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Multi-parameter evaluation of fast sol–gel process by terahertz measurements

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Abstract

We present a feasibility study to apply terahertz (THz) spectroscopy and THz imaging as non-destructive diagnostic tools for sol–gel analysis, manufacturing and quality control. By performing THz spectroscopy on liquid and solid samples we were able to follow several key parameters during the sol–gel formation process and of the final product. Sol–gel transformations were monitored by THz absorption, whereas density changes have been observed through changes in refractive indices. Time domain spectroscopy (TDS), both in transmission and reflection geometries, was used to monitor the properties of fast sol–gel resins. THz imaging of gold coated, thin-film sol–gel enables us to determine inhomogeneities and defects in their internal structure. We demonstrated that THz spectroscopy can be implemented as an online analytical tool for multi-parameter evaluation of the sol–gel process during fabrication, and of the final product.

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References

  1. Let AL, Mainwaring DE, Rix CJ, Murugaraj P (2007) J Phys Chem Solids 68:1428

    Article  CAS  Google Scholar 

  2. Yan S, Yin J, Yang J, Chen X (2007) Mater Lett 61:2683

    Article  CAS  Google Scholar 

  3. Armelao L, Eisenmenger-Sittner C, Groenewolt M, Gross S, Sada C, Schubert U, Tondello E, Zattin A (2005) J Mater Chem 15:1838

    Article  CAS  Google Scholar 

  4. Montemayor SM, Garcia-Cerda LA, Torres-Lubian JR, Rodriguez-Fernandez OS (2007) J Sol–Gel Sci Techn 42:181

    Article  CAS  Google Scholar 

  5. Mendez-Vivar J (2006) J Sol–Gel Sci Techn 38:159

    Article  CAS  Google Scholar 

  6. Croutxe-Barghorn C, Soppera O, Carre C (2007) J Sol–Gel Sci Techn 41:93

    Article  CAS  Google Scholar 

  7. Zhou H, Yi D, Yu Z, Xiao L, Li J (2007) Thin Solid Films 515:6909

    Article  CAS  Google Scholar 

  8. Wang ZJ, Usuki H, Kumagai T, Kokawa H (2007) J Sol–Gel Sci Techn 42:375

    Article  CAS  Google Scholar 

  9. Li B, Hakuta Y, Hayashi H (2007) Mater Lett 61:3791

    Article  CAS  Google Scholar 

  10. Perez-Pastenes H, Ochoa-Tapia A, Viveros T, Montoya A (2006) J Sol–Gel Sci Techn 37:49

    Article  CAS  Google Scholar 

  11. Xing W, You B, Wu L (2007) J Sol–Gel Sci Techn 42:187

    Article  CAS  Google Scholar 

  12. Nam KH, Lee TH, Bae BS, Popall M (2006) J Sol–Gel Sci Techn 39:255

    Article  CAS  Google Scholar 

  13. Oubaha M, Dubois M, Murphy B, Etienne P (2006) J Sol–Gel Sci Techn 38:111

    Article  CAS  Google Scholar 

  14. Brown ER (2003) Int J High Speed Electron Syst 13:995

    Article  Google Scholar 

  15. Chan TLJ, Bjarnason JE, Lee AWM, Celis MA, Brown ER (2004) Appl Phys Lett 85:2523

    Article  CAS  Google Scholar 

  16. Guo R, Akiyama K, Minamide H, Ito H (2006) Appl Phys Lett 88:91120

    Article  Google Scholar 

  17. Gorenflo S, Tauer U, Hinkov I, Lambrecht A, Helm H (2006) Chem Phys Lett 421:494

    Article  CAS  Google Scholar 

  18. Anastasi RF, Madaras EI (2006) Proc of SPIE 6176:61760O

    Article  Google Scholar 

  19. Sengupta A, Bandyopadhyay A, Barat RB, Gary DE (2005) Proc SPIE 6120:61200A

    Article  Google Scholar 

  20. Chamberlain JM (2004) Proc SPIE 5619:0277

    Google Scholar 

  21. Yamashita M, Kawase K, Otani C (2005) Opt Express 13:115

    Article  Google Scholar 

  22. Ikeda T, Matsushita A, Tatsuno M, Minami Y, Yamaguchi M, Yamamoto K, Tani M, Hangyo M (2005) Appl Phys Lett 87:034105

