Abstract
For several decades, the sol–gel process allows the fabrication of functional materials through the strong coupling between materials chemistry and advanced processing. This branch of material’s science is generally associated with the formation of oxide and hybrid materials obtained through a transition between a sol and a gel. Engineering the sol–gel process to extend same principles to other classes of materials is an emerging and promising research line. These aspects will be illustrated in this article by reviewing the successful case of optical materials with tunable structural colours. It will be shown that sol–gel transition from molecular or colloidal building blocks results in optical materials with great diversity in structure and composition such as oxide, hybrid, or metal–organic frameworks. Applicative examples will be provided including photocatalytic, “invisible” and anti-reflective coatings, graded photonic mirrors and 2D photonic sensors.
Highlights
-
After 30 years from D. Ulrich’s pionnering works, most of the key advantages of the sol-gel process are still valid today suppression or appearance of structural colours was obtained by controlling the interplay between intrinsic optical properties of the materials and their structure.
-
Anti-reflective, invisible and photocatalytic coatings, graded Bragg mirros and diffraction gratings can be fabricated through engineering the sol-gel process to conventional and emerging materials.
-
Taking advantage of the versatility of the sol-gel process by extending the composition threshold beyond oxides is an exciting future research line for the field.
Similar content being viewed by others
References
Ulrich DR (1988) Better Ceramics through Chemistry. In: Laine RM (ed) Transformation of organometallics into common and exotic materials: design and activation. Springer, Netherlands, Dordrecht, pp 207–235. https://doi.org/10.1007/978-94-009-1393-6_19
Better Ceramics Through Chemistry II, Brinker CJ, Clark DE, Ulrich DR (eds.), Materials Research Society Symposium Proceedings, Materials Research Society, New York, 73, 1986
Faustini M, Nicole L, Ruiz-Hitzky E, Sanchez C (2018) History of organic–inorganic hybrid materials: prehistory, art, science, and advanced applications. Adv Funct Mater 28:1704158. https://doi.org/10.1002/adfm.201704158
Ulrich DR (1988) Prospects of sol–gel processes. J Non-Cryst Solids 100:174–193. https://doi.org/10.1016/0022-3093(88)90015-4
Faustini M, Grosso D, Boissiere C, Backov R, Sanchez C (2014) “Integrative sol–gel chemistry”: a nanofoundry for materials science. J Sol–Gel Sci Technol 70:216–226. https://doi.org/10.1007/s10971-014-3321-9
Yanagisawa T, Shimizu T, Kuroda K, Kato C (1990) The preparation of alkyltriinethylaininonium–kaneinite complexes and their conversion to microporous materials. Bull Chem Soc Jpn 63:988–992
Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD, Chu CTW, Olson DH, Sheppard EW, McCullen SB, Higgins JB, Schlenker JL (1992) A new family of mesoporous molecular sieves prepared with liquid crystal templates. J Am Chem Soc 114:10834–10843. https://doi.org/10.1021/ja00053a020
Ceratti DR, Faustini M, Sinturel C, Vayer M, Dahirel V, Jardat M, Grosso D (2015) Critical effect of pore characteristics on capillary infiltration in mesoporous films. Nanoscale 7:5371–5382
Faustini M, Boissiere C, Nicole L, Grosso D (2014) From chemical solutions to inorganic nanostructured materials: a journey into evaporation-driven processes. Chem Mater 26:709–723. https://doi.org/10.1021/cm402132y
Brinker CJ, Frye GC, Hurd AJ, Ashley CS (1991) Fundamental of sol–gel dip-coating. Thin Solid Films 201:97–108. https://doi.org/10.1016/0040-6090(91)90158-t
Faustini M, Drisko GL, Boissiere C, Grosso D (2014) Liquid deposition approaches to self-assembled periodic nanomasks. Scr Materialia 74:13–18. https://doi.org/10.1016/j.scriptamat.2013.07.029
