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Journal of Radioanalytical and Nuclear Chemistry

, Volume 307, Issue 3, pp 1811–1817 | Cite as

The preparation of non-radioactive glassy surrogate nuclear explosion debris (SNED) loaded with isotopically altered Xe

  • Martin Liezers
  • April J. Carman
  • Gregory C. Eiden
Article

Abstract

The measurement of Kr and Xe isotope ratios in nuclear explosion debris can be performed requiring little sample preparation. Fragments of debris are simply crushed or heated to release trapped gases Kr and Xe arising from fission product decay. As a suitable test material for this measurement, we have been investigating a method to incorporate isotopically enriched 129Xe in glassy materials that mimic nuclear explosion debris. The approach used to prepare these materials will be described along with some of the example results obtained.

Keywords

Trinitite Nuclear forensics Fission Xe Surrogate nuclear explosion debris Laser melting Laser ablation 

Notes

Acknowledgments

This work was funded by the Office of Defense Nuclear Nonproliferation Research and Development with the U.S. Department of Energy’s National Nuclear Security Administration under contract DE-AC05-75RLO1830. The views, opinions and findings contained within this paper are those of the authors and should not be construed as an official position, policy or decision of the DOE unless designated by other documentation.

References

  1. 1.
    Bowyer TW, Schlosser C, Abel KH, Auer M, Hayes JC, Heimbigner TR, McIntyre JI, Panisko ME, Reeder PL, Satorius H, Schlze J, Weiss W (2002) Detection and analysis of xenon isotopes for the comprehensive nuclear-test ban treaty international monitoring system. J Environ Radioact 59:139–151CrossRefGoogle Scholar
  2. 2.
    Meshik AP, Pravdivtseva OV, Hohenburg CM (2005) Fission xenon in trinitites. Meteorit Planet Sci Suppl 40:5321Google Scholar
  3. 3.
    Cassata WS, Prussin SG, Knight KB, Hutcheon ID, Isselhardt BH, Renne PR (2014) When the dust settles: stable xenon isotope ratio constraints on the formation of nuclear fallout. J Environ Radioact 137:88–95CrossRefGoogle Scholar
  4. 4.
    Merrill GL (1974) A static mode mass spectrometer for the measurement of noble gases. Int J Mass Spectrom Ion Phys 13:281–290CrossRefGoogle Scholar
  5. 5.
    Aregbe Y, Mayer K, Valkiers P, De Bièvre P (1996) Release of anthropogenic xenon to the atmosphere: a large scale isotope dilution. Int J Mass Spectrom Ion Proc 154:89–97CrossRefGoogle Scholar
  6. 6.
    Montana A, Guo Q, Boettcher S, White BS, Brearley M (1993) Xe and Ar in high pressure silicate liquids. Am Mineral 78:1135–1142Google Scholar
  7. 7.
    Shibata T, Takahashi E, Matsuda J-I (1998) Solubility of neon, argon, krypton and xenon in binary and ternary silicate systems: a new view on noble gas solubility. Geochim Cosmochim Acta 62(7):1241–1253CrossRefGoogle Scholar
  8. 8.
    Matsumoto T, Matsuda J-I, Yatsevich I, Ozima M (2010) Noble gas mass spectrometry with a compressor driven recycling system for improved sensitivity. Geochem J 44:167–172CrossRefGoogle Scholar
  9. 9.
    Inn KGW, Johnson CM, Oldham W, Jerome S, Tandon L, Schaaff T, Jones R, Mackney D, MacKill P, Palmer B, Smith D, LaMont S, Griggs J (2013) The urgent requirement for new radioanalytical certified reference materials for nuclear safeguards, forensics, and consequence management. J Radioanal Nucl Chem 196:5–22CrossRefGoogle Scholar
  10. 10.
    Jerome S, Leggitt J, Inn KGW (2012) Fresh, post-IND reference material based on glass. Presentation at the international workshop on certified reference materials for nuclear measurements, Saclay, FranceGoogle Scholar
  11. 11.
    Dai ZR, Crowhurst JC, Grant CD, Knight KB, Tang V, Chernov AA, Cook EG, Lotscher JP, Hutcheon ID (2013) Exploring high temperature phenomena related to post-detonation using an electric arc. J Appl Phys 114:204901. doi: 10.1063/1.4829660 CrossRefGoogle Scholar
  12. 12.
    Carney KP, Finck MR, McGrath CA, Martin LR, Lewis RR (2014) The development of radioactive glass surrogates for fallout debris. J Radioanal Nucl Chem 299:363–372CrossRefGoogle Scholar
  13. 13.
    Liezers M, Fahey AJ, Carman AJ, Eiden GC (2015) The formation of trinitite –like surrogate nuclear explosion debris (SNED) and extreme thermal fractionation of SRM-612 glass induced by high power CW CO2 laser irradiation. J Radioanal Nucl Chem 304:705–715CrossRefGoogle Scholar
  14. 14.
    Albert MS, Balamore D (1998) Development of hyperpolarized noble gas MRI. Nucl Instrum Methods Phys Res A 402:441–453CrossRefGoogle Scholar
  15. 15.
    Rosman KJR, Taylor PDP (1998) Isotopic compositions of elements 1997. Pure Appl Chem 70(1):217–235CrossRefGoogle Scholar

Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2015

Authors and Affiliations

  • Martin Liezers
    • 1
  • April J. Carman
    • 1
  • Gregory C. Eiden
    • 1
  1. 1.J4-60, Pacific Northwest National LaboratoryRichlandUSA

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