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Synthesis and suitability characterization of microcrystalline cellulose from Citrus x sinensis sweet orange peel fruit waste-based biomass for polymer composite applications

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Abstract

Presently, waste management is the primary focus of scientific inquiry. The recyclable and reusable organic waste are dumbed a lot as landfills in the environment and that could be converted into application-oriented polymer reinforcing material. Cellulose is a widespread biopolymer that is found in the majority of bio waste materials. The organic waste Citrus x sinensis peel (Citrus × aurantium f. aurantium) is used as a raw material in this research. The waste material was utilized to extract the cellulose using optimum chemical conditions such as alkali treatment, acid hydrolysis, and bleaching and purification process. Fourier transform spectroscopy was applied to the cellulose to detect the functional groups it contained and indicated progressive removal of non-cellulosic constituents. The cellulose that was extracted has a yield percentage of 67.82% and a density of 1.413 g/cm3. The differential scanning curve analysis reveals that the temperature of degradation is 308.17 °C. Through the utilisation of thermogravimetric analysis, each phase of thermal activity was studied. According to an X-ray diffraction investigation, cellulose has a crystalline size of 9.63 nm and a higher crystallinity index of 72.54 percent exhibiting unique physicochemical properties. The Scanning electron microscopy shows the different size and shape of particles oriented with rough surface. Using ImageJ software, the other distinguishing characteristics of surface morphology, and particle size analysis are performed. The elemental analysis demonstrates the cellulose's organic nature by demonstrating its higher carbon and oxygen content. On the basis of the physicochemical characteristics of the celluloses, it could be considered as alternative sources of cellulose for potential value-added industrial applications and more applicable for the polymer composite reinforcement filler material.

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Data availability

The data that support the findings of this study are available on request from the corresponding author. The data are not publicly available due to privacy or ethical restrictions.

References

  1. Divya D, Suyambulingam I, Sanjay MR, Siengchin S (2022) Suitability examination of novel cellulosic plant fiber from Furcraea selloa K. Koch peduncle for a potential polymeric composite reinforcement. Polym Compos 43:4223–4243. https://doi.org/10.1002/PC.26683

    Article  CAS  Google Scholar 

  2. Giacon VM, Rebelo VSM, dos Santos GM et al (2021) Influence of mercerization on the physical and mechanical properties of polymeric composites reinforced with amazonian fiber. Fibers and Polymers 22:1950–1956. https://doi.org/10.1007/s12221-021-0460-9

    Article  CAS  Google Scholar 

  3. Rangappa SM, Siengchin S, Parameswaranpillai J et al (2022) Lignocellulosic fiber reinforced composites: Progress, performance, properties, applications, and future perspectives. Polym Compos 43:645–691. https://doi.org/10.1002/pc.26413

    Article  CAS  Google Scholar 

  4. Mishra R, Wiener J, Militky J et al (2020) Bio-composites reinforced with natural fibers: Comparative analysis of thermal, static and dynamic-mechanical properties. Fibers Polym 21:619–627. https://doi.org/10.1007/s12221-020-9804-0

    Article  CAS  Google Scholar 

  5. Chua KY, Azzahari AD, Abouloula CN et al (2020) Cellulose-based polymer electrolyte derived from waste coconut husk: residual lignin as a natural plasticizer. J Polym Res. https://doi.org/10.1007/s10965-020-02110-8

    Article  Google Scholar 

  6. Dinesh S, Kumaran P, Mohanamurugan S et al (2020) Influence of wood dust fillers on the mechanical, thermal, water absorption and biodegradation characteristics of jute fiber epoxy composites. J Polym Res. https://doi.org/10.1007/s10965-019-1975-2

    Article  Google Scholar 

  7. Subash N, Adish Kumar S (2022) A simplified geopolymer concrete mix design considering five mineral admixtures. Eur J Environ Civ Eng 26:7572–7585. https://doi.org/10.1080/19648189.2021.2003252

    Article  Google Scholar 

  8. Esfandiari A (2008) The statistical investigation of mechanical properties of PP/natural fibers composites. Fibers and Polymers 9:48–54. https://doi.org/10.1007/s12221-008-0008-2

