Skip to main content
SpringerLink
Log in

Extraction of microamounts of europium and americium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of diphenyl-N-butylcarbamoylmethyl phosphine oxide

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

Extraction of microamounts of europium and americium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B−) in the presence of diphenyl-N-butylcarbamoylmethyl phosphine oxide (DPBCMPO, L) has been investigated. The equilibrium data have been explained assuming that the complexes HL+, HL +2 , ML 3+2 , ML 3+3 and ML 3+4 (M3+ = Eu3+, Am3+) are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined. It has been found that the stability constants of the corresponding complexes EuL 3+ n and AmL 3+ n , where n = 2, 3, 4 and L is DPBCMPO, in water saturated nitrobenzene are comparable.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. W. W. Schulz, E. P. Horwitz, Separ. Sci. Technol., 23 (1988) 1191.

    Article  CAS  Google Scholar 

  2. C. Cuillerdier, C. Musikas, P. Hoel, L. Nigond, X. Vitart, Separ. Sci. Technol., 26 (1991) 1229.

    Article  CAS  Google Scholar 

  3. G. R. Mahajan, D. R. Prabhu, V. K. Manchanda, L. P. Badheka, Waste Managem., 18 (1998) 125.

    Article  CAS  Google Scholar 

  4. V. N. Romanovskiy, I. V. Smirnov, V. A. Babain, T. A. Todd, R. S. Herbst, J. D. Law, K. N. Brewer, Solvent Extr. Ion Exch., 19 (2001) 1.

    Article  CAS  Google Scholar 

  5. J. D. Law, R. S. Herbst, T. A. Todd, V. N. Romanovskiy, V. A. Babain, V. M. Esimantovskiy, I. V. Smirnov, B. N. Zaitsev, Solvent Extr. Ion Exch., 19 (2001) 23.

    Article  CAS  Google Scholar 

  6. E. Makrlík, P. Vaňura, Talanta, 32 (1985) 423.

    Article  Google Scholar 

  7. M. F. Hawthorne, D. C. Young, T. D. Andrews, D. V. Howe, R. L. Pilling, A. D. Pitts, M. Reintjes, L. F. Warren, P. A. Wegner, J. Am. Chem. Soc., 90 (1968) 879.

    Article  CAS  Google Scholar 

  8. E. Makrlík, Collect. Czech. Chem. Commun., 57 (1992) 289.

    Article  Google Scholar 

  9. R. Chiarizia, E. P. Horwitz, Solvent Extr. Ion Exch., 10 (1992) 101.

    Article  CAS  Google Scholar 

  10. G. Suresh, M. S. Murali, J. N. Mathur, Radiochim. Acta, 91 (2003) 127.

    Article  CAS  Google Scholar 

  11. B. J. Mincher, Solvent Extr. Ion Exch., 10 (1992) 615.

    Article  CAS  Google Scholar 

  12. P. Vaňura, E. Makrlík, J. Radioanal. Nucl. Chem., 267 (2006) 251.

    Article  Google Scholar 

  13. P. Vaňura, E. Makrlík, J. Radioanal. Nucl. Chem., 267 (2006) 465.

    Article  Google Scholar 

  14. E. Makrlík, P. Vaňura, Collect. Czech. Chem. Commun., 51 (1986) 498.

    Google Scholar 

  15. E. Makrlík, P. Vaňura, P. Selucký, unpublished results.

  16. J. Rais, S. Tachimori, Separ. Sci. Technol., 29 (1994) 1347.

    Article  CAS  Google Scholar 

  17. P. Vaňura, E. Makrlík, J. Rais, M. Kyrš, Collect. Czech. Chem. Commun., 47 (1982) 1444.

    Google Scholar 

  18. P. Vaňura, E. Makrlík, Collect. Czech. Chem. Commun., 58 (1993) 1324.

    Article  Google Scholar 

  19. L. G. Sillén, B. Warnqvist, Arkiv Kemi., 31 (1969) 315.

    Google Scholar 

  20. E. Makrlík, P. Vaňura, P. Selucký, J. Radioanal. Nucl. Chem., 275 (2008) 309.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Applied Sciences, University of West Bohemia, Husova 11, 306 14, Pilsen, Czech Republic

    E. Makrlík

  2. Institute of Chemical Technology, Technická 5, 166 28, Prague, Czech Republic

    P. Vaňura

  3. Nuclear Research Institute, 250 68, Řež, Czech Republic

    P. Selucký

Authors
  1. E. Makrlík
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. P. Vaňura
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. P. Selucký
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. Makrlík.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Makrlík, E., Vaňura, P. & Selucký, P. Extraction of microamounts of europium and americium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of diphenyl-N-butylcarbamoylmethyl phosphine oxide. J Radioanal Nucl Chem 279, 137–142 (2009). https://doi.org/10.1007/s10967-007-7203-2

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10967-007-7203-2

Keywords

Search

Navigation