Alemán JV, Chadwick AV, He J, Hess M, Horie K, Jones RG, Kratochvíl P, Meisel I, Mita I, Moad G, Penczek S, Stepto RFT (2007) Definitions of terms relating to the structure and processing of sols, gels, networks, and inorganic-organic hybrid materials (IUPAC Recommendations 2007). Pure Appl Chem, 79. https://doi.org/10.1351/pac200779101801
Innocenzi P. The sol to gel transition. Springer International Publishing AG Switzerland: Springer; 2016
Fellinger T-P (2017) Sol–gel carbons from ionothermal syntheses. J Sol–Gel Sci Technol 81:52–58. https://doi.org/10.1007/s10971-016-4115-z
Tian T, Zeng Z, Vulpe D, Casco ME, Divitini G, Midgley PA, Silvestre-Albero J, Tan J-C, Moghadam PZ, Fairen-Jimenez D (2018) A sol–gel monolithic metal–organic framework with enhanced methane uptake. Nat Mater 17:174–179. https://doi.org/10.1038/nmat5050
Almeida RM, Portal S (2003) Photonic band gap structures by sol–gel processing. Curr Opin Solid State Mater Sci 7:151–157
Dislich H, Hinz P (1982) Proceedings of the International Workshop on Glasses and Glass Ceramics from Gels History and principles of the sol–gel process, and some new multicomponent oxide coatings. J Non-Cryst Solids 48:11–16. https://doi.org/10.1016/0022-3093(82)90242-3
Livage J, Henry M, Sanchez C (1988) Sol–gel chemistry of transition metal oxides. Prog Solid State Chem 18:259–341. https://doi.org/10.1016/0079-6786(88)90005-2
Geffcken W, Berger E (1939) Ger Pat 736(May):411
Naudin G, Ceratti DR, Faustini M (2017) Sol-Gel Derived Functional Coatings for Optics. In: Pillai S., Hehir S. (eds) Sol-Gel Materials for Energy, Environment and Electronic Applications. Advances in Sol-Gel Derived Materials and Technologies. Springer, Cham
Louis B, Krins N, Faustini M, Grosso D (2011) Understanding crystallization of anatase into binary SiO2/TiO2 Sol–Gel optical thin films: an in situ thermal ellipsometry analysis. J Phys Chem C 115:3115–3122. https://doi.org/10.1021/jp109653p
Lee D, Rubner MF, Cohen RE (2006) All-nanoparticle thin-film coatings. Nano Lett 6:2305–2312. https://doi.org/10.1021/nl061776m
Brigo L, Faustini M, Pistore A, Kang HK, Ferraris C, Schutzmann S, Brusatin G (2016) Porous inorganic thin films from bridged silsesquioxane sol–gel precursors. J Non-Cryst Solids 432:399–405
Sanchez C, Boissiere C, Cassaignon S, Chaneac C, Durupthy O, Faustini M, Grosso D, Laberty-Robert C, Nicole L, Portehault D, Ribot F, Rozes L, Sassoye C (2014) Molecular engineering of functional inorganic and hybrid materials. Chem Mater 26:221–238. https://doi.org/10.1021/cm402528b
Soler-Illia G, Azzaroni O (2011) Multifunctional hybrids by combining ordered mesoporous materials and macromolecular building blocks. Chem Soc Rev 40:1107–1150. https://doi.org/10.1039/c0cs00208a
Faustini M, Vayer M, Marmiroli B, Hillmyer M, Amenitsch H, Sinturel C, Grosso D (2010) Bottom-up approach toward titanosilicate mesoporous pillared planar nanochannels for nanofluidic applications. Chem Mater 22:5687–5694. https://doi.org/10.1021/cm101502n
Faustini M, Giraud M, Jones D, Rozière J, Dupont M, Porter TR, Nowak S, Bahri M, Ersen O, Sanchez C (2019) Hierarchically structured ultraporous iridium‐based materials: a novel catalyst architecture for proton exchange membrane water electrolyzers. Adv Energy Mater 9:1802136
Brinker CJ, Lu YF, Sellinger A, Fan HY (1999) Evaporation-induced self-assembly: nanostructures made easy Adv Mater 11:579–585. https://doi.org/10.1002/(sici)1521-4095(199905)11:73.0.co;2-r
Joannopoulos JD, Johnson SG, Winn JN, Meade RD (2008) Photonic crystals molding the flow of light Second edition Introduction. In Photonic crystals: molding the flow of light, 2nd edn, pp 1–5
Yakovlev AV, Milichko VA, Vinogradov VV, Vinogradov AV (2016) Inkjet color printing by interference nanostructures. ACS Nano 10:3078–3086
