Abstract
Nanocrystalline ceria–yttria co stabilized zirconia (CYSZ) powder was successfully synthesized by the Pechini complex route. The obtained powder was tetragonal ZrO2. Fourier transform infrared spectroscopy was employed to evaluate the bonding characteristics of the obtained gel. Thermo gravimetric analysis together with differential scanning calorimetry was used to investigate the variations of dried gel properties with temperature and to identify the appropriate heating process. The effect of heat treatment procedure on the purity and crystallographic structure of the final product was studied by the use of X-ray diffraction. Furthermore, Raman spectra were recorded at room temperature to find out about possible Raman modes and to understand the structure of CYSZ nanoparticles. The changes in morphology and the size distribution were studied by field emission scanning electron microscopy and transmission electron microscopy. The CYSZ powder contained primary particles of 25 nm size with a uniform distribution. Thermal conductivity of nanostructured CYSZ measured by laser flash technique, found to be lower than conventional counterpart.
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References
Cao X, Vassen R, Stoever D (2004) Ceramic materials for thermal barrier coatings. J Eur Ceram Soc 24(1):1–10
Reardon J, Dorfman M (1987) Advanced thermal barrier coating systems. J Mater Energy Syst 8(4):414–419
Di Girolamo G, Blasi C, Schioppa M, Tapfer L (2010) Structure and thermal properties of heat treated plasma sprayed ceria–yttria co-stabilized zirconia coatings. Ceram Int 36(3):961–968
Pawlowski L (2008) The science and engineering of thermal spray coatings. Wiley, Hoboken
Hannink RH, Kelly PM, Muddle BC (2000) Transformation toughening in zirconia-containing ceramics. J Am Ceram Soc 83(3):461–487
Viazzi C, Bonino J-P, Ansart F, Barnabé A (2008) Structural study of metastable tetragonal YSZ powders produced via a sol–gel route. J Alloy Compd 452(2):377–383
Harmsworth P, Stevens R (1991) Microstructure and phase composition of ZrO2–CeO2 thermal barrier coatings. J Mater Sci 26(15):3991–3995
Taylor R, Brandon J, Morrell P (1992) Microstructure, composition and property relationships of plasma-sprayed thermal barrier coatings. Surf Coat Technol 50(2):141–149
Ahmadi-Pidani R, Shoja-Razavi R, Mozafarinia R, Jamali H (2012) Evaluation of hot corrosion behavior of plasma sprayed ceria and yttria stabilized zirconia thermal barrier coatings in the presence of Na2SO4 + V2O5 molten salt. Ceram Int 38(8):6613–6620
Liu LY, Shankar R, Howard P (2010) High sintering resistance of a novel thermal barrier coating. Surf Coat Technol 204(20):3154–3160
Jamali H, Mozafarinia R, Shoja Razavi R, Ahmadi-Pidani R, Reza Loghman-Estarki M (2012) Fabrication and evaluation of plasma-sprayed nanostructured and conventional YSZ thermal barrier coatings. Curr Nanosci 8(3):402–409
Jamali H, Mozafarinia R, Shoja-Razavi R, Ahmadi-Pidani R (2014) Comparison of hot corrosion behaviors of plasma-sprayed nanostructured and conventional YSZ thermal barrier coatings exposure to molten vanadium pentoxide and sodium sulfate. J Eur Ceram Soc 34(2):485–492
Jamali H, Mozafarinia R, Shoja Razavi R, Ahmadi-Pidani R (2012) Comparison of thermal shock resistances of plasma-sprayed nanostructured and conventional yttria stabilized zirconia thermal barrier coatings. Ceram Int 38(8):6705–6712
Racek O, Berndt CC, Guru D, Heberlein J (2006) Nanostructured and conventional YSZ coatings deposited using APS and TTPR techniques. Surf Coat Technol 201(1):338–346
Gong W, Sha C, Sun D, Wang W (2006) Microstructures and thermal insulation capability of plasma-sprayed nanostructured ceria stabilized zirconia coatings. Surf Coat Technol 201(6):3109–3115
Muccillo E, Avila D (1999) Synthesis and characterization of submicron zirconia–12 mol% ceria ceramics. Ceram Int 25(4):345–351
Potdar H, Deshpande S, Deshpande A, Gokhale S, Date S, Khollam Y, Patil A (2002) Preparation of ceria–zirconia (Ce0.75Zr0.25O2) powders by microwave–hydrothermal (MH) route. Mater Chem Phys 74(3):306–312
Weng X, Perston B, Wang XZ, Abrahams I, Lin T, Yang S, Evans JR, Morgan DJ, Carley AF, Bowker M (2009) Synthesis and characterization of doped nano-sized ceria–zirconia solid solutions. Appl Catal B 90(3):405–415
Sharma S, Gokhale N, Dayal R, Lal R (2002) Synthesis, microstructure and mechanical properties of ceria stabilized tetragonal zirconia prepared by spray drying technique. Bull Mater Sci 25(1):15–20
Settu T, Gobinathan R (1996) Synthesis and characterization of Y2O3–ZrO2 and Y2O3–CeO2–ZrO2 precursor powders. J Eur Ceram Soc 16(12):1309–1318
