In situ sol–gel preparation of high transparent fluorinated polyimide/nano-MgO hybrid films
Hybrid nanocomposite films of magnesium oxide (MgO) in fluorinated polyimide (PI) from 4, 4′-(hexafluoroisopropylidene) diphthalic anhydride (6FDA) and 4, 4′-Diaminodiphenyl ether (ODA) have been successfully fabricated via an in situ sol–gel polymerization technique. The MgO content in hybrid films was varied from 0 to 5 wt%. The hybrid films were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), ultraviolet–visible (UV–Vis) spectroscopy and thermal gravimetric analyses (TGA). The results of FTIR, XRD and FESEM showed that the MgO nanoparticles were well dispersed in the polymer matrix due to the coordination between the carbonyl group of polymers and Mg atom, and the as-prepared hybrid films exhibited excellent optical transparency in the visible region and good UV-shielding properties in the UV region. Although the thermal stability of the hybrid films is slight inferior to pure PI, it is still good for the practical application below the temperature of 300 °C.
KeywordsPolyimides MgO Nanocomposites In situ sol–gel
The authors gratefully acknowledge the support from the National Natural Science Foundation of China (No. 50902054), the Fundamental Research Funds for the Central Universities (No. 2012QN043), and the Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission & Ministry of Education, South-Central University for Nationalities (No. CHCL09005). The authors also acknowledge the experimental help from Huazhong University of Science & Technology Analytical and Testing Center.
- 10.Srisuwan S, Thongyai S, Praserthdam P (2010) J Appl Polym Sci 117:2422–2427Google Scholar
- 12.Zhang LD, Mou JM (2001) Nano-materials and nano-structure. Science Press, BeijingGoogle Scholar
- 15.Li Q, Wang L, Wang H, Lu R, Liu T (2006) Chn J Appl Chem 23:1145–1149Google Scholar
- 23.Nakamoto K (2009) Infrared and Raman spectra of inorganic and coordination compounds, part B, Chap 1, 6th edn. Wiley, New York, pp 65–66Google Scholar