Journal of Sol-Gel Science and Technology

, Volume 38, Issue 3, pp 293–302 | Cite as

Electrospraying: an in-situ polymerisation route for fabricating high macroporous scaffolds

  • S. N. Jayasinghe
  • A. C. Sullivan


This paper reports a direct jet-based polymerisation by polycondensation approach to forming a self-supporting scaffold structure. The processing technique is electrospraying, which is also known as electrohydrodynamic atomization. A specially formulated ethanolic siloxane sol derived from alkoxysilanes was synthesised and electrosprayed using a ring-shaped ground electrode configuration. The medium was seen to electrospray in the stable cone-jet mode, which later gave rise to the growing or forming of “fir-tree” like structures. The materials were characterised using microscopy, solid state NMR, FTIR, XRD and DSC. Hence this paper explains the direct controlled polycondensation from the siloxane sol and further presents the basis by which these scaffolds take shape.


Electrospraying Electric field-assisted assembling Polycondensation Siloxane Micro-patterning Forming Scaffolds 


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© Springer Science + Business Media, LLC 2006

Authors and Affiliations

  1. 1.Department of Mechanical EngineeringUniversity College LondonLondonUnited Kingdom
  2. 2.Department of ChemistryQueen Mary, University of LondonLondonUK

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