Journal of Sol-Gel Science and Technology

, Volume 81, Issue 2, pp 611–622 | Cite as

Preparation of fluoroalkyl end-capped vinyltrimethoxysilane oligomeric silica/poly(tetrafluoroethylene) nanocomposites possessing a superoleophilic/superhydrophobic characteristic: application to the separation of oil and water

  • Jun-ichi Suzuki
  • Yutaro Takegahara
  • Yuri Oikawa
  • Masaya Chiba
  • Satoshi Yamada
  • Masashi Sugiya
  • Hideo Sawada
Original Paper: Sol-gel and hybrid materials with surface modification for applications

Abstract

Fluoroalkyl end-capped vinyltrimethoxysilane oligomer [R F-(CH2CHSi(OMe)3) n -R F; R F = CF(CF3)OC3F7, n = 2, 3: R F-(VM) n -R F oligomer] can undergo the sol–gel reaction in the presence of poly(tetrafluoroethylene) fine particles under alkaline conditions to afford the corresponding fluorinated oligomeric silica/poly(tetrafluoroethylene) nanocomposites [R F-(VM-SiO3/2) n -R F/poly(tetrafluoroethylene) nanocomposites]. Interestingly, the modified glass, poly(tetrafluoroethylene) sheet and filter paper surfaces treated with the obtained nanocomposites were found to exhibit a superoleophilic/superhydrophobic characteristic, although the original poly(tetrafluoroethylene) sheet and the modified glass surface treated with the R F-(VM) n -R F oligomeric silica nanoparticles [R F-(VM-SiO3/2) n -R F] can provide the usual oleophobic/hydrophobic and oleophobic/superhydrophobic properties, respectively. The modified filter paper was applied to the separation membrane for the mixture of oil/water. In addition, the fluorinated poly(tetrafluoroethylene) nanocomposite white-colored powders thus obtained were applied to the packing material for the column chromatography to separate the mixture of oil/water and water-in-oil emulsions. We have also studied on the reusability of the present nanocomposite particle powders as the packing material for the separation of not only the mixture of oil/water but also the water-in-oil emulsions, and the colorless oil was quantitatively isolated under similar conditions even after the use of the packing materials five times.

Graphical Abstract

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Keywords

Fluorinated oligomer Silica nanocomposites PTFE particle Superoleophilicity Superhydrophobicity Separation of oil and water 

Notes

Acknowledgments

This work was partially supported by a Grant-in-Aid for Scientific Research (KAKENHI (C) No.16K05891) from the Japan Society for the Promotion of Science (JSPS).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no competing interests.

Supplementary material

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Supplementary Movie S1
10971_2016_4209_MOESM2_ESM.mov (6.9 mb)
Supplementary Movie S2
10971_2016_4209_MOESM3_ESM.docx (278 kb)
Supplementary Information