    Article  CAS  Google Scholar 

  9. Shih YF, Huang CC (2011) Polylactic acid (PLA)/banana fiber (BF) biodegradable green composites. J Polym Res 18:2335–2340. https://doi.org/10.1007/s10965-011-9646-y

    Article  CAS  Google Scholar 

  10. Maurya AK, Manik G (2023)  Advances towards development of industrially relevant short natural fiber reinforced and hybridized polypropylene composites for various industrial applications: a review. J Polym Res 2022 30:1–20. https://doi.org/10.1007/S10965-022-03413-8

    Article  Google Scholar 

  11. Mahmud S, Hasan KMF, Jahid MA et al (2021) Comprehensive review on plant fiber-reinforced polymeric biocomposites. Springer, US

    Book  Google Scholar 

  12. Asyraf MRM, Syamsir A, Ishak MR et al (2023) Mechanical properties of hybrid lignocellulosic fiber-reinforced biopolymer green composites: a review. Fibers Polym 24:337–353. https://doi.org/10.1007/s12221-023-00034-w

    Article  CAS  Google Scholar 

  13. Bhandari K, Roy Maulik S, Bhattacharyya AR (2020) Synthesis and characterization of microcrystalline cellulose from rice husk. J Inst Eng  (India): Ser E 101:99–108. https://doi.org/10.1007/s40034-020-00160-7

    Article  CAS  Google Scholar 

  14. John MJ, Anandjiwala RD (2008) Recent developments in chemical modification and characterization of natural fiber-reinforced composites. Polym Compos 29:187–207. https://doi.org/10.1002/PC.20461

    Article  CAS  Google Scholar 

  15. Kumar M, Revathi K, Khanna S (2015) Biodegradation of cellulosic and lignocellulosic waste by Pseudoxanthomonas sp R-28. Carbohydr Polym 134:761–766. https://doi.org/10.1016/j.carbpol.2015.08.072

    Article  CAS  PubMed  Google Scholar 

  16. Subash N, Avudaiappan S, Kumar SA et al (2021) Experimental investigation on geopolymer concrete with various sustainable mineral ashes. Materials. https://doi.org/10.3390/ma14247596

    Article  PubMed  PubMed Central  Google Scholar 

  17. Prakash O, Naik M, Katiyar R et al (2018) Novel process for isolation of major bio-polymers from Mentha arvensis distilled biomass and saccharification of the isolated cellulose to glucose. Ind Crops Prod 119:1–8. https://doi.org/10.1016/j.indcrop.2018.03.063

    Article  CAS  Google Scholar 

  18. Sunesh NP, Suyambulingam I, Divakaran D, Siengchin S (2023) Isolation of microcrystalline cellulose from valoniopsis pachynema green macroalgae: Physicochemical, thermal, morphological, and mechanical characterization for biofilm applications. Waste Biomass Valorization. https://doi.org/10.1007/s12649-023-02228-y

    Article  Google Scholar 

  19. Narayana Perumal S, Suyambulingam I, Divakaran D, Siengchin S (2023) Extraction and physico-mechanical and thermal characterization of a novel green bio-plasticizer from pedalium murex plant biomass for biofilm application. J Polym Environ. https://doi.org/10.1007/s10924-023-02898-8

    Article  Google Scholar 

  20. Hasanin MS, Kassem N, Hassan ML (2021) Preparation and characterization of microcrystalline cellulose from olive stones. Biomass Convers Biorefin. https://doi.org/10.1007/s13399-021-01423-y

    Article  Google Scholar 

  21. Mysiukiewicz O, Sałasińska K, Barczewski M, Szulc J (2020) The influence of oil content within lignocellulosic filler on thermal degradation kinetics and flammability of polylactide composites modified with linseed cake. Polym Compos 41:4503–4513. https://doi.org/10.1002/PC.25727

    Article  CAS  Google Scholar 

  22. Barman A, Shrivastava NK, Khatua BB, Ray BC (2015) Green composites based on high-density polyethylene and Saccharum spontaneum: Effect of filler content on morphology, thermal, and mechanical properties. Polym Compos 36:2157–2166. https://doi.org/10.1002/PC.23126

