Journal of Sol-Gel Science and Technology

, Volume 86, Issue 1, pp 34–41 | Cite as

Some aspects of estimation of extraction selectivity under the conditions of competitive sorption on modified silica gels

  • Dzhamilya N. Konshina
  • Zaual A. Temerdashev
  • Valeriy V. Konshin
Original Paper: Characterization methods of sol-gel and hybrid materials
  • 38 Downloads

Abstract

Systematic studies of silica gels with covalently immobilized thiosemicarbazide and formazan groups under the conditions of competitive sorption from multicomponent systems were conducted. A methodological approach to determine the selectivity of the modified sorption material with regard to Cu(II), Ni(II), Co(II), Cd(II), and Zn(II) was proposed. Solid-phase extraction in equilibrium conditions of Cu(II), Zn(II), Co(II), Cd(II), and Ni(II) on a silica gel with covalently immobilized thiosemicarbazide and formazan groups in the conditions of competitive sorption was studied. The possibility to use the pseudo-second-order kinetic equation for assessment of mutual influence at competitive sorption has been shown. We found that sorption from multicomponent solutions proceeds as a non-additive process under the conditions of an excess of functional groups.

Keywords

Adsobtion capacity Multicomponent sorbtion Silica gel Surface modification Thiosemicarbazide Formazan 

Notes

Acknowledgements

This publication was financially supported by the Russian Ministry of Education and Science (project no. 4.4892.2017/8.9). This work was accomplished with the use of the scientific equipment of the Centre of Collective Employment “Ecoanalytical Centre”, Kuban State University (RFMEFI59317Х0008).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