Gazoni RM, Bellino MG, Fuertes MC, Giménez G, Soler-Illia GJAA, Ricci MLM (2017) Designed nanoparticle–mesoporous multilayer nanocomposites as tunable plasmonic–photonic architectures for electromagnetic field enhancement. J Mater Chem C 5:3445–3455
Checcucci S, Bottein T, Gurioli M, Favre L, Grosso D, Abbarchi M (2019) Multifunctional metasurfaces based on direct nanoimprint of titania sol–gel coatings. Adv Opt Mater 7:1801406
England GT, Russell C, Shirman E, Kay T, Vogel N, Aizenberg J (2017) The optical Janus effect: asymmetric structural color reflection materials. Adv Mater 29:1606876
Banerjee S, Dionysiou DD, Pillai SC (2015) Self-cleaning applications of TiO2 by photo-induced hydrophilicity and photocatalysis. Appl Catal B Environ 176–177:396–428. https://doi.org/10.1016/j.apcatb.2015.03.058
Li R, Faustini M, Boissiere C, Grosso D (2014) Water capillary condensation effect on the photocatalytic activity of porous TiO2 in air. J Phys Chem C 118:17710–17716. https://doi.org/10.1021/jp5046468
Paz Y, Luo Z, Rabenberg L, Heller A (1995) Photooxidative self-cleaning transparent titanium-dioxide films on glass. J Mater Res 10:2842–2848. https://doi.org/10.1557/jmr.1995.2842
Maggos T, Bartzis JG, Liakou M, Gobin C (2007) Photocatalytic degradation of NOx gases using TiO2-containing paint: a real scale study. J Hazard Mater 146:668–673. https://doi.org/10.1016/j.jhazmat.2007.04.079
Ao CH, Lee SC, Yu JZ, Xu JH (2004) Photodegradation of formaldehyde by photocatalyst TiO2: effects on the presences of NO, SO2 and VOCs. Appl Catal B Environ 54:41–50. https://doi.org/10.1016/j.apcatb.2004.06.004
Ao CH, Lee SC, Mak CL, Chan LY (2003) Photodegradation of volatile organic compounds (VOCs) and NO for indoor air purification using TiO2: promotion versus inhibition effect of NO. Appl Catal B Environ 42:119–129. https://doi.org/10.1016/s0926-3373(02)00219-9
Li W, Wu Z, Wang J, Elzatahry AA, Zhao D (2014) A Perspective on mesoporous TiO2 materials. Chem Mater 26:287–298. https://doi.org/10.1021/cm4014859
Yang PD, Zhao DY, Margolese DI, Chmelka BF, Stucky GD (1999) Block copolymer templating syntheses of mesoporous metal oxides with large ordering lengths and semicrystalline framework. Chem Mater 11:2813–2826. https://doi.org/10.1021/cm990185c
Soler-Illia GJAA, Angelome PC, Fuertes MC, Grosso D, Boissiere C (2012) Critical aspects in the production of periodically ordered mesoporous titania thin films. Nanoscale 4:2549–2566. https://doi.org/10.1039/C2NR11817C
Du J, Lai XY, Yang NL, Zhai J, Kisailus D, Su FB, Wang D, Jiang L (2011) Hierarchically ordered macro-mesoporous TiO2-graphene composite films: improved mass transfer, reduced charge recombination, and their enhanced photocatalytic activities. ACS Nano 5:590–596. https://doi.org/10.1021/nn102767d
Ceratti DR, Louis B, Paquez X, Faustini M, Grosso D (2015) A new dip coating method to obtain large-surface coatings with a minimum of solution Adv Mater 27:4958–4962. https://doi.org/10.1002/adma.201502518
Fattakhova-Rohlfing D, Zaleska A, Bein T (2014) Three-dimensional titanium dioxide nanomaterials. Chem Rev 114:9487–9558. https://doi.org/10.1021/cr500201c
Stathatos E, Lianos P, Falaras P, Siokou A (2000) Photocatalytically deposited silver nanoparticles on mesoporous TiO2 films. Langmuir 16:2398–2400. https://doi.org/10.1021/la981783t
Young T (1802) The Bakerian lecture: on the theory of light and colours. Philos Trans R Soc Lond 92:12–48
Kubota H (1950) On the interference color of thin layers on glass surface. J Phys Soc Jpn 5:10–14. https://doi.org/10.1143/JPSJ.5.10
Dong W, Sun Y, Lee CW, Hua W, Lu X, Shi Y, Zhang S, Chen J, Zhao D (2007) Controllable and repeatable synthesis of thermally stable anatase nanocrystal−silica composites with highly ordered hexagonal mesostructures. J Am Chem Soc 129:13894–13904. https://doi.org/10.1021/ja073804o
