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How to calculate uncertainties of neutron flux parameters and uncertainties of analysis results in k0-NAA?

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Abstract

A novel method is presented for the calculation of uncertainties of neutron flux parameters and element mass fractions and their uncertainties in k0-neutron activation analysis (k0-NAA) using the Kragten universally applicable spreadsheet technique. The results obtained are compared with other approaches for evaluation of uncertainties of the neutron flux parameters and element mass fractions, namely with the Kayzero for Windows, k0-IAEA and ERON programs. The differences observed are discussed in terms of how the above programs take into account various uncertainty sources and their correlations.

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References

  1. De Corte F (1987) The k0 standardization method, a move to the optimization of neutron activation analysis. University of Gent, Belgium

    Google Scholar 

  2. Van Sluijs R (2003) KAYZERO/SOLCOI®, User’s manual for reactor neutron activation analysis using the k0 standardization method, ver. 5a, k0-Ware, Heerlen, The Netherlands

  3. Rossbach M, Blaauw M, Bacchi MA, Lin X (2007) The k0-IAEA program. J Radioanal Nucl Chem 274:657–662

    Article  CAS  Google Scholar 

  4. Robouch P, Arana G, Eguskiza M, Pommé S, Extebarria N (2000) Uncertainty budget for k0-NAA. J Radioanal Nucl Chem 245:195–197

    Article  CAS  Google Scholar 

  5. Kragten J (1994) Tutorial review. Calculating standard deviations and confidence intervals with a universally applicable spreadsheet technique. Analyst 119:2161–2165

    Article  CAS  Google Scholar 

  6. Younes N, Robouch P (2003) A web tool for calculating k0-NAA uncertainties. J Radioanal Nucl Chem 257:665–667

    Article  CAS  Google Scholar 

  7. Smodiš B, Bučar T (2006) Overall measurement uncertainty of k0-based neutron activation analysis. J Radioanal Nucl Chem 269:311–316

    Article  Google Scholar 

  8. Bučar T, Smodiš B (2006) Assessment of the intrinsic uncertainty of the k0-based NAA. Nucl Instrum Methods A 564:683–687

    Article  Google Scholar 

  9. Bučar T, Smodiš B (2008) Computer-assisted uncertainty assessment of k0-NAA measurement results. Nucl Instrum Methods A 595:647–652

    Article  Google Scholar 

  10. Smodiš B, Bučar T (2010) Comparison of k 0–NAA measurement results with calculated uncertainties for reference samples. Nucl Instrum Methods A 622:407–410

    Article  Google Scholar 

  11. Kubešová M, Kučera J (2010) Validation of k 0 standardization method in neutron activation analysis—The use of Kayzero for Windows programme at the nuclear physics institute, Řež. Nucl Instrum Methods A 622:403–406

    Article  Google Scholar 

  12. Kubešová M, Kučera J (2011) Validace metody k0 standardizace v neutronové aktivační analýze programem Kayzero for Windows. Chem Listy 105:261–268 in czech

    Google Scholar 

  13. Kubešová M, Kučera J (2011) Comparison of Kayzero for Windows and k0-IAEA software packages for k 0 standardization in neutron activation analysis. Nucl Instrum Methods A 654:206–212

    Article  Google Scholar 

  14. De Corte F, Simonits A (1994) Vade mecum for k0 users. DMS Research, Geleen

    Google Scholar 

  15. Kubešová M, Kučera J, Fikrle M (2011) A new monitor set for the determination of neutron flux parameters in short-time k0-NAA. Nucl Instrum Methods A 656:61–64

    Article  Google Scholar 

  16. Vermaercke P, Robouch P, Eguskiza M, De Corte F, Kennedy G, Smodiš B, Jačimović R, Yonezawa C, Matsue H, Lin X, Blaauw M, Kučera J (2006) Characterisation of synthetic multi-element standards (SMELS) used for the validation of k 0-NAA. Nucl Instrum Methods A 564:675–682

    Article  CAS  Google Scholar 

  17. Rossbach M, Blaauw M (2006) Progress in the k 0-IAEA program. Nucl Instrum Methods A 564:698–701

    Article  CAS  Google Scholar 

  18. De Corte F, Simonits A (2003) Recommended nuclear data for use in the k0 standardization of neutron activation analysis. At Data Nucl Data Tables 85:47–67

    Article  Google Scholar 

  19. Kolotov VP, De Corte F (2004) Compilation of k 0 and related data for NAA in the form of electronic database (IUPAC Technical Report). Pure Appl Chem 76:1921–1926

    Article  CAS  Google Scholar 

  20. Blaauw M, Bode P, De Bruin M (1991) An alternative convention describing the (n, γ)-reaction rate suited for use in the k0-method of NAA. J Radioanal Nucl Chem 152:435–445

    Article  CAS  Google Scholar 

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Acknowledgments

This work was supported by projects GA ČR 202/09/0363, 202/09/H086, and SGS 10/212/OHK4/2T/14.

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Correspondence to Marie Kubešová.

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Kubešová, M., Kučera, J. How to calculate uncertainties of neutron flux parameters and uncertainties of analysis results in k0-NAA?. J Radioanal Nucl Chem 293, 87–94 (2012). https://doi.org/10.1007/s10967-012-1698-x

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  • DOI: https://doi.org/10.1007/s10967-012-1698-x

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