References

  1. 1.
    Pujari SP, Scheres L, Marcelis AT, Zuilhof H (2014) Covalent surface modification of oxide surfaces. Angew Chem Int Ed Engl 53:2–36.  https://doi.org/10.1002/anie.201306709 CrossRefGoogle Scholar
  2. 2.
    Terada K (1991) Preconcentration of trace elements by sorption. Anal Sci 7:187–198.  https://doi.org/10.2116/analsci.7.187 CrossRefGoogle Scholar
  3. 3.
    Biernat Jan F, Konieczka P (1994) Complexing and chelating agents immobilized on silica gel and related materials and their application for sorption of inorganic species. Sep Purif Methods 23:77–348.  https://doi.org/10.1080/03602549408006624 CrossRefGoogle Scholar
  4. 4.
    Garg BS, Sharma RK, Bhojak N, Mittal S (1999) Chelating resins and their application in the analysis of trace metal ions. Microchem J 61:94–114.  https://doi.org/10.1006/mchj.1998.1681 CrossRefGoogle Scholar
  5. 5.
    Price Peter M, James HC, Duncan JM (2000) Modified silicas for clean technology. J Chem Soc Dalton Trans: 101–110.  https://doi.org/10.1039/A905457J
  6. 6.
    Voronkov MG, Vlasova NN, Pozhidaev YuN (2000) Organosilicon ion-exchange and complexing adsorbents. Appl Organomet Chem 14:287–303.  https://doi.org/10.1002/pat.743 CrossRefGoogle Scholar
  7. 7.
    Sharma RK, Mittal S, Koe M (2003) Analysis of trace amounts of metal ions using silica-based chelating resins: a green analytical method. Crit Rev Anal Chem 33:183–197.  https://doi.org/10.1080/713609163 CrossRefGoogle Scholar
  8. 8.
    Jal PK, Patel S, Mishra BK (2004) Chemical modification of silica surface by immobilization of functional groups for extractive concentration of metal ions. Talanta 62:1005–1028.  https://doi.org/10.1016/j.talanta.2003.10.028 CrossRefGoogle Scholar
  9. 9.
    Zougagh M, Cano Pavon JM, Garcia de Torres A (2005) Chelating sorbents based on silica gel and their application in atomic spectrometry. Anal Bioanal Chem 381:1103–1113.  https://doi.org/10.1007/s00216-004-3022-2 CrossRefGoogle Scholar
  10. 10.
    Kara D, Fisher A (2012) Modified silica gels and their use for the preconcentration of trace elements. Sep Purif Rev 41:267–317.  https://doi.org/10.1080/15422119.2011.608765 CrossRefGoogle Scholar
  11. 11.
    Sierra I, Perez-Quintanilla Dn (2013) Heavy metal complexation on hybrid mesoporous silicas: an approach to analytical applications. Chem Soc Rev 42:3792–3807.  https://doi.org/10.1039/C2CS35221D CrossRefGoogle Scholar
  12. 12.
    Ding C, Cheng W, Wang X, Wu ZY, Sun Y, Chen C, Wang X, Yu SH (2016) Competitive sorption of Pb(II), Cu(II) and Ni(II) on carbonaceous nanofibers: a spectroscopic and modeling approach. J Hazard Mater 313:253–261.  https://doi.org/10.1016/j.jhazmat.2016.04.002 CrossRefGoogle Scholar
  13. 13.
    Selim HM, Zhang H (2013) Modeling approaches of competitive sorption and transport of trace metals and metalloids in soils: a review. J Environ Qual 42(3):640–653.  https://doi.org/10.2134/jeq2012.0323 CrossRefGoogle Scholar
  14. 14.
    Shaheen SM, Tsadilas CD, Rinklebe J (2013) A review of the distribution coefficients of trace elements in soils: influence of sorption system, element characteristics, and soil colloidal properties. Adv Colloid Interface Sci 201-202:43–56.  https://doi.org/10.1016/j.cis.2013.10.005 CrossRefGoogle Scholar
  15. 15.
    Covelo EF, Vega FA, Andrade ML (2006) Competitive sorption and desorption of heavy metals by individual soil components. J Hazard Mater 140(1-2):308–315.  https://doi.org/10.1016/j.jhazmat.2006.09.018 CrossRefGoogle Scholar
  16. 16.
    Xiao B, Thomas KM (2004) Competitive adsorption of aqueous metal ions on an oxidized nanoporous activated carbon. Langmuir 20(11):4566–4578.  https://doi.org/10.1021/la049712j CrossRefGoogle Scholar
  17. 17.
    Cheng W, Ding C, Wang X, Wu Z, Sun Y, Yu S, Hayat T, Wang X (2016) Competitive sorption of As(V) and Cr(VI) on carbonaceous nanofibers. Chem Eng J 293:311–318.  https://doi.org/10.1016/j.cej.2016.02.073 CrossRefGoogle Scholar
  18. 18.
    Konshina DN, Furina (Danilova) AV, Temerdashev ZA, Gurinov AA, Konshin VV (2014) Immobilization of guanazyl functional groups on silica for solid-phase extraction of metal ions. Anal Lett 47:2665–2681.  https://doi.org/10.1080/00032719.2014.917421 CrossRefGoogle Scholar
  19. 19.
    Konshina DN, Open’ko VV, Temerdashev ZA, Gurinov AA, Konshin VV (2016) Synthesis of novel silicagel-supported thiosemicarbazide and its properties for solid phase extraction of mercury. Sep Sci Technol 51:1103–1111.  https://doi.org/10.1080/01496395.2016.1143005 CrossRefGoogle Scholar
  20. 20.
    Konshina DN, Danilova AV, Temerdashev ZA, Bolotin SN, Gurinov AA, Konshin VV (2016) Preparation and properties of silica gel with immobilized formazan group. Russ J Appl Chem 89:476–483.  https://doi.org/10.1134/S107042721604011X CrossRefGoogle Scholar
  21. 21.
    Sergio P (2006) A note on Fisher’s correlation coefficient. Appl Math Lett 19:499–502.  https://doi.org/10.1016/0021-9797(74)90252-5 CrossRefGoogle Scholar
  22. 22.
    Filip E, Nadejde C, Creanga D, Dorohoi D (2009) Spectral investigation of triphenylformazan derivatives in ultra violet light. Rom J Phys 54:649–657Google Scholar
  23. 23.
    João P, Vareda LD (2017) Functionalized silica xerogels for dsorption of heavy metals from groundwater and soils. J Sol Gel Sci Technol 84:400–408.  https://doi.org/10.1007/s10971-017-4326-y CrossRefGoogle Scholar
  24. 24.
    Giles CH, Smith D, Huitson A (1974) A general treatment and classification of the solute adsorption isotherm. I. Theoretical. J Colloid Interface Sci 47:755–765.  https://doi.org/10.1016/0021-9797(74)90252-5 CrossRefGoogle Scholar
  25. 25.
    Ho YS, McKay G (2000) The kinetics of sorption of divalent metal ions onto sphagnum moss peat. Water Res 34:735–742.  https://doi.org/10.1016/S0043-1354(99)00232-8 CrossRefGoogle Scholar
  26. 26.
    Fu L, Zhang L, Wang S, Zhang G, Peng J (2017) Selective recovery of Au(III) from aqueous solutions by nano-silica grafted with 4-(aminomethyl) pyridine. J Sol Gel Sci Technol 83:467–477CrossRefGoogle Scholar

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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Department of Chemistry and High TechnologiesKuban State UniversityKrasnodarRussia

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