Abstract
Fiber needle felt–silica aerogel composite was successfully prepared by via sol–gel process based on water glass. The thermal conductivity show V-type variation tendency with the increase of water to Si. Thermogravimetric analysis-differential scanning calorimetry analysis revealed that the thermal stability was up to approximately 390.58 °C. It has been found that the fire hazard of the composites decreased with the increased ratio of water to Si according to the cone calorimeter test, which can be characterized by peak heat release rate, fire performance index, and fire growth rate index. The fiber needle felt/aerogels present greatly improved compressive and flexural strength (elastic modulus: 0.1–0.97 MPa; flexural modulus: 0.33–0.66 MPa) while keeping inherent properties of pure silica aerogel: low bulk density (0.166 g/cm3), low thermal conductivity of 0.0236 W/m·K, and high specific surface area (1091.62 m2/g). As a result, the as-prepared composite shows a great potential to be applied in the thermal insulation field.
Highlights
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Fiber needle felt reinforced silica aerogel were obtained under ambient pressure.
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The water glass based aerogel show high flexibility & thermal insulation ability.
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The composites' flammable ability were studied through cone calorimeter.
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References
Liu G, Wu Z, Hu M (2012) Energy consumption and management in public buildings in China: an investigation of Chongqing. Energy Procedia 14: 1925-1930
Dai HM, Zhao Q, Lin BQ, He S, Chen XF, Zhang Y, Niu Y, Yin SH (2018) Premixed combustion of low-concentration coal mine methane with water vapor addition in a two-section porous media burner. Fuel 213:72–82
Wan KKW, Li DHW, Liu D, Lam JC (2011) Future trends of building heating and cooling loads and energy consumption in different climates. Build Environ 46:223–234
He S, Huang DM, Bi HJ, Li Z, Yang H, Cheng XD (2015) Synthesis and characterization of silica aerogels dried under ambient pressure bed on water glass. J Non-Cryst Solids 410:58–64
Pierre AC, Rigacci A (2011) SiO2 aerogels. In: Aegerter AM, Leventis N, Koebel MM (Eds) Aerogels handbook. Springer, New York, NY, pp 21–45
Baetens R, Jelle BP, Gustavsen A (2011) Aerogel insulation for building applications: a state-of-the-art review. Energ Build 43:761–769
Katti A, Shimpi N, Roy S, Lu HB, Fabrizio EF, Dass A, Capadona LA, Leventis N (2006) Chemical, physical, and mechanical characterization of isocyanate cross-linked amine-modified silica aerogels. Chem Mater 18:285–296
Leventis N, Sotiriou-Leventis C, Zhang GH, Rawashdeh AMM (2002) Nanoengineering strong silica aerogels. Nano Lett 2:957–960
Capadona LA, Meador MAB, Alunni A, Fabrizio EF, Vassilaras P, Leventis N (2006) Flexible, low-density polymer crosslinked silica aerogels. Polymer (Guildf) 47:5754–5761
Meador MAB, Fabrizio EF, Ilhan F, Dass A, Zhang GH, Vassilaras P, Johnston JC, Leventis N (2005) Cross-linking amine-modified silica aerogels with epoxies: mechanically strong lightweight porous materials. Chem Mater 17:1085–1098
Nguyen BN, Meador MAB, Medoro A, Arendt V, Randall J, McCorkle L, Shonkwiler B (2010) Elastic behavior of methyltrimethoxysilane based aerogels reinforced with tri-isocyanate. ACS Appl Mater Interfaces 2:1430–1443
Karout A, Buisson P, Perrard A, Pierre AC (2005) Shaping and mechanical reinforcement of silica aerogel biocatalysts with ceramic fiber felts. J Sol-Gel Sci Technol 36:163–171
Wang J, Kuhn J, Lu X (1995) Monolithic silica aerogel insulation doped with TiO2 powder and ceramic fibers. J Non-Cryst Solids 186:296–300
Guanming DZLXY (2006) Study on preparation and performance of SiO_2 aerogels composites reinforced by mullite fiber [J]. N Chem Mater 7:021
Kim C-Y, Lee J-K, Kim B-I (2008) Synthesis and pore analysis of aerogel-glass fiber composites by ambient drying method. Colloids Surf A 313:179–182
Yuan B, Ding S, Wang D, Wang G, Li H (2012) Heat insulation properties of silica aerogel/glass fiber composites fabricated by press forming. Mater Lett 75:204–206
Li Z, Gong L, Cheng X, He S, Li C, Zhang H (2016) Flexible silica aerogel composites strengthened with aramid fibers and their thermal behavior. Mater Des 99:349–355
He S, Sun G, Cheng X, Dai H, Chen X (2017) Nanoporous SiO2 grafted aramid fibers with low thermal conductivity. Compos Sci Technol 146:91–98
