Abstract
From extraction experiments and γ-activity measurements, the exchange extraction constants corresponding to the general equilibrium \( {\text{M}}^{ 2+ } \left( {\text{aq}} \right) + {\text{Sr}}^{ 2+ } \left( {\text{org}} \right) \Leftrightarrow {\text{M}}^{ 2+ } \left( {\text{org}} \right) + {\text{ Sr}}^{ 2+ } \left( {\text{aq}} \right) \) taking place in the two-phase water–phenyltrifluoromethyl sulfone (abbrev. FS 13) system (M2+ = Mg2+, Ca2+, Ba2+, Cu2+, Zn2+, Cd2+, Pb2+, \( {\text{UO}}_{2}^{2 + } \), Mn2+, Fe2+, Co2+, Ni2+; aq = aqueous phase, org = FS 13 phase) were evaluated. Furthermore, the individual extraction constants of the M2+ cations in this two-phase system were calculated; they were found to increase in the series of Mg2+,\( {\text{UO}}_{2}^{2 + } \) < Ca2+, Co2+ < Cd2+, Ni2+ < Zn2+ < Cu2+, Mn2+, Fe2+ < Pb2+ < Ba2+.
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Acknowledgments
This work was supported by the Grant Agency of Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Project No.: 42900/1312/3114 “Environmental Aspects of Sustainable Development of Society” and by the Czech Ministry of Education, Youth and Sports, Project MSM 6046137307.
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Makrlík, E., Selucký, P. & Vaňura, P. Individual extraction constants of some divalent metal cations in the two-phase water-phenyltrifluoromethyl sulfone system. J Radioanal Nucl Chem 290, 397–401 (2011). https://doi.org/10.1007/s10967-011-1374-6
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DOI: https://doi.org/10.1007/s10967-011-1374-6