated to decrease with time at room temperature.

  • The rate and extent of stress reduction were found to be larger in humid atmosphere or in water than in dry atmosphere.

  • The adsorption of water molecules and the resulting volume expansion of films may be the origin of the reduction in tensile stress.

  • Such an instability of in-plane stress is an important issue from the viewpoint of the stability of the thin film performance and of the geometry and dimension precisions of thin film devices.

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References

  1. 1.

    Ma BH, Liu SS, Tong S, Narayanan M, Balachandran U (2012) J Appl Phys 112:114117

    Article  Google Scholar 

  2. 2.

    Tsvetkov N, Lu QY, Chen Y, Yildiz B (2015) ACS Nano 9:1613–1621

    CAS  Article  Google Scholar 

  3. 3.

    Kozuka H (2018) In: Klein LC, Aparicio M, Jitianu A (eds) Handbook of sol-gel science and technology, 2nd edn., Springer International Publishing AG, Basel, p 275–311

  4. 4.

    Ohno K, Uchiyama H, Kozuka H (2012) J Appl Phys 111:014901

    Article  Google Scholar 

  5. 5.

    Nakanishi S, Kojima R, Kozuka H (2020) J Sol-Gel Sci Tehcnol 93:506–516

    CAS  Article  Google Scholar 

  6. 6.

    Stoney GG (1909) Proc R Soc Lond A82:172–175

    Google Scholar 

  7. 7.

    Hoffman RW (1966) In: Hass G, Francombe MH, Hoffman RW, Vossen JL (eds) Physics of thin films, vol 3, Academic Press, New York, p 211–273

  8. 8.

    Brantley WA (1973) J Appl Phys 44:534–535

    CAS  Article  Google Scholar 

  9. 9.

    Ohya Y, Saiki H, Tanaka T, Takahashi Y (1996) J Am Ceram Soc 79:825–830

    CAS  Article  Google Scholar 

  10. 10.

    Committee of Fain Seramikkusu Jiten (1987) Fain seramikkusu jiten (fine ceramics dictionary), Gihodo, Tokyo, p 317

  11. 11.

    Wood DL, Nassau K, Kometani TY (1990) Appl Opt 29:2485–2488

    CAS  Article  Google Scholar 

  12. 12.

    Guo S, Arwin H, Jacobsen SN, Järrendahl K, Helmersson U (1995) J Appl Phys 77:5369–5376

    CAS  Article  Google Scholar 

  13. 13.

    Malitson IH (1965) J Opt Soc Am 55:1205–1209

    CAS  Article  Google Scholar 

  14. 14.

    Amberg CH, McIntosh R (1952) Can J Chem 30:1012–1030

    CAS  Article  Google Scholar 

  15. 15.

    Yates DJC (1954) Proc R Soc Lond Ser A 224:526–544

    CAS  Article  Google Scholar 

  16. 16.

    Kowalczyk P, Furmaniak S, Gauden PA, Terzyk AP (2010) J Phys Chem C 114:5126–5133

    CAS  Article  Google Scholar 

  17. 17.

    Arlt T, Bermejo M, Blanco MA, Gerward L, Jiang JZ, Saun Olsen J, Recio JM (2000) Phys Rev B 61:14414–14419

    CAS  Article  Google Scholar 

  18. 18.

    Pabst W, Gregorová E (2013) Ceram–Silik 57:167–184

    CAS  Google Scholar 

  19. 19.

    Kandil HM (1983) Dissertation for the Degree of Doctor of Philosophy, Department of Materials Science and Engineering, Iowa State University, Ames, Iowa, USA

  20. 20.

    Gerward L, Staun Olsen J, Petit L, Vaitheeswaran G, Kanchana V, Svane A (2005) J Alloy Compd 400:56–61

    CAS  Article  Google Scholar 

Download references

Acknowledgements

This work is supported by JSPS KAKENHI Grant Number JP19K22070 and by Nippon Sheet Glass Foundation for Materials Science and Engineering.

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Correspondence to Hiromitsu Kozuka.

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Kozuka, H., Kitano, S., Nishimura, Y. et al. Apparent relaxation of in-plane residual stress of sol–gel-derived crystalline and glass oxide thin films. J Sol-Gel Sci Technol (2020). https://doi.org/10.1007/s10971-020-05323-x

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Keywords

  • Thin film
  • Stress
  • Relaxation
  • Titania
  • Silica
  • Ceria