Abstract
Boundary equations for a diagram of the ambiguous, forbidden, and unique combinations of hexavalent plutonium versus the Pu oxidation number are presented. The equations and the diagram apply after disproportionation reactions have reached equilibrium. A curve illustrates the equilibrium fraction of Pu(V) versus the Pu oxidation number in a solution at pH 2.
References
Silver GL (2009) Appl Radiat Isot 67:103–105
Johnson DA (1968) Some thermodynamic aspects of inorganic chemistry. Cambridge University Press, Cambridge, p 85
Silver GL (2006) J Radioanal Nucl Chem 267:305–308
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Silver, G.L. The Pu(VI), oxidation-number diagram. J Radioanal Nucl Chem 283, 533–535 (2010). https://doi.org/10.1007/s10967-009-0362-6
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DOI: https://doi.org/10.1007/s10967-009-0362-6