Abstract
To study the impurity elements, which render color-induced topaz long lived radionuclides, three samples of topaz, from three different cities of the Northern Pakistan (Baltistan, Gilgit and Mardan) were analyzed using k 0 instrumental neutron activation analysis (k 0-INAA). The samples were irradiated in Pakistan Research Reactor-1 (PARR-1) and PARR-2 at Pakistan Institute of Nuclear Science & Technology (PINSTECH), Islamabad. The method was validated by analyzing IAEA-S7 reference material. In three samples a total of 22 trace level impurity elements were quantified. Among impurities, 10 elements including As, Ce, Ga, Ge, La, Na, Sb, Sc, U and Zn were common in topaz of all the three places. The storage time has been calculated for each sample required to bring the induced radioactivity down to permissible level given by US National Regulatory Commission.
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References
Manutchehr-Danai M (ed) (2009) Dictionary of gems, gemology, 3rd edn. Springer-Verlag, Heidelberg, Germany
Cardarelli F (2008) Materials handbook, 2nd edn. Springer, London, UK
Ponce BF, Pingitore NE Jr, Hoffer JM, Anthony EY, Woronow A (1993) J Geochem Explor 49:269
Olabanji SO, Ige OA, Mazzoli C, Ceccato D, Akintunde JA, De Poli M, Moschini G (2005) Nucl Instrum Methods Phys Res B 240:350
Leal AS, Krambrock K, Ribeiro LGM, Menezes MABC, Vermaercke P, Sneyers L (2007) Nucl Instrum Methods Phys Res 580:423
Ashbaugh CE (1992) Gems Gemol 28:104
Ashbaugh CE (1991) Radioact Radiochem 2:42
de Magalhaes CMS, Macedo ZS, Valerio MEG, Hernandes AC, Souza DN (2004) Nucl Instrum Methods Phys Res B 218:277
Ying W, Yong-Bao G (2002) Radiat Phys Chem 63:223
Souza DN, Meira RA, Lima JF, Valerio MEG, Caldas LVE (2003) Appl Radiat Isot 58:489
Krambrock K, Ribeiro LGM, Pinheiro MVB, Leal AS, Menezes MADBC, Spaeth JM (2007) Phys Chem Miner 34:437
Roelandts I (2000) J Radioanal Nucl Chem 243:209
Ravisankar R, Manikandan E, Dheenathayalu M, Rao B, Seshadreesan NP, Nair KGM (2006) Nucl Instrum Methods Phys Res B 251:496
Vitali V, Franklin UM (1986) J Archaeol Sci 13:161
Wasim M, Zaidi JH, Arif M, Fatima I (2008) J Radioanal Nucl Chem 277:525
Wasim M, Arif M, Zaidi JH, Anwar Y (2009) Radiochim Acta 97:651
Wasim M (2010) J Radioanal Nucl Chem 285:337
IAEA Analytical Quality Control Services (2004) Reference materials catalogue, 2004–2005, 1st edn. International Atomic Energy Agency, Vienna, Austria, Jan 2004, p 35
USNRC regulations (2010) http://www.nrc.gov/reading-rm/doc-collections/cfr/part030/part030-0070.html. Accessed June 2010
Acknowledgment
The authors are grateful for the help of personnel from Material Laboratory, PIEAS. Yasir Anwar and Sajid Iqbal are also acknowledged for their help during experimentation.
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Wasim, M., Zafar, W.A., Tufail, M. et al. Elemental analysis of topaz from northern areas of Pakistan and assessment of induced radioactivity level after neutron irradiation for color induction. J Radioanal Nucl Chem 287, 821–826 (2011). https://doi.org/10.1007/s10967-010-0879-8
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DOI: https://doi.org/10.1007/s10967-010-0879-8