    Article  Google Scholar 

  23. Takahashi H, Hosoda M (2000) Appl Phys Lett 77:1085

    Article  CAS  Google Scholar 

  24. Yu BL, Yang Y, Zeng F, Xin X, Alfano RR (2005) Appl Phys Lett 86:061912

    Article  Google Scholar 

  25. Braly LB, Cruzan JD, Liu K, Fellers RS, Saykally RJ (2000) J Chem Phys 112:10293

    Article  CAS  Google Scholar 

  26. Asaki MLT, Redondo A, Zawodzinski TA, Taylor AJ (2002) J Chem Phys 116:8469

    Article  CAS  Google Scholar 

  27. Venables DS, Chiu A, Schmuttenmaer CA (2000) J Chem Phys 113:3243

    Article  CAS  Google Scholar 

  28. Kojima S, Kitahara H, Nishizawa S, Yang YS, Wada Takeda M (2005) J Mol Struct 744:243

    Article  Google Scholar 

  29. Feofilov SP, Kaplyanskii AA, Zakhachenya RI (1996) J Lumin 66:349

    Article  Google Scholar 

  30. Liu HB, Zhang XC (2006) Chem Phys Lett 429:229

    Article  CAS  Google Scholar 

  31. Liu H, Xu J, Lee MY, Janumpally R, Dordick J, Zhang XC (2003) Conference on Lasers and Electro Optics CLEO IEEE Cat No. CH37419-TBR

  32. Zhang J, Grischkowsky D (2004) J Phys Chem B 108:18590

    Article  CAS  Google Scholar 

  33. Gvishi R, Strum G, Shitrit N, Dror R (2007) Optical Material OPTAMAT 33508

  34. Gutina A, Haruvy Y, Gilath I, Axelrod E, Kozlovich N, Feldman Y (1999) J Phys Chem. B 103:5454

    Article  CAS  Google Scholar 

  35. Haruvy Y, Heller A, Webber SE (1992) Chap. 28 In: Bein T (ed) Supramolecular Architecture: Synthetic Control in Thin Films and Solids, Proc ACS Sym

  36. Gvishi R (2008) In: Reisfeld R, Levi D (eds) J Sol–Gel Sci Techn Special Issue for the 60th Anniversary of Avnir D, Springer

  37. Taday PF, Newnham DA (2004) Spectroscopy Eur 16:20

    CAS  Google Scholar 

  38. Chen Y, Liu H, Deng Y, Schauki D, Fitch MJ, Osiander R, Dodson C, Spicer JB, Shur M, Zhang XC (2004) Chem Phys Lett 400:357

    Article  CAS  Google Scholar 

  39. Mickan SP, Shavartsman R, Munch J, Zhang XC, Abbott D (2004) J Opt B: Quantum Semiclass Opt 6:S786

    Article  Google Scholar 

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Acknowledgment

We would like acknowledge the Israeli Ministry of Defense (IMOD) for partial support of this research.

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Authors and Affiliations

  1. Electro-optics Division, Soreq NRC, Yavne, 81800, Israel

    Raz Gvishi, Avraham Englander & Gadi Peleg

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  1. Raz Gvishi
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  2. Avraham Englander
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  3. Gadi Peleg
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Correspondence to Raz Gvishi.

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Gvishi, R., Englander, A. & Peleg, G. Multi-parameter evaluation of fast sol–gel process by terahertz measurements. J Sol-Gel Sci Technol 48, 18–23 (2008). https://doi.org/10.1007/s10971-008-1772-6

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  • DOI: https://doi.org/10.1007/s10971-008-1772-6

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