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Determination of the chemical forms of iodine with IC-ICP-MS and its application to environmental samples

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Abstract

An online analytical system using ion chromatography (IC) followed by inductively coupled plasma mass spectrometry (ICP-MS) was developed for the separate determination of I− and IO −3 in aqueous solutions with a detection limit 0.1–1 μg 1/1. The total iodine concentration was also directly determined by ICP-MS. Iodine in several environmental samples (i.e., rain, river water, brine, and soil solution) was successfully determined with information on its chemical form. The release of I− into soil solution with decreasing Eh was observed in an incubation experiment with flooded soil. An iodine form other than I− and IO −3 was observed in several environmental samples.

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Authors and Affiliations

  1. National Institute of Radiological Sciences, Anagawa 4-9-1, Inage-ku, Chiba, 263-8555, Japan

    S. Yoshida

  2. Gakushuin University, Mejiro 1-5-1, Toshima-ku, Tokyo, 171-8588, Japan

    Y. Muramatsu

  3. Utsunomiya University, Minemachi 350, Utsunomiya-shi, Tochigi, 321-8505, Japan

    S. Katou & H. Sekimoto

Authors
  1. S. Yoshida
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  2. Y. Muramatsu
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  3. S. Katou
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  4. H. Sekimoto
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Yoshida, S., Muramatsu, Y., Katou, S. et al. Determination of the chemical forms of iodine with IC-ICP-MS and its application to environmental samples. J Radioanal Nucl Chem 273, 211–214 (2007). https://doi.org/10.1007/s10967-007-0738-4

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  • DOI: https://doi.org/10.1007/s10967-007-0738-4

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