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Individual extraction constants of some divalent metal cations in the two-phase water-phenyltrifluoromethyl sulfone system

  • E. Makrlík
  • P. Selucký
  • P. Vaňura
Article
  • 60 Downloads

Abstract

From extraction experiments and γ-activity measurements, the exchange extraction constants corresponding to the general equilibrium \( {\text{M}}^{ 2+ } \left( {\text{aq}} \right) + {\text{Sr}}^{ 2+ } \left( {\text{org}} \right) \Leftrightarrow {\text{M}}^{ 2+ } \left( {\text{org}} \right) + {\text{ Sr}}^{ 2+ } \left( {\text{aq}} \right) \) taking place in the two-phase water–phenyltrifluoromethyl sulfone (abbrev. FS 13) system (M2+ = Mg2+, Ca2+, Ba2+, Cu2+, Zn2+, Cd2+, Pb2+, \( {\text{UO}}_{2}^{2 + } \), Mn2+, Fe2+, Co2+, Ni2+; aq = aqueous phase, org = FS 13 phase) were evaluated. Furthermore, the individual extraction constants of the M2+ cations in this two-phase system were calculated; they were found to increase in the series of Mg2+,\( {\text{UO}}_{2}^{2 + } \) < Ca2+, Co2+ < Cd2+, Ni2+ < Zn2+ < Cu2+, Mn2+, Fe2+ < Pb2+ < Ba2+.

Keywords

Individual extraction constants Divalent metal cations Water–phenyltrifluoromethyl sulfone system Dicarbollylcobaltate anion 

Notes

Acknowledgments

This work was supported by the Grant Agency of Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Project No.: 42900/1312/3114 “Environmental Aspects of Sustainable Development of Society” and by the Czech Ministry of Education, Youth and Sports, Project MSM 6046137307.

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2011

Authors and Affiliations

  1. 1.Faculty of Environmental SciencesCzech University of Life SciencesPrague 6Czech Republic
  2. 2.Nuclear Research InstituteŘežCzech Republic
  3. 3.Department of Analytical ChemistryInstitute of Chemical Technology, PraguePrague 6Czech Republic

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