Abstract
Mn/Nb-doped lead zirconate titanate thin films (PMZT/PNZT) were fabricated by sol–gel process. The effects of Mn/Nb dopant on the phase development, microstructure, ferroelectric and dielectric characteristics of films were studied systematically. For PMZT films, the ferroelectric and dielectric properties were found to deteriorate at low Mn concentration (1 %), while improve slightly as the doping level increased to 2 %. On the other hand, for PNZT films, the optimum doping level was found to be 2 %. The remnant polarization (2Pr) and coercive field (2Ec) were ~50 μC/cm2 and ~63 kV/cm, respectively. In addition, the maximum dielectric constant was found to be 1,630 for 2 % Nb doped films. The ferroelectric and dielectric properties were found to decrease as the increase of Nb doping level (~4 %), due to the fact that the excess Nb would accumulate at grain boundary, hinder the grain growth and decrease the grain size. The improved performance make Mn/Nb doped PZT thin films a promising ferroelectric material for practical applications.
Similar content being viewed by others
References
Chen Z, Zeng Y, Yang CT, Yang BC (2006) Appl Surf Sci 253:1500
Meng XJ, Sun JL, Wang XG, Lin T, Ma JH, Guo SL, Chu JH (2002) Appl Phys Lett 81:4035
Kayasu V, Ozenbas M (2009) J Eur Ceram Soc 29:1157
Cheng JR, Meng ZY (2001) Thin Solid Films 385:5
Moazzami R, Hu CM, Shepherd WH (1992) IEEE Trans Electron Devices 39:2044
Scott JF (1998) Annu Rev Mater Sci 28:79
Bretos I, Jiménez R, Wu AY, Kingon AI, Vilarinho PM, Calzada ML (2014) Adv Mater 26:1405
Kanno I, Kotera H, Wasa K (2003) Sens Actuator A 107:68
Zhang T, Zhang SY, Wasa K, Zhang H, Chen ZJ, Shui XJ, Yang YT (2011) Phys Status Solidi A 208:2460
Jeon YB, Sood R, Jeong JH, Kim SG (2005) Sens Actuator A 122:16
Shen HF, Guo Q, Zhao ZM, Cao GZ (2009) Mater Res Bull 44:2152
Zhang Q, Whatmore RW (2003) J Appl Phys 94:5228
Dobbelaere CD, Calzada ML, Jiménez R, Ricote J, Bretos I, Mullens J, Hardy A, Bael MKV (2011) J Am Chem Soc 133:12922
Hu SH, Meng XJ, Wang GS, Sun JL, Li DX (2004) J Cryst Growth 264:307
Hsu YC, Wu CC, Lee CC, Cao GZ, Shen IY (2004) Sens Actuator A 116:369
Jung DJ, Dawber M, Ruediger A, Scott JF, Kim HH, Kim K (2002) Appl Phys Lett 81:2436
Vilquin B, Rhun GL, Bouregba R, Poullain G, Murray H (2002) Appl Surf Sci 195:63
Muralt P (2000) IEEE Trans Ultrason Ferr 47:903
Zhu WL, Fujii I, Ren W, Trolier-Mckinstry S (2011) J Appl Phys 109:064105
Souza ECF, Simoes AZ, Cilense M, Longo E, Varela JA (2004) Mater Chem Phys 88:155
Haccart T, Remiens D, Cattan E (2003) Thin Solid Films 423:235
Pereira M, Peixoto AG, Gomes MJM (2001) J Eur Ceram Soc 21:1353
Zhu WL, Fujii I, Ren W, Trolier-Mckinstry S (2012) J Am Ceram Soc 95:2906
Park JH, Yoon KH, Kang DH, Park J (2003) Mater Chem Phys 79:151
Thomas R, Mochizuki S, Mihara T, Ishida T (2003) Thin Solid Films 443:14
Karan NK, Thomas R, Pavunny SP, Saavedra-Arias JJ, Murari NM, Katiyar RS (2009) J Alloys Compd 482:253
Zhang Q, Whatmore RW (2001) J Phys D Appl Phys 34:2296
Kwok KW, Tsang RCW, Chan HLW, Choy CL (2004) J Appl Phys 95:1372
Brennecka GL, Parish CM, Tuttle BA, Brewer LN, Rodriguez MA (2008) Adv Mater 20:1407
Wolf RA, Trolier-Mckinstry S (2004) J Appl Phys 95:1397
Sama N, Soyer C, Remiens D, Verrue C, Bouregba R (2010) Sens Actuator A 158:99
Li JK, Yao X (2004) Mater Lett 58:3447
Millon C, Malhaire C, Barbier D (2004) Sens Actuator A 113:376
Calzada ML, Jiménez R, González A (2005) Chem Mater 17:1441
Kwok CK, Desu SB (1992) Appl Phys Lett 60:1430
Jegatheesan P, Giridharan NV (2012) J Mater Sci Mater Electron 23:1103
Ruangchalermwong C, Li JF, Zhu ZX, Lai FP, Muensit S (2009) Thin Solid Films 517:6599
Dunn S, Whatmore RW (2002) J Eur Ceram Soc 22:825
Lin Y, Zhao BR, Peng HB, Hao Z, Xu B, Zhao ZX, Chen JS (1999) J Appl Phys 86:4467
Acknowledgments
Supported by the National Natural Science Foundation of China (Grant Nos. 50802066, 51072145, 51272191 and 51372181), Fundamental Research Funds for the Central Universities and Self-determined and Innovative Research Funds of WUT (Grant No. 2013-IV-034).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Sun, H., Zhang, Y., Liu, X. et al. The effect of Mn/Nb doping on dielectric and ferroelectric properties of PZT thin films prepared by sol–gel process. J Sol-Gel Sci Technol 74, 378–386 (2015). https://doi.org/10.1007/s10971-014-3608-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10971-014-3608-x