Allain E, Besson S, Durand C, Moreau M, Gacoin T, Boilot JP (2007) Transparent mesoporous nanocomposite films for self‐cleaning applications. Adv Funct Mater 17:549–554
Guldin S, Kohn P, Stefik M, Song J, Divitini G, Ecarla F, Ducati C, Wiesner U, Steiner U (2013) Self-cleaning antireflective optical coatings. Nano Lett 13:5329–5335. https://doi.org/10.1021/nl402832u
Li R, Boudot M, Boissière C, Grosso D, Faustini M (2017) Suppressing structural colors of photocatalytic optical coatings on glass: the critical role of SiO2. ACS Appl Mater Interfaces 9:14093–14102. https://doi.org/10.1021/acsami.7b02233
Grosso D, Soler-Illia GJdAA, Crepaldi EL, Cagnol F, Sinturel C, Bourgeois A, Brunet-Bruneau A, Amenitsch H, Albouy PA, Sanchez C (2003) Highly porous TiO2 anatase optical thin films with cubic mesostructure stabilized at 700 °C. Chem Mater 15:4562–4570. https://doi.org/10.1021/cm031060h
Faustini M, Grenier A, Naudin G, Li R, Grosso D (2015) Ultraporous nanocrystalline TiO2-based films: synthesis, patterning and application as anti-reflective, self-cleaning, superhydrophilic coatings. Nanoscale 7:19419–19425. https://doi.org/10.1039/C5NR06466J
Faustini M, Nicole L, Boissiere C, Innocenzi P, Sanchez C, Grosso D (2010) Hydrophobic, antireflective, self-cleaning, and antifogging sol–gel coatings: an example of multifunctional nanostructured materials for photovoltaic cells. Chem Mater 22:4406–4413. https://doi.org/10.1021/cm100937e
C.J. Brinker AJH, Schunk PR, Frye GC, Ashley CS (1992) Review of sol–gel thin film formation. J Non-Cryst Solids 147:13
Deegan RD, Bakajin O, Dupont TF, Huber G, Nagel SR, Witten TA (1997) Capillary flow as the cause of ring stains from dried liquid drops. Nature 389:827–829
Bindini E, Naudin G, Faustini M, Grosso D, Boissière C (2017) Critical role of the atmosphere in dip-coating process. J Phys Chem C 121:14572–14580. https://doi.org/10.1021/acs.jpcc.7b02530
Faustini M, Grosso D (2016) Self-assembled inorganic nanopatterns (INPs) made by sol–gel dip-coating: Applications in nanotechnology and nanofabrication. Comptes Rendus Chim 19:248–265. https://doi.org/10.1016/j.crci.2015.05.011
Faustini M, Capobianchi A, Varvaro G, Grosso D (2012) Highly controlled dip-coating deposition of fct FePt nanoparticles from layered salt precursor into nanostructured thin films: an easy way to tune magnetic and optical properties. Chem Mater 24:1072–1079. https://doi.org/10.1021/cm2033492
Ceratti DR, Louis B, Paquez X, Faustini M, Grosso D (2015) A new dip coating method to obtain large-surface coatings with a minimum of solution. Adv Mater 27:4958–4962. https://doi.org/10.1002/adma.201502518
Faustini M, Ceratti DR, Louis B, Boudot M, Albouy P-A, Boissiere C, Grosso D (2014) Engineering functionality gradients by dip coating process in acceleration mode. Acs Appl Mater Interfaces 6:17102–17110. https://doi.org/10.1021/am504770x
Shekhah O, Liu J, Fischer RA, Woll C (2011) MOF thin films: existing and future applications. Chem Soc Rev 40:1081–1106. https://doi.org/10.1039/c0cs00147c
Demessence A, Boissiere C, Grosso D, Horcajada P, Serre C, Ferey G, Soler-Illia G, Sanchez C (2010) Adsorption properties in high optical quality nanoZIF-8 thin films with tunable thickness. J Mater Chem 20:7676–7681. https://doi.org/10.1039/c0jm00500b
Demessence A, Horcajada P, Serre C, Boissiere C, Grosso D, Sanchez C, Ferey G (2009) Elaboration and properties of hierarchically structured optical thin films of MIL-101(Cr). Chem Commun (46):7149–7151. https://doi.org/10.1039/b915011k
Lu G, Hupp JT (2010) Metal–organic frameworks as sensors: a ZIF-8 based Fabry–Pérot device as a selective sensor for chemical vapors and gases. J Am Chem Soc 132:7832–7833. https://doi.org/10.1021/ja101415b
