Skip to main content
Log in

Coal bottom ash natural radioactivity in building materials

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

The viability of ground coal bottom ash as a potential Portland cement constituent to be used in building materials is assessed. Currently, coal fly ash is used to produce Portland cements and concretes. However, coal bottom ash is mainly landfilled. Gamma spectrometry analysis, compressive strength, physical and chemical testing were performed. The ground coal bottom ash activity concentration index (I = 1.03) was compared to that of the coal fly ash (I = 1.11) provided from the same thermo-electrical power plant. Ground coal bottom ash could be used in building materials in the same way as coal fly ash as a Portland cement constituent.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2

Similar content being viewed by others

References

  1. Trevisi R, Risica S, D’Alessandro M, Paradiso D, Nuccetelli C (2012) Natural radioactivity in building materials in the European Union: a database and an estimate of radiological significance. J Environ Radioact 105:11–20

    Article  CAS  PubMed  Google Scholar 

  2. Schroeyers W, Puertas F, Alonso M, Torres Carrasco M, Rivilla P, Gascó C, Trinidad JA, Suárez JA, Navarro N, Yagüe L, Mora JC, Orellana JG, Masqué P, Hierro A, Bolívar JP, Vázquez M, Quintana B (2015) In: Verdú G (ed) Introduction of the COST Action: COST TU1301 “NORM4-building”. 4º Joint Congress 20 SEFM/15 SEPR (Spanish Society for Radiological Protection. Ed.) Valencia. Spain

  3. Council Directive 2013/59/Euratom of 5 Dec. 2013 Laying Down Basic Safety Standards for Protection against the Dangers Arising from Exposure to Ionising Radiation and Repealing Directives 89/618/Euratom. 90/641/Euratom. 96/29/Euratom. 97/43/Euratom and 2003/122/Euratom. L13. vol. 57. ISSN 1977-0677. https://ec.europa.eu/energy/sites/ener/files/documents/CELEX-32013L0059-EN-TXT.pdf. Accessed 27 Jul 2018

  4. Puertas F, García-Díaz I, Palacios M, Gazulla MF, Gómez MP, Orduña M (2010) Clinkers and cements obtained from raw mix containing ceramic waste as a prime material. Characterization, hydration and leaching studies. Cem Concr Compos 32:175–186

    Article  CAS  Google Scholar 

  5. Mejía JM, Mejía de Gutiérrez R, Puertas F (2013) Rice husk ash as a source of silica in alkali-activated fly ash and granulated blast furnace slag systems. Mater Constr 63:361–375

    Article  CAS  Google Scholar 

  6. Sanjuán MA, Argiz C (2012) The new European standard on common cements specifications EN 197-1:2011. Mater Constr 62:425–430

    Article  CAS  Google Scholar 

  7. Argiz C, Menéndez E, Moragues A, Sanjuán MA (2015) Fly ash characteristics of Spanish coal-fired power plants. Afinidad 572:269–277

    Google Scholar 

  8. Carlson CL, Adriano DC (1993) Environmental impacts of coal combustion residues. J Environ Qual 22:227–247

    Article  CAS  Google Scholar 

  9. Ural S (2005) Comparison of fly ash properties from Afsin-Elbistan coal basin, Turkey. J Hazard Mater B119:85–92

    Article  CAS  Google Scholar 

  10. ACAA (2007) Coal Combustion Product (CCP) Production & Use Survey Results. ACAA, Aurora, CO, USA

  11. ECOBA (2005) European Coal Combustion Products Association e.V. Annual Report. ecoba e.V. Essen. Germany

  12. EPA (2008) Study on Increasing the Usage of Recovered Mineral Components in Federally Funded Projects Involving Procurement of Cement or Concrete to Address the Safe. Accountable. Flexible. Efficient Transportation Equity Act: A Legacy for Users. United States Environmental Protection Agency in conjunction with the U.S. Department of Transportation and the U.S. Department of Energy. Report to Congress. June 3. 2008. EPA530-R-08-007. United States Environmental Protection Agency Washington. D.C. 20460. USA

  13. Baró J, Sánchez A, Chinchón S, Yagüe A, Vázquez E (1988) Natural radiation in fly ashes from coal thermal stations in Spain. Cem Concr Res 18:131–137

    Article  Google Scholar 

  14. Chinchón-Payá S, Piedecausa B, Hurtado S, Sanjuán MA, Chinchón S (2011) Radiological impact of cement, concrete and admixtures in Spain. Radiat Measur 46:734–735

    Article  CAS  Google Scholar 

  15. Kovler K, Perevalow A, Steiner V, Metzger LA (2005) Radon exhalation of cementitious materials made with coal fly ash. Part I—Scientific background and testing of the cement and fly ash emanation. J Environ Radioact 82:321–334

    Article  CAS  PubMed  Google Scholar 

  16. Quintana B, Pedrosa MC, Vázquez-Canelas L, Santamaría R, Sanjuán MA, Puertas F (2018) A complete analysis method of NORM building materials by γ-ray spectrometry with HPGe detectors. Appl Radiat Isot 134:470–476

    Article  CAS  PubMed  Google Scholar 

  17. Quintana B, Montes C (2014) Summing-coincidence corrections with Geant4 in routine measurements by γ spectrometry of environmental samples. Appl Radiat Isot 87:390–393

    Article  CAS  PubMed  Google Scholar 

  18. Agostinelli S, Allison J, Amako K, Apostolakis J, Araujo H et al (2003) Geant4—a simulation toolkit. Nucl Instr Methods A 506:250–303

