Sorption of various elements on ion-exchange resins in acetic media

Abstract

An anion-exchange resin (Dowex 1×8) and a cation-exchange resin (Dowex 50W×8) were used for the determination of the distribution coefficients (Kd) for the following elements: Sr, Cd, Ba, Ra, Sc, Y, Pm, Lu, Ac, Ti, Zr, Hf, Th, As, Sb, and Se in acetic acid media. Concentration of acetic acid was expanded down to 0.01 M and the distribution coefficients on the ion-exchange resins for the elements with valences from II to VI were determined. Furthermore, the Kd values for a mixtures of acetic acid and ammonium acetate were obtained. Accumulated data is important for more efficient separations and purifications of these elements in the future.

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Acknowledgements

The studies are carried out within the framework of the Program (№: 03-2-1100-2010/2021) on Cooperation between Joint Institute for Nuclear Research Dzhelepov Laboratory of Nuclear Problems in Dubna and the Faculty of Nuclear Sciences and Physical Engineering of the Czech Technical University in Prague.

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Dadakhanov, J., Marinova, A., Baimukhanova, A. et al. Sorption of various elements on ion-exchange resins in acetic media. J Radioanal Nucl Chem 327, 1191–1199 (2021). https://doi.org/10.1007/s10967-021-07600-7

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Keywords

  • Distribution coefficient
  • Ion-exchange resins
  • Acetic acid
  • Ammonium acetate
  • Gamma-ray spectrometry