Hinterholzinger FM, Ranft A, Feckl JM, Ruhle B, Bein T, Lotsch BV (2012) One-dimensional metal-organic framework photonic crystals used as platforms for vapor sorption. J Mater Chem 22:10356–10362. https://doi.org/10.1039/C2JM15685G
Hu Z, Tao C-a, Wang F, Zou X, Wang J (2015) Flexible metal-organic framework-based one-dimensional photonic crystals. J Mater Chem C 3:211–216. https://doi.org/10.1039/C4TC01501K
Ranft A, Niekiel F, Pavlichenko I, Stock N, Lotsch BV (2015) Tandem MOF-based photonic crystals for enhanced analyte-specific optical detection. Chem Mater 27:1961–1970. https://doi.org/10.1021/cm503640c
Lu G, Farha OK, Kreno LE, Schoenecker PM, Walton KS, Van Duyne RP, Hupp JT(2011) Fabrication of metal-organic framework-containing silica-colloidal crystals for vapor sensing Adv Mater 23:4449–4452. https://doi.org/10.1002/adma.201102116
Faustini M, Cattoni A, Peron J, Boissière C, Ebrard P, Malchère A, Steyer P, Grosso D (2018) Dynamic shaping of femtoliter dew droplets. ACS Nano 12:3243–3252. https://doi.org/10.1021/acsnano.7b07699
Bottein T, Dalstein O, Putero M, Cattoni A, Faustini M, Abbarchi M, Grosso D (2018) Environment-controlled sol–gel soft-NIL processing for optimized titania, alumina, silica and yttria-zirconia imprinting at sub-micron dimensions. Nanoscale 10:1420–1431. https://doi.org/10.1039/C7NR07491C
Echeverría JC, Faustini M, Garrido JJ (2016) Effects of the porous texture and surface chemistry of silica xerogels on the sensitivity of fiber-optic sensors toward VOCs. Sens Actuators B Chem 222:1166–1174. https://doi.org/10.1016/j.snb.2015.08.010
Boudot M, Ceratti DR, Faustini M, Boissiere C, Grosso D (2014) Alcohol-assisted water condensation and stabilization into hydrophobic mesoporosity. J Phys Chem C 118:23907–23917. https://doi.org/10.1021/jp508372d
Boudot M, Cattoni A, Grosso D, Faustini M (2016) Ethanol–water co-condensation into hydrophobic mesoporous thin films: example of a photonic ethanol vapor sensor in humid environment. J Sol–Gel Sci Technol 1–10. https://doi.org/10.1007/s10971-016-4084-2
Dalstein O, Gkaniatsou E, Sicard C, Sel O, Perrot H, Serre C, Boissière C, Faustini M (2017) Evaporation-directed crack-patterning of metal–organic framework colloidal films and their application as photonic sensors. Angew Chem Int Ed 56:14011–14015. https://doi.org/10.1002/anie.201706745
Schueller OJA, Duffy DC, Rogers JA, Brittain ST, Whitesides GM (1999) Reconfigurable diffraction gratings based on elastomeric microfluidic devices. Sens Actuators A Phys 78:149–159
Grzybowski BA, Qin D, Whitesides GM (1999) Beam redirection and frequency filtering with transparent elastomeric diffractive elements. Appl Opt 38:2997–3002
Chen H-L, Cattoni A, De Lépinau R, Walker AW, Höhn O, Lackner D, Siefer G, Faustini M, Vandamme N, Goffard J (2019) A 19.9%-efficient ultrathin solar cell based on a 205-nm-thick GaAs absorber and a silver nanostructured back mirror. Nat Energy 4:761–767
Odziomek M, Bahri M, Boissiere C, Sanchez C, Lassalle-Kaiser B, Zitolo A, Ersen O, Nowak S, Tard C, Giraud M, Faustini M, Peron J (2020) Aerosol synthesis of thermally stable porous noble metals and alloys by using bi-functional templates. Mater Horiz. https://doi.org/10.1039/C9MH01408J
Acknowledgements
Sorbonne Université, CNRS and Collège de France are acknowledged. MF gratefully acknowledges all the co-authors of the works described in this article. MF acknowledges the funding from the European Research Council under European Union’s Horizon 2020 Programme (Grant Agreement no. 803220, TEMPORE).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The author declares that he has no conflict of interest.
Additional information
Publisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Faustini, M. Sol–gel engineering to tune structural colours. J Sol-Gel Sci Technol 95, 504–516 (2020). https://doi.org/10.1007/s10971-020-05319-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10971-020-05319-7