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Polymer-ceramic nanocomposites for high energy density applications

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Abstract

Next-generation capacitive energy storage requires novel materials with engineered nano-architectures to compete with conventional methods for energy storage. While current materials and processing strategies produce capacitors with enhanced dielectric permittivity, their breakdown strengths are low. The new fabrication route described in this paper provides flexible, free-standing nanocomposite films with high dielectric permittivity and high breakdown strength. Monodispersed ceramic fillers [BaTiO3, Ba1−xCaxTiO3 (X = 0.3 ± 0.05), and BaZr1−xTixO3 (X = 0.2 ± 0.05)] were synthesized via solvothermal method. Surface-exchanged nanoparticles were combined with polyvinylidene fluoride (PVDF) to fabricate stable polymer-ceramic blends. The PVDF/ceramic nanocomposites resulting from this approach have high dielectric permittivity, low loss tangent, and high electric breakdown strength. The calculated maximum energy densities for the BaTiO3, Ba1–xCaxTiO3 [X = 0.3 ± 0.05], and BaZr1–xTixO3 [X = 0.2 ± 0.05] nanocomposite films are 3.24, 4.72, and 7.74 J cm−3 respectively. This a result of the interplay between the dependencies of permittivity and breakdown strength on volume fraction. It is proposed that the interaction, enhanced by functionalized surface hydroxyl groups, between ceramic and polymer components is the main reason for the improved dielectric properties. This approach is versatile and is readily applicable to other combinations of polymer-ceramics composites so that cooperative properties can be exploited.

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References

  1. Bai Y, Cheng ZY, Bharti V, Xu HS, Zhang QM (2000) High-dielectric-constant ceramic-powder polymer composites. Appl Phys Lett 76:3804

    Article  Google Scholar 

  2. Chu BJ et al (2006) A dielectric polymer with high electric energy density and fast discharge speed. Science 313:334

    Article  Google Scholar 

  3. Dang ZM, Lin YH, Nan CW (2003) Novel ferroelectric polymer composites with high dielectric constants. Adv Mater 15:1625

    Article  Google Scholar 

  4. Puli VS, Pradhan DK, Riggs BC, Chrisey DB, Katiyar RS (2014) Investigations on structure, ferroelectric, piezoelectric and energy storage properties of barium calcium titanate (BCT) ceramics. J Alloy Compd 584:369

    Article  Google Scholar 

  5. Lai MB et al (2013) Effects and mechanism of graft modification on the dielectric performance of polymer-matrix composites. Compos Sci Technol 89:127

    Article  Google Scholar 

  6. Nguyen H, Navid A, Pilon L (2010) Pyroelectric energy converter using co-polymer P(VDF-TrFE) and Olsen cycle for waste heat energy harvesting. Appl Therm Eng 30:2127

    Article  Google Scholar 

  7. Polizos G, Tomer V, Manias E, Randall CA (2010) Epoxy-based nanocomposites for electrical energy storage. II: nanocomposites with nanofillers of reactive montmorillonite covalently-bonded with barium titanate. J Appl Phys 108:074117

  8. Xia WM, Xu Z, Wen F, Zhang ZC (2012) Electrical energy density and dielectric properties of poly(vinylidene fluoride-chlorotrifluoroethylene)/BaSrTiO3 nanocomposites. Ceram Int 38:1071

    Article  Google Scholar 

  9. Wang Q, Zhu L (2011) Polymer nanocomposites for electrical energy storage. J Polym Sci Part B Polym Phys 49:1421

    Article  Google Scholar 

  10. Wu W, Huang XY, Li ST, Jiang PK, Toshikatsu T (2012) Novel three-dimensional zinc oxide superstructures for high dielectric constant polymer composites capable of withstanding high electric field. J Phys Chem C 116:24887

    Article  Google Scholar 

  11. Li JJ et al (2009) Nanocomposites of ferroelectric polymers with TiO2 nanoparticles exhibiting significantly enhanced electrical energy density. Adv Mater 21:217

    Article  Google Scholar 

  12. Rabuffi M, Picci G (2002) Status quo and future prospects for metallized polypropylene energy storage capacitors. IEEE Trans Plasma Sci 30:1939