    Article  CAS  Google Scholar 

  19. Puertas F, Alonso MM, Torres-Carrasco M, Rivilla P, Gasco C, Yagüe L, Suárez JA, Navarro N (2015) Radiological characterization of anhydrous/hydrated cements and geopolymers. Constr Build Mater 101:1105–1112

    Article  Google Scholar 

  20. Mohanty AK, Sengupta D, Das SK, Saha SK (2004) Natural radioactivity and radiation exposure in the high background area at Chatrapur beach placer deposit of Orissa, India. J Environ Radioact 75:15–33

    Article  CAS  PubMed  Google Scholar 

  21. Kovler K (2017) The national survey of natural radioactivity in concrete produced in Israel. J Environ Radioact 168:46–53

    Article  CAS  PubMed  Google Scholar 

  22. Chinchón-Payá S, Piedecausa B, Hurtado S, Sanjuán MA, Chinchón S (2011) Radiological impact of cement, concrete and admixtures in Spain. Radiat Measur 46:734–735

    Article  CAS  Google Scholar 

  23. Chinchón S, López-Soler A, Sánchez A, Gingaume M, Yagüe A, Vázquez E (1989) Quantification of fly ash in cement and mortars by means of gamma spectroscopy. Cem Concr Res 19:173–176

    Article  Google Scholar 

  24. Kovler K (2012) Does the utilization of coal fly ash in concrete construction present a radiation hazard? Constr Build Mater 29:158–166

    Article  Google Scholar 

  25. Misdaq MA, Moustaaidine H (1997) New method for determining the radon emanation coefficients and radon production rates in different building materials using solid state nuclear track detectors. J Radioanal Nucl Chem 218:9–12

    Article  CAS  Google Scholar 

  26. UNSCEAR (1988) Report. sources. effects and risks of ionizing radiation. United Nations Scientific Committee on the Effects of Atomic Radiation. Report to the General Assembly with Annexes. United Nations. New York

  27. Pandit GG, Sahu SK, Puranik VD (2011) Natural radionuclides from coal fired thermal power plants—estimation of atmospheric release and inhalation risk. Radioprotection 46:S173–S179

    Article  Google Scholar 

  28. Charro E, Pardo R, Peña V (2013) Statistical analysis of the spatial distribution of radionuclides in soils around a coal-fired power plant in Spain. J Environ Radioact 124:84–92

    Article  CAS  PubMed  Google Scholar 

  29. Bhangare RC, Tiwari M, Ajmal PY, Sahu SK, Pandit GG (2014) Distribution of natural radioactivity in coal and combustion residues of thermal power plants. J Radioanal Nucl Chem 300:17–22

    Article  CAS  Google Scholar 

  30. European Commission (1999) Radiation Protection 122-Radiological Protection Principles Concerning the Natural Radioactivity of Building Materials. Directorate General Environment. Nuclear Safety and Civil Protection. https://ec.europa.eu/energy/sites/ener/files/documents/112.pdf. Accessed 27 Jul 2018

  31. Markkanen M (1995) Radiation Dose Assessments for Materials with Elevated Natural Radioactivity. Report STUK-B-STO 32. Radiation and Nuclear Safety Authority-STUK. Helsinki. Iceland

  32. Stojanovska Z, Nedelkovski D, Ristova M (2010) Natural radioactivity and human exposure by raw materials and end product from cement industry used as building materials. Radiat Measur 45:969–972

    Article  CAS  Google Scholar 

  33. Argiz C, Menéndez E, Sanjuán MA (2013) Effect of mixes made of coal bottom ash and fly ash on the mechanical strength and porosity of Portland cement. Mater Constr 309:49–64

    Google Scholar 

  34. Raju R, Paul MM, Aboobacker KA (2014) Strength performance of concrete using bottom ash as fine aggregate. Int J Res in Eng Technol 2:111–122

    Google Scholar 

  35. Khan RA, Ganesh A (2016) The effect of coal bottom ash (CBA) on mechanical and durability characteristics of concrete. J Build Mater Struct 3:31–42

    Google Scholar 

  36. Argiz C, Sanjuán MA, Menéndez E (2017) Coal bottom ash for portland cement production. Adv Mater Sci Eng ID 6068286:1–7

    Google Scholar 

  37. Sanjuán MA, Menéndez E, Argiz C (2018) Assessment of a new portland cement component: ground coal bottom ash. DYNA 93:192–196

    Article  Google Scholar 

  38. Argiz C, Menéndez E, Moragues A, Sanjuán MA (2014) Recent advances in coal bottom ash use as a new common portland cement constituent. Struct Eng Int 24:503–508

    Article  Google Scholar 

  39. Nisnevich M, Sirotin G, Schlesinger T, Eshel Y (2008) Radiological safety aspects of utilizing coal ashes for production of lightweight concrete. Fuel 87:1610–1616

    Article  CAS  Google Scholar 

  40. Nisnevich M, Schlesinger T, Eshel Y, Grof Y (1999) Lightweight concrete with bottom ash-radiological aspects. ACI Mater J 96:250–254

    CAS  Google Scholar 

Download references

Acknowledgements

This study was realized under the EU’s COST Action TU1301 NORM4BUILDING. http://norm4building.org/.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Miguel Ángel Sanjuán.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sanjuán, M.Á., Quintana, B. & Argiz, C. Coal bottom ash natural radioactivity in building materials. J Radioanal Nucl Chem 319, 91–99 (2019). https://doi.org/10.1007/s10967-018-6251-0

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10967-018-6251-0

Keywords

Navigation