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Separation of rare earths by reverse phase partition chromatography

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Abstract

Individual separation of rare earth isotopes from lanthanum to lutetium has been carried out using reverse phase partition chromatography and analyzed by γ-ray spectrometric technique. HDEHP from FLUKA and BDH on inert support celite has been used as extracting agent, whereas hydrochloric acid of different molarities was used as eluting agent. Good separation between individual rare earths has been achieved but the elution pattern differs based on the HDEHP from FLUKA and BDH.

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References

  1. Cuninghame JG, Sizeland ML, Willis HH, Eakins J, Mercer ER (1955) J Inorg Nucl Chem 1:163–164

    Article  CAS  Google Scholar 

  2. Choppin GR, Silva RJ (1956) J Inorg Nucl Chem 3:153–154

    Article  CAS  Google Scholar 

  3. Smith HL, Hoffman DC (1956) J Inorg Nucl Chem 3:243–247

    Article  CAS  Google Scholar 

  4. Danon J (1958) J Inorg Nucl Chem 5:237–239

    Article  CAS  Google Scholar 

  5. Yamabe T, Hayashi T (1973) J Chromatography A 76:213–220

    Article  CAS  Google Scholar 

  6. Faris JP (1967) J Chromatography A 26:232–238

    Article  CAS  Google Scholar 

  7. Foti SC, Wish L (1967) J Chromatography A 29:203–209

    Article  CAS  Google Scholar 

  8. Molnar F, Horvath A, Khalkin VA (1967) J Chromatography A 26:225–231

    Article  CAS  Google Scholar 

  9. Deelstra H, Verbeek F (1965) J Chromatography A 17:558–566

    Article  CAS  Google Scholar 

  10. Dybczyriski R (1964) J Chromatography A 14:79–96

    Article  Google Scholar 

  11. Higgins GH, Street K Jr (1950) J Am Chem Soc 72:5321–5322

    Article  CAS  Google Scholar 

  12. Thompson SG, Cunningham BB, Seaburg GT (1950) J Am Chem Soc 72:2798–2801

    Article  CAS  Google Scholar 

  13. Mayer SW, Preiling EC (1953) J Am Chem Soc 75:5647–5649

    Article  CAS  Google Scholar 

  14. Ward EH, Choppin GR (1965) J Inorg Nucl Chem 27:459–462

    Article  CAS  Google Scholar 

  15. Taketatsu T, Toriumi N (1969) J Inorg Nucl Chem 27:2235–2246

    Article  Google Scholar 

  16. Kosinski FE, Bostian H (1969) J Inorg Nucl Chem 31:3623–3631

    Article  CAS  Google Scholar 

  17. Aziz A, Lyle SJ (1969) J Inorg Nucl Chem 31:3471–3480

    Article  CAS  Google Scholar 

  18. Navratil O, Dubinin I (1969) J Inorg Nucl Chem 31:2927–2932

    Article  CAS  Google Scholar 

  19. Siekiersiki S, Fidelis I (1960) J Chromatography A 4:60–64

    Article  Google Scholar 

  20. Fidelis I, Siekierski S (1961) J Chromatography A 5:161–165

    Article  CAS  Google Scholar 

  21. Winchester JW (1963) J Chromatography A 10:502–506

    Article  CAS  Google Scholar 

  22. Pierce TB, Hobbs RS (1963) J Chromatography A 12:74–80

    Article  CAS  Google Scholar 

  23. Sochacka RJ, Siekierski S (1964) J Chromatography A 16:376–384

    Article  CAS  Google Scholar 

  24. Siekierski S, Sochacka RJ (1964) J Chromatography A 16:385–395

    Article  CAS  Google Scholar 

  25. Fidelis I, Siekierski S (1965) J Chromatography A 17:542–548

    Article  CAS  Google Scholar 

  26. Horwitz EP, Bloomquist CAA, Henderson DJ (1969) J Inorg Nucl Chem 31:1149–1166

    Article  CAS  Google Scholar 

  27. Horwitz EP, Bloomquist CAA (1972) J Inorg Nucl Chem 34:3851–3871

    Article  CAS  Google Scholar 

  28. Horwitz EP, Bloomquist CAA (1973) J Inorg Nucl Chem 35:271–284

    Article  CAS  Google Scholar 

  29. Ishii D, Hirose A, Iwasaki Y (1978) J Radioanal Nucl Chem 46:41–49

    Article  CAS  Google Scholar 

  30. Polkowska-Mototrenko H, Dybczynski R (1980) J Radioanal Nucl Chem 59:31–34

    Article  Google Scholar 

  31. Baker JD, Gehrke RJ, Greenwood RC, Meikrantz DH (1981) Radiochim Acta 28:51–54

    Article  CAS  Google Scholar 

  32. Baranyal R (1982) Radiochem Radioanal Lett 54(4):231–238

    Google Scholar 

  33. Adachi M, Oguma K, Kuroda R (1990) Chromatographia 29:579–582

    Article  CAS  Google Scholar 

  34. Ikeda A, Suzuki T, Aida M, Fujii Y, Mitsugashira T, Hara M, Ozawa M (2005) J Radioanal Nucl Chem 263:605–611

    Article  CAS  Google Scholar 

  35. Flynn K (1975) Report ANL 75-22

  36. NuDat 2.6 (2011) National Nuclear Data Center Brookhaven National Laboratory. http://www.nndc.bnl.gov/

Download references

Acknowledgments

The authors thank to the Head, Radiochemistry Division for his keen interest and encouragement during this experimental work.

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Authors and Affiliations

  1. Radiochemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai, 400085, India

    H. Naik, A. G. C. Nair & A. Ramaswami

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  1. H. Naik
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  2. A. G. C. Nair
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  3. A. Ramaswami
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Correspondence to H. Naik.

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Naik, H., Nair, A.G.C. & Ramaswami, A. Separation of rare earths by reverse phase partition chromatography. J Radioanal Nucl Chem 311, 237–241 (2017). https://doi.org/10.1007/s10967-016-4910-6

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  • DOI: https://doi.org/10.1007/s10967-016-4910-6

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