    Article  Google Scholar 

  13. Wang Y, Zhou X, Chen Q, Chu BJ, Zhang QM (2010) Recent development of high energy density polymers for dielectric capacitors. IEEE Trans Dielectr Electr Insul 17:1036

    Article  Google Scholar 

  14. Zhang QM et al (2002) An all-organic composite actuator material with a high dielectric constant. Nature 419:284

    Article  Google Scholar 

  15. Zhou X et al (2009) Electrical breakdown and ultrahigh electrical energy density in poly(vinylidene fluoride-hexafluoropropylene) copolymer. Appl Phys Lett 94:162901

  16. Dalle Vacche S et al (2014) Effect of silane coupling agent on the morphology, structure, and properties of poly(vinylidene fluoride-trifluoroethylene)/BaTiO3 composites. J Mater Sci 49:4552

    Article  Google Scholar 

  17. Liu SH, Zhai JW, Wang JW, Xue SX, Zhang WQ (2014) Enhanced energy storage density in poly(vinylidene fluoride) nanocomposites by a small loading of suface-hydroxylated Ba0.6Sr0.4TiO3 nanofibers. ACS Appl Mater Interfaces 6:1533

    Article  Google Scholar 

  18. Xie LY, Huang XY, Yang K, Li ST, Jiang PK (2014) “Grafting to” route to PVDF-HFP-GMA/BaTiO3 nanocomposites with high dielectric constant and high thermal conductivity for energy storage and thermal management applications. J Mater Chem A 2:5244

    Article  Google Scholar 

  19. Cho WS (1998) Structural evolution and characterization of BaTiO3 nanoparticles synthesized from polymeric precursor. J Phys Chem Solids 59:659

    Article  Google Scholar 

  20. Smith MB et al (2008) Crystal structure and the paraelectric-to-ferroelectric phase transition of nanoscale BaTiO3. J Am Chem Soc 130:6955

    Article  Google Scholar 

  21. Kim P et al (2009) High energy density nanocomposites based on surface-modified BaTiO3 and a ferroelectric polymer. ACS Nano 3:2581

    Article  Google Scholar 

  22. Niederberger M, Garnweitner G, Pinna N, Antonietti M (2004) Nonaqueous and halide-free route to crystalline BaTiO3, SrTiO3, and (Ba, Sr)TiO3 nanoparticles via a mechanism involving C–C bond formation. J Am Chem Soc 126:9120

    Article  Google Scholar 

  23. Adireddy S, Lin CK, Cao BB, Zhou WL, Caruntu G (2010) Solution-based growth of monodisperse cube-like BaTiO3 colloidal nanocrystals. Chem Mater 22:1946

    Article  Google Scholar 

  24. Mohanty D et al (2012) Synthesis and piezoelectric response of cubic and spherical LiNbO3 nanocrystals. RSC Adv 2:1913

    Article  Google Scholar 

  25. Li CC, Chang SJ, Lee JT, Liao WS (2010) Efficient hydroxylation of BaTiO3 nanoparticles by using hydrogen peroxide. Coll Surf A—Physicochem Eng Asp 361:143

    Article  Google Scholar 

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Acknowledgments

This work was supported by the NSF-EFRI Award # 1038272 Grant. This work was supported in part by the Tulane/Xavier Center for Bioenvironmental Research.

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Authors and Affiliations

  1. Department of Physics and Engineering Physics, Tulane University, 6400 Freret Street, 2001 Percival Stern Hall, New Orleans, LA, 70118, USA

    Shiva Adireddy, Venkata S. Puli, Tiffany J. Lou, S. C. Sklare, Brian C. Riggs & Douglas B. Chrisey

  2. Department of Chemistry, Tulane University, New Orleans, LA, USA

    Ravinder Elupula

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  1. Shiva Adireddy
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  2. Venkata S. Puli
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  6. Brian C. Riggs
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  7. Douglas B. Chrisey
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Correspondence to Shiva Adireddy.

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Adireddy, S., Puli, V.S., Lou, T.J. et al. Polymer-ceramic nanocomposites for high energy density applications. J Sol-Gel Sci Technol 73, 641–646 (2015). https://doi.org/10.1007/s10971-014-3573-4

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  • DOI: https://doi.org/10.1007/s10971-014-3573-4

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