Abstract
To provide radiation hard device is very critical and when a new technology come into existence it becomes more challenging. In this research paper we have explored the radiation response of hafnium dioxide (HfO2)/silicon (Si) structure based metal oxide semiconductor (MOS) capacitor on p-type substrate, subjected to 2.7 MeV proton irradiation at various fluencies (3.6 × 1012 protons/cm2, 7.2 × 1012 protons/cm2, 1.08 × 1013 protons/cm2, 1.8 × 1013 protons/cm2, 2.16 × 1013 protons/cm2 and 3.6 × 1013 protons/cm2). Through electrical characteristics, radiation hardness of atomic layer deposited HfO2 based MOS capacitor has been investigated. To directly measure interface charge and to evaluate its change with the ionizing doses, capacitance–voltage (C–V) and conductance–voltage (G–V) measurements are taken. To provide an evidence for the change in the device parameters pre and post-irradiation curves are plotted to compare the degradation of the device. Shift in C–V and G–V characteristics were observed in irradiated devices that also indicate a change in flat band voltage, midgap voltage and conductance of devices. Generation of new traps after proton irradiation was also confirmed by these measurements.
Similar content being viewed by others
References
Maurya S (2015) Study of atomic layer deposited HfO2/Si interfaces for their quality, reliability and radiation based interface modifications. Ph.D. dissertation, IIIT-Allahabad, India
Maurya S, Tribedi LC, Maringanti R (2014) Engineering of silicon/HfO2 interface by variable energy proton irradiation. Appl Phys Lett 105:071605
Kahraman A, Yilmaz E (2017) Irradiation response of radio-frequency sputtered Al/Gd2O3/p-Si MOS capacitors. Radiat Phys Chem 139:114–119
Maurya S (2016) Effect of zero bias gamma ray irradiation on HfO2 thin films. J Mater Sci Mater Electron 27(12):12796–12802
Kang AY, Lenahan PM, Conley JF (2002) The radiation response of the high dielectric-constant hafnium oxide/silicon system. IEEE Trans Nucl Sci 49(6):2636–2642
Holmes-Siedle AG, Adams L (2002) Handbook of radiation effects, 2nd edn. Oxford University Press, New York
Maurya S (2017) Interface modification by irradiation with alpha particles. J Mater Sci Mater Electron 28(23):17442–17447
Maurya S (2015) Silicon/HfO2 interface: effects of proton irradiation. AIP Conf Proc 1665:120041-1-3
Kim TY, Cho K, Park W, Park J, Song Y, Hong S, Hong WK, Lee T (2014) Irradiation effects of high-energy proton beams on MoS2 field effect transistors. ACS Nano 8(3):27742781
Maurya S (2016) Silicon/HfO2 interface: effects of gamma irradiation. AIP Conf Proc 1731:120034
Schwank JR, Shaneyfelt MR, Fleetwood DM, Felix JA, Dodd PE, Paillet P, Ferlet-Cavrois V (2008) Radiation effects in MOS oxides. IEEE Trans Nucl Sci 55(4):1833
Maurya Savita, Shrivastava Sarita (2016) Challenges beyond 100 nm MOS devices. J VLSI Des Tools Technol 6(2):1–4
Felix JA, Fleetwood DM, Schrimpf RD, Hong JG, Lucovsky G, Schwank JR (2002) Total-dose radiation response of hafnium–silicate capacitors. IEEE Trans Nucl Sci 49(6):3191–3196
Felix JA, Shaneyfelt MR, Fleetwood DM, Schwank JR, Dodd PE, Gusev EP (2004) Charge trapping and annealing in high-K gate dielectrics. IEEE Trans Nucl Sci 51(6):3143–3149
Dixit SK, Zhou XJ, Schrimpf RD, Fleetwood DM, Pantelide ST, Choi R (2007) Radiation induced charge trapping in ultrathin HfO2-based MOSFETs. IEEE Trans Nucl Sci 54(6):1883–1890
Wilk GD, Wallace RM, Anthony JM (2001) High-κ gate dielectrics: current status and materials properties considerations. J Appl Phys 89:5243
Verrelli E, Galanopoulos G, Zouboulis I, Tsoukalas D (2010) Trapping properties of sputtered hafnium oxide films: bulk traps vs. interface traps. Thin Solid Films 518:5579–5584
Maurya S (2018) Effect of nitrogen passivation/pre nitration on interface properties of atomic layer deposited HfO2. J Mater Sci Mater Electron 29(9):7917–7923
Ziegler JF, Ziegler MD, Biersack JP (2008) SRIM, the stopping and range of ions in matter. SRIM Company, Chester
Nicollian EH, Brews JR (2003) MOS (metal oxide semiconductor) physics and technology. Wiley, New York
Yilmaz E, Kaleli B, Turan R (2007) A systematic study on MOS type radiation sensors. Nucl Instrum Methods Phys Res B 264(2):287–292
Ergin FB, Turan R, Shishiyanu ST, Yilmaz E (2010) Effect of γ-radiation on HfO2 based MOS capacitor. Nucl Instrum Methods Phys Res Sect B Beam Interact Mater Atoms 268(9):1482–1485
Tugluoglu N (2007) 60Co γ-ray irradiation effects on the interface traps density of tin oxide films of different thicknesses on n-type Si (111) substrates. Nucl Instrum Methods Phys Res B Beam Interact Mater Atoms 254(1):118
Acknowledgements
One of the authors would like to thank, Dr. Savita Maurya, her advisor and guide for her instructions and valuable time. Her enthusiasm for Semiconductor Devices research as well as her precise insights in work has been incentive for me. What I learned from her both in research and in real life would be precious treasure which I would always benefit from in my future life. MCN for manuscript is IU/R&D/2018-MCN000257.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Maurya, S., Awasthi, S. Effect of zero bias, 2.7 MeV proton irradiation on HfO2. J Radioanal Nucl Chem 318, 947–953 (2018). https://doi.org/10.1007/s10967-018-6229-y
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-018-6229-y