Nanocomposites based on nickel ferrites dispersed in sol–gel silica matrices
- 125 Downloads
In this work, we describe the effects of thermal treatments on the structural, morphological, and textural properties of nanocomposites formed by nickel ferrite dispersed in xerogel and aerogel silica matrices. The catalytic properties for the total oxidation of an organochloro model contaminant, the chlorobenzene, are also evaluated. Wet samples with different amounts of NiFe2O4 in matrix were prepared by sol–gel process. Xerogels and aerogels obtained in monolithic form were prepared by controlled and hypercritical drying, respectively, and heated at temperatures between 300 and 1,100°C. The specific surface area and total pore volume of the samples change with heating mainly due to the variation on their texture. The xerogel treated at 500°C and the aerogel treated at 700°C showed the most catalytic activity, converting chlorobenzene at temperatures as low as 150°C, while the other catalysts were active only at temperatures higher than 300°C. No organic by-products were observed in the oxidation of chlorobenzene, suggesting that total oxidation takes place under the reaction conditions. A strong decrease in catalytic activity was observed for nanocomposites treated at 1,100°C, due to matrix densification, which led to the encapsulation of the ferrite particles and hindered the access of the gas to the ferrite surface.
KeywordsOxides Sol–gel growth Heat treatment Adsorption
This work was supported by CNPq and FAPEMIG (Brazilian funding agencies). The authors acknowledge the use of the infrastructure of the LMA/UFMG, the Center of Microscopy/UFMG and the help of their technicians.
- 1.Komarneni S, Fregeau E, Breval E, Roy R (1998) J Am Ceram Soc 71(1):C26Google Scholar
- 17.Silva JB, Mohallem NDS (2001) J Magn Magn Mater 232:572Google Scholar
- 19.Cullity BD (1978) Elements of X-ray diffraction. Addison, CaliforniaGoogle Scholar
- 20.Gregg SJ, Sing KSW (1997) Adsorption, surface area, and porosity. Academic Press Inc, New YorkGoogle Scholar
- 21.Lowell S, Shields JE (2005) Powder surface area and porosity. Chapman & Hall, New YorkGoogle Scholar