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Comparison of k 0 NAA analysis results of four different reference materials using six various materials for comparator factor calculation

Abstract

This study compares the analytical performance of several existing materials as k 0-NAA comparator materials (Al-0.1 % Au, Al-0.1 % Ag, Al-1.0 % Co and Al-2.0 % Sc) with the new Al-0.1 % Au material (ERM-EB530). Trace elements in four reference materials (bakelite, fly ash, biological tissue and sediments) were analysed by k 0-NAA using IRMM-530, IRMM-530R, ERM-EB530, IRMM-533, IRMM-528R and IRMM-534 as comparator material. The different k 0-NAA comparators gave reliable, precise and accurate results for all elements and matrices. The study demonstrated that the new Al-0.1 % Au comparator (ERM-EB530) is fit for k 0-NAA and that switching from IRMM-530 or IRMM-530R to ERM-EB530 should not lead to changes in k 0-NAA results.

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References

  1. Ingelbrecht C, Peetermans F, De Corte F, De Wispelaere A, Vandecasteele C, Courtijn E, D’Hondt P (1991) Aluminium–gold reference material for the k 0-standardization of neutron activation analysis. Nucl Instrum Methods A303:119–122

    CAS  Article  Google Scholar 

  2. Ingelbrecht C, Derbyshire M, Robouch P (2001) Certification of gold mass fraction in Al-0.1% Au Alloy: IRMM-530R. Report EUR 19930 EN. European Commission, Brussels

  3. Ingelbrecht C, Roebben G, Derbyshire M, Linsinger TPJ, Lamberty A (2004) Certification of silver mass fraction in Al-0.1% Ag alloy: IRMM-533. Report EUR 20527 EN. European Commission, Brussels

  4. Ingelbrecht C, Derbyshire M (2001) Certification of cobalt mass fraction in three Al-Co alloys: Al-0.1% Co (IRMM-527R), Al-1.0% Co (IRMM-528R), Al-0.01% Co (IRMM-532). Report EUR 19931 EN. European Commission, Brussels

  5. Ingelbrecht C, Linsinger TPJ, Derbyshire M, Lamberty A (2003) The certification of scandium mass fraction in Al-2.0% Sc alloy: IRMM-534. Report EUR 20528 EN. European Commission, Brussels

  6. ASTM E481-10 (2010) Standard test method for measuring neutron fluence rate by radioactivation of cobalt and silver, ASTM International, West Conshohocken

  7. Ingelbrecht C (2003) Reference materials for reactor neutron fluence rate and temperature measurements In: Wagemans J, Aït Abderrahim H, D’hondt P, De Raedt C (ed) Reactor dosimetry in the 21st century. Proceedings of the 11th international symposium on reactor dosimetry, World Scientific Publishing Co. Pte. Ltd., Singapore

  8. De Corte F, Simonits A (1994) Vademecum for k 0 users. DSM Research, Geleen

    Google Scholar 

  9. De Corte F, Simonits A (2003) Recommended nuclear data for use in the k(0) standardization of neutron activation analysis. At Data Nucl Data Tables 85:47–67

    Article  Google Scholar 

  10. Bacquart T, Moens A, Linsinger TPJ (2014) Certification of gold mass fraction in Al-0.1 % Au: ERM-EB530A, B and C. Report EUR 26830 EN, Publications Office of the European Union, Luxembourg

  11. Bacquart T, Li JH, Ribeiro Guevara S, Arribére MA, Gerganova T, Sterckx M, Schumacher P, Linsinger TPJ (2015) A novel route to produce a homogeneous certified reference material for k 0-neutron activation analysis: application to the certification of gold mass fraction in an Al-0.1% Au alloy. Microchem J 124:159–166 (in Press)

    Article  Google Scholar 

  12. Duewer DL, Gasca-Aragon H, Lippa KA, Toman B (2012) Experimental design and data evaluation considerations for comparisons of reference materials. Accredit Qual Assur 17:567–588

    Article  Google Scholar 

  13. Snell J, De Vos E, Emteborg H, Schimmel H (2012) The certification of the mass fractions of elements in mussel tissue: certified reference material ERM®-CE278 k, EUR Report 25523. European Community, Luxembourg

    Google Scholar 

  14. Held A, Kramer GN, Robouch P, Wätjen U (2007) The certification of the mass fractions of As, Cd Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Sb, Se, Tl, V and Zn in fly ash BCR-176R, EUR Report 22667. European Community, Luxembourg

    Google Scholar 

  15. Held A, Kramer GN, Lamberty A, Robouch P, Wätjen U (2006) The certification of the mass fractions of As, Cd Co, Cr, Cu, Fe, Hg, Mn, Ni, Sb, Sc, Se, Sn, Th, Tl, U, V and Zn in three sediments BCR-277R estuarine sediment, BCR-280R lake sediment and BCR-320R channel sediment, EUR Report 21667. European Community, Luxembourg

    Google Scholar 

  16. Vermaercke P, Robouch P, Eguskiza M, De Corte F, Kennedy G, Smodiš B, Jaćimović R, Yonezawa C, Matsue H, Lin X, Blaauw M, Kučera J (2006) Characterisation of synthetic multi-element standards (SMELS) used for the validation of k 0-NAA. Nucl Instrum Methods A564:675–682

    Article  Google Scholar 

  17. Arbocco Farina F, Vermaercke P, Smits K, Sneyers L, Strijckmans K (2013) Experimental validation of some thermal neutron self-shielding calculation methods for cylindrical samples in INAA. J Radioanal Nucl Chem 296:931–938

    Article  Google Scholar 

  18. IAEA (2009) MATSFF program, International Atomic Energy Agency, Vienna. https://www-nds.iaea.org/naa/matssf/. Accessed 25 Aug 2015

  19. ISO/IEC Guide 98-3 (2008) Uncertainty of measurement: part 3: guide to the expression of uncertainty in measurement (GUM:1995). International Organization for Standardization, Geneva

  20. Robouch P, Arana G, Eguskiza E, Pommé S, Etxebarria N (2000) Uncertainty budget for k 0-NAA. J Radioanal Nucl Chem 245:195–197

    CAS  Article  Google Scholar 

  21. Linsinger TPJ (2015) ERM Application Note 1: comparison of a measurement result with the certified value. www.erm-crm.org. Accessed 09 Apr 2015

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Acknowledgments

The Authors would like to thank K. Smits for doing the many measurements and calculations required for this work.

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Correspondence to L. Sneyers.

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Bacquart, T., Sneyers, L., Linsinger, T.P.J. et al. Comparison of k 0 NAA analysis results of four different reference materials using six various materials for comparator factor calculation. J Radioanal Nucl Chem 309, 155–163 (2016). https://doi.org/10.1007/s10967-016-4752-2

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  • DOI: https://doi.org/10.1007/s10967-016-4752-2

Keywords

  • k 0-NAA
  • ERM-EB530
  • Gold comparator
  • Comparator factor calculation
  • k 0 Comparators
  • Comparability of calibrants