Abstract
Development of rapid gross alpha/beta screening in waters has been presented. Modification of conventional ASTM method assumed direct mixing of samples with liquid scintillation cocktail, without any sample pretreatment. Optimization of method involved sample-to-cocktail ratio determination based on the achieved detection limit and quench level of sample as well as the optimal value of pulse shape analysis discriminator investigation. Results of calibration experiments and method’s validity measurements are presented. Direct alpha/beta method provides deviations <40% from reference values, but offers advantages over conventional alpha/beta measurements, it is ultra fast, simple and inexpensive test for efficient screening of water samples.
Similar content being viewed by others
Notes
α-ROI and β-ROI refer to α-Region Of Interest, and β-Region Of Interest, i.e. the counting windows set for alpha and beta spectra, respectively. α-ROI has been set between 500 and 800 channels in SP12, and β-ROI has been set between 1 and 1024 channels in SP11 [4].
References
ASTM International D 7283-06, standard test method for alpha- and beta- activity in water by liquid scintillation counting. 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States
Sanchez-Cabeza JA, Pujal LA (1995) A rapid method for the simultaneous determination of gross alpha and beta activities in water samples using a low background Liquid Scintillation Counter. Health Phys 68:674–682
Jobbágy V, Merešová J, Dupuis E, Kwakman P, Altzitzoglou T, Rožkov A, Hult M, Emteborg H, Wätjen U (2015) Results of a European interlaboratory comparison on gross alpha/beta activity determination in drinking water. J Radioanal Nucl Chem 306(1):325–331
Todorović N, Nikolov J, Tenjović B, Bikit I, Vesković M (2012) Establishment of a method for measurement of gross alpha/beta activities in water from Vojvodina region. Radiat Meas 47:1053–1059
Stojković I, Tenjović B, Nikolov J, Todorović N (2015) Radionuclide, scintillation cocktail and chemical/color quench influence on discriminator setting in gross alpha/beta measurements by LSC. J Environ Radioactiv 144:41–46
Stojković I, Tenjović B, Nikolov J, Todorović N (2017) Possibilities and limitations of color quench correction methods for gross alpha/beta measurements. Appl Radiat Isotopes 122:164–173
Sanchez-Cabeza JA, Pujol Ll, Merino J, Leon L, Molero J, Vidal-Quadras A, Schell WR, Mitchell PI (1992) Optimization and calibration of a low-background liquid scintillation counter for the simultaneous determination of alpha and beta emitters in aqueous samples. In: Noakes JE, Schonhofer F, Polach HA, eds. Radiocarbon (1993) pp. 43–50. Liquid scintillation spectrometry
Bhade SPD, Reddy PJ, Narayanan A, Narayan KK, Babu DAR, Sharma DN (2010) Standardization of calibration procedures for quantification of gross alpha and gross beta activities using liquid scintillation counter. J Radioanal Nucl Chem 284:367–375
Sas D, Janda J (2017) Rapid determination of gross alpha/beta activity in urine with LSC. J Radioanal Nucl Chem 311:23. doi:10.1007/s10967-016-5077-x
Curie LA (1968) Limits for qualitative detection and quantitative determination. Application to radiochemistry. Anal Chem 40:586–593
Council Directive 2013/51/EURATOM of 22 October 2013 laying down requirements for the protection of the health of the general public with regard to radioactive substances in water intended for human consumption
Official Gazette of the Republic of Serbia No. 38/2011
Acknowledgements
The authors acknowledge the financial support of the Provincial Secretariat for Higher Education and Scientific Research within the project “Radioactivity in drinking water and cancer incidence in Vojvodina” No. 114-451-2405/2016 and the Ministry of education, science and technological development of the Republic of Serbia within Projects No. OI171002 and III43002.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Stojković, I., Todorović, N., Nikolov, J. et al. Establishment of rapid LSC method for direct alpha/beta measurements in waters. J Radioanal Nucl Chem 314, 623–627 (2017). https://doi.org/10.1007/s10967-017-5346-3
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-017-5346-3