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Sorption study of U(VI), Th(IV) and Ce(III) on poly[dibenzo-18-crown-6] in l-arginine to develop sequential column chromatographic separation method

  • Sandip R. Sabale
  • D. V. Jadhav
  • B. S. Mohite
Article

Abstract

A simple and efficient column chromatographic method has been developed for the sequential separation of U(VI), Th(IV) and Ce(III) using poly[dibenzo-18-crown-6] as stationary phase and l-arginine as a counter ion. The different elution patterns with various eluting agents were observed for individual element. The capacity of poly[dibenzo-18-crown-6] for U(VI), Th(IV) and for Ce(III) was found to be 0.96, 0.86 and 1.49 (±0.01) mmol/g of crown polymer, respectively. The method is efficient to separate the elements in multicomponent mixtures and has good recovery. The method is extended to determine the U(VI), Th(IV) and Ce(III) from monazite sand. The method is simple, rapid and selective having good reproducibility (~±2%).

Keywords

U(VI) Th(IV) Ce(III) Poly[dibenzo-18-crown-6] l-arginine Separation 

Notes

Acknowledgements

One of the authors (Mr. Sandip Sabale) is gratefully acknowledges the University Grant Commission for awarding Research Fellowship.

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2010

Authors and Affiliations

  1. 1.Analytical and Environmental Research Lab, Department of ChemistryShivaji UniversityKolhapurIndia

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