Chandradass J, Kang S, Bae DS (2008) Synthesis of silica aerogel blanket by ambient drying method using water glass based precursor and glass wool modified by alumina sol. J Non-Cryst Solids 354:4115–4119
Li C, Cheng X, Li Z, Pan Y, Huang Y, Gong L (2017) Mechanical, thermal and flammability properties of glass fiber film/silica aerogel composites. J Non-Cryst Solids 457:52–59
He S, Yang H, Chen X (2017) Facile synthesis of highly porous silica aerogel granules and its burning behavior under radiation. J Sol-Gel Sci Technol 82:407–416
Healy JJ, Degroot JJ, Kestin J (1976) Theory of transient hot-wire method for measuring thermal-conductivity. Phys B & C 82:392–408
Li CC, Cheng XD, Li Z, Pan YL, Huang YJ, Gong LL (2017) Mechanical, thermal and flammability properties of glass fiber film/silica aerogel composites. J Non-Cryst Solids 457:52–59
Wu H, Liao Y, Ding Y, Wang H, Peng C, Yin S (2014) Engineering thermal and mechanical properties of multilayer aligned fiber-reinforced aerogel composites. Heat Transf Eng 35:1061–1070
Bentz DP (2007) Transient plane source measurements of the thermal properties of hydrating cement pastes. Mater Struct 40:1073–1080
Zhang YH, Weidenkaff A, Reller A (2002) Mesoporous structure and phase transition of nanocrystalline TiO2. Mater Lett 54:375–381
Deng ZS, Wang J, Wu AM, Shen J, Zhou B (1998) High strength SiO2 aerogel insulation. J Non-Cryst Solids 225:101–104
He S, Li Z, Shi X, Yang H, Gong L, Cheng X (2015) Rapid synthesis of sodium silicate based hydrophobic silica aerogel granules with large surface area. Adv Powder Technol 26:537–541
Li Z, Cheng X, He S, Shi X, Yang H (2015) Characteristics of ambient-pressure-dried aerogels synthesized via different surface modification methods. J Sol-Gel Sci Technol 76:138–149
Li L, Yalcin B, Nguyen BN, Meador MAB, Cakmak M (2009) Flexible nanofiber-reinforced aerogel (Xerogel) synthesis, manufacture, and characterization. ACS Appl Mater Interfaces 1:2491–2501
Pan Y, He S, Cheng X, Li Z, Li C, Huang Y, Gong L (2017) A fast synthesis of silica aerogel powders-based on water glass via ambient drying. J Sol-Gel Sci Technol 82:594–601
Pan Y, He S, Gong L, Cheng X, Li C, Li Z, Liu Z, Zhang H (2017) Low thermal-conductivity and high thermal stable silica aerogel based on MTMS/water-glass co-precursor prepared by freeze drying. Mater Des 113:246–253
He S, Chen X (2017) Flexible silica aerogel based on methyltrimethoxysilane with improved mechanical property. J Non-Cryst Solids 463:6–11
Shi F, Wang L, Liu J (2006) Synthesis and characterization of silica aerogels by a novel fast ambient pressure drying process. Mater Lett 60:3718–3722
Li Z, Cheng X, Shi L, He S, Gong L, Li C, Zhang H (2016) Flammability and oxidation kinetics of hydrophobic silica aerogels. J Hazard Mater 320:350–358
Petrella R (1994) The assessment of full-scale fire hazards from cone calorimeter data. J Fire Sci 12:14–43
Wu G, Yu Y, Cheng X, Zhang Y (2011) Preparation and surface modification mechanism of silica aerogels via ambient pressure drying. Mater Chem Phys 129:308–314
Coffman BE, Fesmire JE, White S, Gould G, Augustynowicz S (2010) Aerogel blanket insulation materials for cryogenic applications. AIP Conference Proceeding 1218: 913–920.
H Wu, Y Chen, Q Chen, Y Ding, X Zhou, H Gao (2013) Synthesis of flexible aerogel composites reinforced with electrospun nanofibers and microparticles for thermal insulation. J Nanomater 2013: 1-8.
Shi D, Sun Y, Feng J, Yang X, Han S, Mi C, Jiang Y, Qi H (2013) Experimental investigation on high temperature anisotropic compression properties of ceramic-fiber-reinforced SiO2 aerogel. Mater Sci Eng A 585:25–31
Fu J, Wang S, He C, Lu Z, Huang J, Chen Z (2016) Facilitated fabrication of high strength silica aerogels using cellulose nanofibrils as scaffold. Carbohydr Polym 147:89–96
Acknowledgements
This research was financially supported by the National Key Research and Development Program of China (2017YFC0804900 and 2017YFC0804907), the Open Project Program of State Key Laboratory of Fire Science (HZ2017-KF12), and the Natural Science Foundation of China (No. 51706165).
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Huang, Y., He, S., Chen, G. et al. Mechanical reinforced fiber needle felt/silica aerogel composite with its flammability. J Sol-Gel Sci Technol 88, 129–140 (2018). https://doi.org/10.1007/s10971-018-4796-6
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DOI: https://doi.org/10.1007/s10971-018-4796-6