Advertisement

Journal of Radioanalytical and Nuclear Chemistry

, Volume 293, Issue 3, pp 839–842 | Cite as

Solvent extraction of some organic cations into nitrobenzene by using cesium dicarbollylcobaltate in the presence of a hexaarylbenzene-based receptor

  • E. Makrlík
  • P. Selucký
  • P. Vaňura
  • P. Toman
  • R. Rathore
Article

Abstract

From extraction experiments and γ-activity measurements, the exchange extraction constants corresponding to the general equilibrium C +(aq) + Cs+(nb) \( \rightleftarrows \) C+(nb) + Cs+(aq) taking place in the two-phase water–nitrobenzene system (C+ = organic cation, 1 = hexaarylbenzene-based receptor; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability constants of the C+ cationic complex species in nitrobenzene saturated with water were calculated.

Keywords

Organic cations Hexaarylbenzene-based receptor Cesium dicarbollylcobaltate Solvent extraction Nitrobenzene 

Notes

Acknowledgments

This work was supported by the Grant Agency of Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Project No.: 42900/1312/3114 “Environmental Aspects of Sustainable Development of Society,” by the Czech Ministry of Education, Youth and Sports, Project MSM 6046137307, and by the Czech Science Foundation, Project P 205/10/2280. Finally, R. R. thanks the National Science Foundation for financial support.

References

  1. 1.
    Shukla R, Lindeman SV, Rathore R (2006) J Am Chem Soc 128:5328CrossRefGoogle Scholar
  2. 2.
    Ma JC, Dougherty DA (1997) Chem Rev 97:1303CrossRefGoogle Scholar
  3. 3.
    Armentrout PB, Rodgers MT (2000) J Phys Chem A 104:2238CrossRefGoogle Scholar
  4. 4.
    Gapeev A, Yang CN, Klippenstein SJ, Dunbar RC (2000) J Phys Chem A 104:3246CrossRefGoogle Scholar
  5. 5.
    Tsuzuki S, Yoshida M, Uchimaru T, Mikami M (2001) J Phys Chem A 105:769CrossRefGoogle Scholar
  6. 6.
    Huang H, Rodgers MT (2002) J Phys Chem A 106:4277CrossRefGoogle Scholar
  7. 7.
    Mo Y, Subramanian G, Gao J, Ferguson DM (2002) J Am Chem Soc 124:4832CrossRefGoogle Scholar
  8. 8.
    Reddy AS, Sastry GN (2005) J Phys Chem A 109:8893CrossRefGoogle Scholar
  9. 9.
    Vijay D, Sastry GN (2008) Phys Chem Chem Phys 10:582CrossRefGoogle Scholar
  10. 10.
    Sakurai K, Mizuno T, Hiroaki H, Gohda K, Oku J, Tanaka T (2005) Angew Chem Int Ed Engl 44:6180CrossRefGoogle Scholar
  11. 11.
    Makrlík E, Vaňura P (1985) Talanta 32:423CrossRefGoogle Scholar
  12. 12.
    Makrlík E, Vaňura P, Selucký P (2009) J Solut Chem 38:1129CrossRefGoogle Scholar
  13. 13.
    Makrlík E, Vaňura P, Sedláková Z (2009) J Radioanal Nucl Chem 280:607CrossRefGoogle Scholar
  14. 14.
    Makrlík E, Vaňura P, Sedláková Z (2010) J Radioanal Nucl Chem 283:157CrossRefGoogle Scholar
  15. 15.
    Makrlík E, Vaňura P (2010) J Radioanal Nucl Chem 283:497CrossRefGoogle Scholar
  16. 16.
    Makrlík E, Vaňura P, Selucký P, Babain VA, Smirnov IV (2010) J Radioanal Nucl Chem 283:839CrossRefGoogle Scholar
  17. 17.
    Romanovskiy VN, Smirnov IV, Babain VA, Todd TA, Herbst RS, Law JD, Brewer KN (2001) Solvent Extr Ion Exch 19:1CrossRefGoogle Scholar
  18. 18.
    Law JD, Herbst RS, Todd TA, Romanovskiy VN, Babain VA, Esimantovskiy VM, Smirnov IV, Zaitsev BN (2001) Solvent Extr Ion Exch 19:23CrossRefGoogle Scholar
  19. 19.
    Makrlík E, Toman P, Vaňura P, Selucký P, Rathore R (2010) J Radioanal Nucl Chem 286:55CrossRefGoogle Scholar
  20. 20.
    Makrlík E, Selucký P, Vaňura P, Toman P, Rathore R (2011) J Radioanal Nucl Chem 287:497CrossRefGoogle Scholar
  21. 21.
    Hawthorne MF, Young DC, Andrews TD, Howe DV, Pilling RL, Pitts AD, Reintjes M, Warren LF, Wegner PA (1968) J Am Chem Soc 90:879CrossRefGoogle Scholar
  22. 22.
    Rais J (1971) Collect Czechoslov Chem Commun 36:3253Google Scholar
  23. 23.
    Makrlík E, Božek F (1998) Pol J Chem 72:949Google Scholar
  24. 24.
    Makrlík E, Selucký P, Vaňura P, Budka J (2010) J Radioanal Nucl Chem 286:155CrossRefGoogle Scholar
  25. 25.
    Daňková M, Makrlík E, Vaňura P (1997) J Radioanal Nucl Chem 221:251CrossRefGoogle Scholar
  26. 26.
    Makrlík E, Vaňura P (1998) ACH-Model Chem 135:213Google Scholar
  27. 27.
    Makrlík E, Vaňura P (2006) Monatsh Chem 137:157CrossRefGoogle Scholar

Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2012

Authors and Affiliations

  • E. Makrlík
    • 1
  • P. Selucký
    • 2
  • P. Vaňura
    • 3
  • P. Toman
    • 4
  • R. Rathore
    • 5
  1. 1.Faculty of Environmental SciencesCzech University of Life SciencesPrague 6Czech Republic
  2. 2.Nuclear Research InstituteŘežCzech Republic
  3. 3.Department of Analytical ChemistryInstitute of Chemical TechnologyPrague 6Czech Republic
  4. 4.Institute of Macromolecular ChemistryAcademy of Sciences of the Czech RepublicPrague 6Czech Republic
  5. 5.Department of ChemistryMarquette UniversityMilwaukeeUSA

Personalised recommendations