Abstract
Results from tests aimed at optimizing an instrumental procedure for the direct and fast determination of uranium in solution by laser fluorescence are presented. A comparison of sample fluorescence measured using different fluorescence enhancing reagents was performed: sodium pyrophosphate, orthophosphoric acid, sulphuric acid and a commercially available fluorescence enhancer were tested for the determination of uranium. From the experimental results, 0.01 M Na4P2O7·10H2O showed the best performance. Effects of reagent pH, different matrices, different concentrations of dissolved Th, and sample volume were investigated. Applications of the improved procedure for the determination of uranium in samples arising from UO2-based high level nuclear waste dissolution studies are described.
Similar content being viewed by others
References
Röllin S, Spahiu K, Eklund U-B (2001) J Nucl Mater 297:231
Opel K, Weiß S, Hübener S, Zänker H, Bernhard G (2007) Radiochim Acta 95:143
Sunder S, Shoesmith DW, Miller NH (1997) J Nucl Mater 244:66
Spahiu K, Cui D, Lundström M (2004) Radiochim Acta 92:625
Shoesmith DW (2000) J Nucl Mater 282:1
Robbins JC, Castledine C, Kostiak W (1985) Analytical procedures for UA-3 uranium analysis—applications manual. Scintrex Limited, Ontario
Scintrex (1983) UA-3 Uranium Analyser, instruction manual, geophysical and geochemical instrumentation and services
Zook AC, Collins LH, Pietri CE (1981) Mikrochim Acta 2:457
Premadas A, Saravanakumar G (2005) J Radioanal Nucl Chem 266:95
Premadas A, Srivastava PK (1999) J Radioanal Nucl Chem 242:23
Galperin A, Shwageraus E, Todosow M (2002) Nucl Technol 138:111
Herring JS, Weaver KD (2003) Nucl Technol 143:22
Todosow M, Galperin A, Herring S, Kazimi M, Downar T, Morozov A (2005) Nucl Technol 151:168
Choi H, Park CJ (2006) Nucl Technol 153:132
Núñez-Carrera A, François Lacouture JL, del Campo CM, Espinosa-Paredes G (2008) Energy Convers Manag 49:47
Gruppelaar H, Schapira JP (eds) (2000) Thorium as a waste management option. Nuclear science and technology series, European Commission Final Report. p 155
Veselsky JC, Kwiecinska B, Wehrstein E, Suschny O (1988) Analyst 113:451
Kelm M, Bohnert E (2005) J Nucl Mater 346:1
Rathore DPS, Tarafder PK, Kayal M, Kumar M (2001) Anal Chim Acta 434:201
Kumar SA, Shenoy NS, Pandey S, Sounderajan S, Venkateswaran G (2008) Talanta 77:422
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Kütahyali, C., Cobos, J. & Rondinella, V.V. Comparison of fluorescence-enhancing reagents and optimization of laser fluorimetric technique for the determination of dissolved uranium. J Radioanal Nucl Chem 287, 1–5 (2011). https://doi.org/10.1007/s10967-010-0832-x
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-010-0832-x