References

  1. 1.
    Drobny JG (2014) Technology of fluoropolymers. CRC Press: Boca Raton, FL, USAGoogle Scholar
  2. 2.
    Ebnesajjad S (2013) Introduction to fluoropolymers—materials, technology and applications. Elsevier: Waltham, MA, USAGoogle Scholar
  3. 3.
    Erbil HY, Demirel AL, Avci Y, Mert O (2003) Science 299:1377–1380CrossRefGoogle Scholar
  4. 4.
    Zhang H, Hu HY, Ye WC, Zhou F (2011) J Appl Polym Sci 122:3145–3151CrossRefGoogle Scholar
  5. 5.
    Aderikha VN, Shapovalov VA (2011) Wear 271:970–976CrossRefGoogle Scholar
  6. 6.
    Vail JR, Krick BA, Marchman KR, Gregory Sawyer W (2011) Wear 270:737–741CrossRefGoogle Scholar
  7. 7.
    Kannarpady GK, Sharma R, Liu B, Trigwell S, Ryerson C, Biris AS (2010) Appl Surf Sci 256:1679–1682CrossRefGoogle Scholar
  8. 8.
    Guo SC, Wu F, Fang L, Mao CY, Dou YY (2015) Mater Technol 30:43–49CrossRefGoogle Scholar
  9. 9.
    Nakajima A, Hashimoto K, Watanabe T (2001) Monatsh Chem 132:31–41CrossRefGoogle Scholar
  10. 10.
    Kulinich SA, Farzaneh M (2004) Appl Surf Sci 230:232–240CrossRefGoogle Scholar
  11. 11.
    Zhou Y, Li M, Zhong X, Zhu Z, Deng P, Liu H (2015) Ceram Int 41:5341–5347CrossRefGoogle Scholar
  12. 12.
    Jucius D, Grigaliunas V, Mikolajunas M, Guobiene A, Kopustinskas V, Gudonyte A, Narmontas P (2011) Appl Surf Sci 257:2353–2360CrossRefGoogle Scholar
  13. 13.
    Gong D, Long J, Fan P, Jiang D, Zhang H, Zhong M (2015) Appl Surf Sci 331:437–443CrossRefGoogle Scholar
  14. 14.
    Bayat A, Ebrahimi M, Nourmohammadi A, Moshfegh AZ (2015) Appl Surf Sci 341:92–99CrossRefGoogle Scholar
  15. 15.
    Iacovetta D, Tam J, Erb U (2015) Surf Coat Technol 279:134–141CrossRefGoogle Scholar
  16. 16.
    Kim D, Hwang W, Park HC, Lee K-H (2008) Curr Appl Phys 8:770–773CrossRefGoogle Scholar
  17. 17.
    Lau KKS, Bico J, Teo KBK, Chhowalla M, Amaratunga GAJ, Milne WL, Mackiniey GH, Gleason KK (2003) Nano Lett 3:1701–1705CrossRefGoogle Scholar
  18. 18.
    Jiang H, Chen L, Chai S, Yao X, Chen F, Fu Q (2014) Compos Sci Technol 103:28–35CrossRefGoogle Scholar
  19. 19.
    Barshilia HC, Gupta N (2014) Vacuum 99:42–48CrossRefGoogle Scholar
  20. 20.
    Wang J-M, Wang L-D, Feng L (2011) J Appl Polym Sci 120:524–529CrossRefGoogle Scholar
  21. 21.
    Milionis A, Martiradonna L, Anyfantis GC, Cozzoli PD, Bayer IS, Fragouli D, Athanassiou A (2013) Colloid Polym Sci 291:401–407CrossRefGoogle Scholar
  22. 22.
    Wang S, Li Y, Fei X, Sun M, Zhang C, Li Y, Yang Q, Hong X (2011) J Colloid Interface Sci 359:380–388CrossRefGoogle Scholar
  23. 23.
    Chen X, Gong Y, Li D, Li H (2016) Colloids Surf A 492:19–25CrossRefGoogle Scholar
  24. 24.
    Chen X, Gong Y, Suo X, Huang J, Liu Y, Li H (2015) Appl Surf Sci 356:639–644CrossRefGoogle Scholar
  25. 25.
    Wang H, Chen E, Jia X, Liang L, Wang Q (2015) Appl Surf Sci 349:724–7432CrossRefGoogle Scholar
  26. 26.
    Wang H, Yan L, Gao D, Liu D, Wang C, Sun L, Zhu Y (2014) Wear 319:62–68CrossRefGoogle Scholar
  27. 27.
    Wang K, Hu N-X, Xu G, Q Y (2011) Carbon 49:1769–1774CrossRefGoogle Scholar
  28. 28.
    Su D, Huamg CY, Hu Y, Jiang Q, Zhang L, Zhu Y (2011) Appl Surf Sci 258:928–934CrossRefGoogle Scholar
  29. 29.
    Latthe SS, Terashima C, Nakata K, Sakai M, Fujishima A (2014) J Mater Chem A 2:5548–5553CrossRefGoogle Scholar
  30. 30.
    Hou W, Wang Q (2009) J Colloid Interface Sci 333:400–403CrossRefGoogle Scholar
  31. 31.
    Sawada H (1996) Chem Rev 96:1779–1808CrossRefGoogle Scholar
  32. 32.
    Sawada H (2007) Prog Polym Sci 32:509–533CrossRefGoogle Scholar
  33. 33.
    Sawada H (2012) Polym Chem 3:46–65CrossRefGoogle Scholar
  34. 34.
    Sawada H (2003) J Fluorine Chem 121:111–130CrossRefGoogle Scholar
  35. 35.
    Sawada H, Nakayama M (1991) J Chem Soc Chem Commun 677–678Google Scholar
  36. 36.
    Sawada H, Suzuki T, Takashima H, Takishita K (2008) Colloid Polym Sci 286:1569–1574CrossRefGoogle Scholar
  37. 37.
    Goto Y, Takashima H, Takishita K, Sawada H (2011) J Colloid Interface Sci 362:375–381CrossRefGoogle Scholar
  38. 38.
    Si Y, Guo Z (2015) Chem Lett 44:874–883CrossRefGoogle Scholar
  39. 39.
    Liu K, Tian Y, Jiang L (2013) Prog Mater Sci 58:503–564CrossRefGoogle Scholar
  40. 40.
    Darmanin T, Guittard F (2014) Prog Polym Sci 39:656–682CrossRefGoogle Scholar
  41. 41.
    Celia E, Darmanin T, de Givenchy ET, Amigoni S, Guittard F (2013) J Colloid Interface Sci 402:1–18CrossRefGoogle Scholar
  42. 42.
    Li J, Wan H, Ye Y, Zhou H, Chen J (2012) Appl Surf Sci 261:470–472CrossRefGoogle Scholar
  43. 43.
    Zhang M, Wang C, Wang S, Shi Y, Li J (2012) Appl Surf Sci 261:764–769CrossRefGoogle Scholar
  44. 44.
    Zhang M, Wang C, Wang S, Shi Y, Li J (2013) Carbohydr Polym 97:59–64CrossRefGoogle Scholar
  45. 45.
    Arbatan T, Zhang L, Fang X-Y, Shen W (2012) Chem Eng J 210:74–79CrossRefGoogle Scholar
  46. 46.
    Kota AK, Kwon G, Choi W, Mabry JM, Tuteja A (2012) Nat Commun 3:1025–1032CrossRefGoogle Scholar
  47. 47.
    Parak S, Lee ES, Sulaiman WRW (2015) J Ind Eng Chem 21:1239–1245CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  • Jun-ichi Suzuki
    • 1
    • 2
  • Yutaro Takegahara
    • 1
  • Yuri Oikawa
    • 1
  • Masaya Chiba
    • 1
  • Satoshi Yamada
    • 3
  • Masashi Sugiya
    • 3
  • Hideo Sawada
    • 1
  1. 1.Department of Frontier Materials Chemistry, Graduate School of Science and TechnologyHirosaki UniversityHirosakiJapan
  2. 2.Kankyo KogakuHirosakiJapan
  3. 3.Research and Development DivisionNippon Chemical Industrial Co., Ltd.TokyoJapan

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