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Quinolinephosphomolybdate as ion exchanger: synthesis, characterization, and application in separation of 90Y from 90Sr

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Abstract

An inorganic ion exchanger, quinolinephosphomolybdate has been synthesized and characterized by elemental analysis, infrared (IR) and X-ray diffraction (XRD) spectroscopy. This compound is highly stable toward thermal, chemical and radiation dose. This has been employed in the separation of carrier-free 90Y from its parent 90Sr from an equilibrium mixture. The absorbed daughter was recovered by using 0.0284 mol L−1 ascorbic acid solutions at pH 5.0 as eluting agent.

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Acknowledgments

Financial assistance from UGC-DAE Center for Scientific Research, Kolkata is gratefully acknowledged. The authors are also grateful to Dr. A. Saha and Dr. A. Datta of UGC-DAE Center for Scientific Research, Kolkata. The authors are obliged to the University of Burdwan for their kind permission to carry out the work using the infrastructure facility.

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Authors and Affiliations

  1. Department of Chemistry, The University of Burdwan, Burdwan, 713 104, WB, India

    Rajesh Chakraborty, Sanjoy Dhara, Sukalyan Basu & Pabitra Chattopadhyay

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  1. Rajesh Chakraborty
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  2. Sanjoy Dhara
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  3. Sukalyan Basu
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  4. Pabitra Chattopadhyay
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Correspondence to Pabitra Chattopadhyay.

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Chakraborty, R., Dhara, S., Basu, S. et al. Quinolinephosphomolybdate as ion exchanger: synthesis, characterization, and application in separation of 90Y from 90Sr. J Radioanal Nucl Chem 287, 55–59 (2011). https://doi.org/10.1007/s10967-010-0688-0

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  • DOI: https://doi.org/10.1007/s10967-010-0688-0

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