Journal of Sol-Gel Science and Technology

, Volume 48, Issue 1–2, pp 6–10 | Cite as

Tin-based hybrid materials with a two-level structural hierarchy

  • Hicham Elhamzaoui
  • Bernard Jousseaume
  • Thierry Toupance
  • Cécile Zakri
Original Paper


Self-assembled tin-based hybrid materials with two levels of hierarchy were obtained spontaneously from the hydrolysis of hexaalkynylorganoditins bridged with an aromatic spacer, while in the case of an aliphatic spacer this phenomenon occurred only in the presence of a surfactant.


Sol–gel method Hierarchy Organotins Hybrid material 



The authors wish to thank the CNRS (Material Program Grant), the European Community (FAME network of Excellence) and the Aquitaine Region for partial financial support of this work.


  1. 1.
    Gómez-Romero P, Sanchez C (2003) Functional hybrid materials. Wiley-VCH, WeinheimGoogle Scholar
  2. 2.
    Soler-Illia GJAA, Sanchez C, Lebeau B, Patarin J (2002) Chem Rev 102:4093CrossRefGoogle Scholar
  3. 3.
    Karkamkar AJ, Kim SS, Mahanti SD, Pinnavaia T (2004) Adv Funct Mat 14:507CrossRefGoogle Scholar
  4. 4.
    Brandhuber D, Torma V, Raab C, Peterlik H, Kulak A, Hüsing N (2005) Chem Mater 17:4262CrossRefGoogle Scholar
  5. 5.
    Amatani T, Nakanishi K, Hirao K, Kodaira T (2005) Chem Mater 17:2114CrossRefGoogle Scholar
  6. 6.
    Vallé K, Belleville P, Pereira F, Sanchez C (2006) Nat Mater 5:107CrossRefGoogle Scholar
  7. 7.
    Schüth F, Schmidt W (2002) Adv Mat 14:629CrossRefGoogle Scholar
  8. 8.
    Lu Y, Fan H, Doke N, Loy DA, Assink RA, LaVan DA, Brinker CJ (2000) J Am Chem Soc 122:5258Google Scholar
  9. 9.
    Inagaki S, Guan S, Ohsuna T, Terasaki O (2002) Nature 416:304CrossRefGoogle Scholar
  10. 10.
    Kapoor MP, Yang Q, Inagaki S (2002) J Am Chem Soc 124:15176CrossRefGoogle Scholar
  11. 11.
    Nakanishi K, Kobayashi Y, Amatani T, Hirao K, Kodaira T (2004) Chem Mater 16:3652CrossRefGoogle Scholar
  12. 12.
    Hunks WJ, Ozin GA (2004) Chem Mater 16:5465CrossRefGoogle Scholar
  13. 13.
    Pang J, John VT, Loy SA, Yang Z, Lu Y (2005) Adv Mater 17:704CrossRefGoogle Scholar
  14. 14.
    Brandhuber D, Peterlik H, Hüsing N (2006) Small 4:503CrossRefGoogle Scholar
  15. 15.
    Ribot F, Banse F, Diter F, Sanchez C (1995) New J Chem 19:1163Google Scholar
  16. 16.
    Ribot F, Banse F, Sanchez C, Lahcini M, Jousseaume B (1997) J Sol–Gel Sci Technol 8:529Google Scholar
  17. 17.
    Ribot F, Lafuma A, Eychenne-Baron C, Sanchez C (2002) Adv Mater 14:1496CrossRefGoogle Scholar
  18. 18.
    Ribot F, Veautier D, Guillaudeu SJ, Lalot TJ (2005) J Mater Chem 15:3973CrossRefGoogle Scholar
  19. 19.
    Elhamzaoui H, Jousseaume B, Riague H, Toupance T, Dieudonne P, Zakri C, Maugey M, Allouchi H (2004) J Am Chem Soc 126:8130CrossRefGoogle Scholar
  20. 20.
    Elhamzaoui H, Jousseaume B, Toupance T, Zakri C, Biesemans M, Willem R, Allouchi H (2006) Chem Commun 1304Google Scholar
  21. 21.
    Jousseaume B, Riague H, Toupance T, Lahcini M, Mountford P, Tyrrell BR (2002) Organometallics 21:4590CrossRefGoogle Scholar
  22. 22.
    Elhamzaoui H, Jousseaume B, Toupance T, Allouchi H (2007) Organometallic 27:3908CrossRefGoogle Scholar
  23. 23.
    Igepal® 520: polyoxyethylene(5) nonylphenyl ether; Pluronic 123: poly(ethyleneoxide)-block-poly(propyleneoxide)-block-poly (ethylene oxide)Google Scholar
  24. 24.
    Toupance T, Elhamzaoui H, Jousseaume B, Riague H, Saadeddin Y, Campet G, Brötz J (2006) Chem Mater 18:6364CrossRefGoogle Scholar
  25. 25.
    Brunauer S, Emmet PJ, Teller E (1938) J Am Chem Soc 60:309CrossRefGoogle Scholar
  26. 26.
    Zhao L, Zhu G, Zhang D, Di Y, Chen Y, Terasaki O, Qiu S (2005) J Phys Chem B 109:764CrossRefGoogle Scholar
  27. 27.
    Yu C, Yu Y, Zhao D (2000) Chem Commun 575Google Scholar
  28. 28.
    Matos JR, Kruk M, Mercuri LP, Jaroniec M, Zhao L, Terasaki O, Pinnavaia TJ, Liu Y (2003) J Am Chem Soc 125:821CrossRefGoogle Scholar
  29. 29.
    Matos JR, Mercuri LP, Kruk M, Jaroniec M (2002) Langmuir 18:884CrossRefGoogle Scholar
  30. 30.
    Sakamoto Y, Diaz I, Terasaki O, Zhao D, Perez-Pariente J, Kim JM, Stucky GD (2002) J Phys Chem B 106:3118CrossRefGoogle Scholar
  31. 31.
    Prabusankar G, Jousseaume B, Toupance T, Allouchi H (2006) Angew Chem 45:1255CrossRefGoogle Scholar
  32. 32.
    Janssen J, Magull JJ, Roesky HW (2002) Angew Chem Int Ed 41:1365CrossRefGoogle Scholar
  33. 33.
    Wraage K, Pape T, Herbst-Irmer R, Noltemeyer M, Schmidt HG, Roesky HW (1999) Eur J Inorg Chem 869Google Scholar
  34. 34.
    Puff H, Reuter H (1989) J Organomet Chem 373:173CrossRefGoogle Scholar
  35. 35.
    Dakternieks D, Zhu H, Tiekink ERT, Coltom R (1994) J Organomet Chem 476:33CrossRefGoogle Scholar
  36. 36.
    Ribot F, Banse F, Sanchez C, Toledano P, Maquet J (1995) Inorg Chem 34:6371CrossRefGoogle Scholar
  37. 37.
    Elhamzaoui H, Toupance T, Maugey M, Zakri C, Jousseaume B (2007) Langmuir 23:785CrossRefGoogle Scholar
  38. 38.
    Liu N, Yu K, Smarsly B, Dunphy DR, Jiang YB, Brinker CJ (2002) J Am Chem Soc 124:14540CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2008

Authors and Affiliations

  • Hicham Elhamzaoui
    • 1
  • Bernard Jousseaume
    • 1
  • Thierry Toupance
    • 1
  • Cécile Zakri
    • 2
  1. 1.Institut des Sciences Moléculaires, UMR 5255Université de BordeauxTalenceFrance
  2. 2.Centre de Recherche Paul PascalPessacFrance

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