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Journal of Radioanalytical and Nuclear Chemistry

, Volume 301, Issue 3, pp 863–869 | Cite as

A resonance light scattering method for the determination of uranium based on a water-soluble salophen and oxalate

  • Lin Chen
  • Lifu Liao
  • Xing Shen
  • Yunfei He
  • Canhui Xu
  • Xilin Xiao
  • Yingwu Lin
  • Changming Nie
Article

Abstract

A resonance light scattering (RLS) method for the direct detection of uranium (VI) or uranyl in aqueous solution without separation procedure has been reported in this paper. Sulfo-salophen, a water-soluble tetradentate Schiff base ligand of uranyl, reacted with uranyl to form a complex. The complex reacted further with oxalate to form supramolecular dimer with large molecular volume, resulting in a production of strong RLS signal. The amount of uranium (VI) was detected through measuring the RLS intensity. A linear range was found to be 0.2–30.0 ng/mL under optimal conditions with a detection limit of 0.15 ng/mL. The method has been applied to determine uranium (VI) in environmental water samples with the relative standard deviations of less than 5 % and the recoveries of 98.8–105.8 %. The present technique is suitable for the assay of uranium (VI) in environmental water samples collected from different sources.

Keywords

Uranium Resonance light scattering Water-soluble salophen Oxalate 

Notes

Acknowledgments

The authors thank the National Natural Science Foundation of China (NSFC Nos. 11275091, 10975069 and 11275090) for financial support.

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2014

Authors and Affiliations

  • Lin Chen
    • 1
  • Lifu Liao
    • 1
  • Xing Shen
    • 1
  • Yunfei He
    • 1
  • Canhui Xu
    • 1
  • Xilin Xiao
    • 1
  • Yingwu Lin
    • 1
  • Changming Nie
    • 1
  1. 1.College of Chemistry and Chemical EngineeringUniversity of South ChinaHengyangChina

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