Suresh Kumar K, Mathews T (2005) Sol–gel synthesis and microwave assisted sintering of zirconia–ceria solid solution. J Alloy Compd 391(1):177–180
Quinelato A, Longo E, Leite E, Bernardi M, Varela J (2001) Synthesis and sintering of ZrO2–CeO2 powder by use of polymeric precursor based on Pechini process. J Mater Sci 36(15):3825–3830
Tu H, Liu X, Yu Q (2011) Synthesis and characterization of scandia ceria stabilized zirconia powders prepared by polymeric precursor method for integration into anode-supported solid oxide fuel cells. J Power Sources 196(6):3109–3113
Sakka S (2005) Handbook of sol–gel science and technology. 1. Sol–gel processing. Springer, Berlin
Langford JT, Wilson A (1978) Scherrer after sixty years: a survey and some new results in the determination of crystallite size. J Appl Crystallogr 11(2):102–113
Naghibi S, Faghihi Sani MA, Madaah Hosseini HR (2014) Application of the statistical Taguchi method to optimize TiO2 nanoparticles synthesis by the hydrothermal assisted sol–gel technique. Ceram Int 40(3):4193–4201
Vivekanandhan S, Venkateswarlu M, Satyanarayana N (2005) Effect of different ethylene glycol precursors on the Pechini process for the synthesis of nano-crystalline LiNi0.5Co0.5VO4 powders. Mater Chem Phys 91(1):54–59
Ejehi F, Marashi S, Ghaani M, Haghshenas D (2012) The synthesis of NaSICON-type ZrNb (PO4)3 structure by the use of Pechini method. Ceram Int 38(8):6857–6863
Wang S, An C, Zhang Y, Zhang Z, Qian Y (2006) Ethanothermal reduction to MoO2 microspheres via modified Pechini method. J Cryst Growth 293(1):209–215
Tsay J-D, Fang T-T, Gubiotti T, Ying J (1998) Evolution of the formation of barium titanate in the citrate process: the effect of the pH and the molar ratio of barium ion and citric acid. J Mater Sci 33(14):3721–3727
Kakihana M, Arima M, Nakamura Y, Yashima M, Yoshimura M (1999) Spectroscopic characterization of precursors used in the Pechini-type polymerizable complex processing of barium titanate. Chem Mater 11(2):438–450
Abreu A Jr, Zanetti S, Oliveira M, Thim G (2005) Effect of urea on lead zirconate titanate—Pb (Zr0.52Ti0.48) O3—nanopowders synthesized by the Pechini method. J Eur Ceram Soc 25(5):743–748
Hajizadeh-Oghaz M, Razavi RS, Loghman-Estarki MR (2014) Synthesis and characterization of non-transformable tetragonal YSZ nanopowder by means of Pechini method for thermal barrier coatings (TBCs) applications. J Sol-Gel Sci Technol 70(1):6–13
Hajizadeh-Oghaz M, Razavi RS, Estarki ML (2014) Large-scale synthesis of YSZ nanopowder by Pechini method. Bull Mater Sci 37(5):969–973
Oghaz MH, Razavi RS, Loghman-Estark MR, Ghasemi R (2013) Optimization of morphology and particle size of modified sol–gel synthesized YSZ nanopowder using Taguchi method. J Nano Res 21:65–70
A Handbook (1979) Metals handbook, powder metallurgy, vol 9
Clarke DR (2003) Materials selection guidelines for low thermal conductivity thermal barrier coatings. Surf Coat Technol 163:67–74
Ahmaniemi S, Vuoristo P, Mäntylä T, Cernuschi F, Lorenzoni L (2004) Modified thick thermal barrier coatings: thermophysical characterization. J Eur Ceram Soc 24(9):2669–2679
Soyez G, Eastman JA, Thompson LJ, Bai G-R, Baldo PM, McCormick AW, DiMelfi RJ, Elmustafa AA, Tambwe MF, Stone DS (2000) Grain-size-dependent thermal conductivity of nanocrystalline yttria-stabilized zirconia films grown by metal-organic chemical vapor deposition. Appl Phys Lett 77(8):1155–1157
Hajizadeh-Oghaz M, Razavi RS, Khajelakzay M (2015) Optimizing sol–gel synthesis of magnesia-stabilized zirconia (MSZ) nanoparticles using Taguchi robust design for thermal barrier coatings (TBCs) applications. J Sol-Gel Sci Technol 73:227–241
Rauf A, Yu Q, Jin L, Zhou C (2012) Microstructure and thermal properties of nanostructured lanthana-doped yttria-stabilized zirconia thermal barrier coatings by air plasma spraying. Scripta Mater 66(2):109–112
Guo X (1997) Space-charge conduction in yttria and alumina codoped-zirconia 1. Solid State Ionics 96(3):247–254
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We gratefully acknowledge support of this research by the Malek Ashtar University of Technology (MUT).
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Hajizadeh-Oghaz, M., Shoja Razavi, R. & Ghasemi, A. Synthesis and characterization of ceria–yttria co-stabilized zirconia (CYSZ) nanoparticles by sol–gel process for thermal barrier coatings (TBCs) applications. J Sol-Gel Sci Technol 74, 603–612 (2015). https://doi.org/10.1007/s10971-015-3639-y
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DOI: https://doi.org/10.1007/s10971-015-3639-y