    Article  CAS  Google Scholar 

  23. Moutousidis D, Karidi K, Athanassiadou E et al (2023) Reinforcement of urea formaldehyde resins with pectins derived from orange peel residues for the production of wood-based panels. Sustain Chem Environ 4:100037. https://doi.org/10.1016/j.scenv.2023.100037

    Article  Google Scholar 

  24. Tarchoun AF, Trache D, Klapötke TM (2019) Microcrystalline cellulose from Posidonia oceanica brown algae: Extraction and characterization. Int J Biol Macromol 138:837–845. https://doi.org/10.1016/j.ijbiomac.2019.07.176

    Article  CAS  PubMed  Google Scholar 

  25. Beroual M, Trache D, Mehelli O et al (2021) Effect of the delignification process on the physicochemical properties and thermal stability of microcrystalline cellulose extracted from date palm fronds. Waste Biomass Valorization 12:2779–2793. https://doi.org/10.1007/s12649-020-01198-9

    Article  CAS  Google Scholar 

  26. Haque S, Chowdhury A, Rana A et al (2015) Synthesis of microcrystalline cellulose from pretreated cotton obtained from Bombax ceiba L. and its characterization. Bangladesh J Sci Ind Res 50:199–204. https://doi.org/10.3329/bjsir.v50i3.25586

    Article  CAS  Google Scholar 

  27. Aldosari OF, Jabli M, Morad MH (2023) Chemical extraction of cellulose from Ligno-cellulosic Astragalus armatus pods: Characterization, and application to the biosorption of methylene blue. Arab J Chem. https://doi.org/10.1016/j.arabjc.2023.105019

    Article  Google Scholar 

  28. Ventura-Cruz S, Flores-Alamo N, Tecante A (2020) Preparation of microcrystalline cellulose from residual Rose stems (Rosa spp.) by successive delignification with alkaline hydrogen peroxide. Int J Biol Macromol 155:324–329. https://doi.org/10.1016/j.ijbiomac.2020.03.222

    Article  CAS  PubMed  Google Scholar 

  29. Somasundaram R, Rajamoni R, Suyambulingam I et al (2022) Utilization of discarded Cymbopogon flexuosus root waste as a novel lignocellulosic fiber for lightweight polymer composite application. Polym Compos 43:1–16. https://doi.org/10.1002/pc.26580

    Article  CAS  Google Scholar 

  30. Sarala R (2020) Characterization of a new natural cellulosic fiber extracted from Derris scandens stem. Int J Biol Macromol 165:2303–2313. https://doi.org/10.1016/j.ijbiomac.2020.10.086

    Article  CAS  Google Scholar 

  31. Chandrasekaran NK, Arunachalam V (2021) State-of-the-art review on honeycomb sandwich composite structures with an emphasis on filler materials. Polym Compos 42:5011–5020. https://doi.org/10.1002/PC.26252

    Article  CAS  Google Scholar 

  32. Ahmadi M, Madadlou A, Sabouri AA (2015) Isolation of micro- and nano-crystalline cellulose particles and fabrication of crystalline particles-loaded whey protein cold-set gel. Food Chem 174:97–103. https://doi.org/10.1016/j.foodchem.2014.11.038

    Article  CAS  PubMed  Google Scholar 

  33. Alle M, Bandi R, Lee SH, Kim JC (2020) Recent trends in isolation of cellulose nanocrystals and nanofibrils from various forest wood and nonwood products and their application. Nanomater Agric For Appl. Elsevier, pp 41–80

  34. Gabriel T, Belete A, Syrowatka F et al (2020) Extraction and characterization of celluloses from various plant byproducts. Int J Biol Macromol 158:1248–1258. https://doi.org/10.1016/j.ijbiomac.2020.04.264

    Article  CAS  Google Scholar 

  35. Haldar D, Purkait MK (2020) Micro and nanocrystalline cellulose derivatives of lignocellulosic biomass: A review on synthesis, applications and advancements. Carbohydr Polym 250:116937. https://doi.org/10.1016/j.carbpol.2020.116937

    Article  CAS  PubMed  Google Scholar 

  36. Hafid HS, Omar FN, Zhu J, Wakisaka M (2021) Enhanced crystallinity and thermal properties of cellulose from rice husk using acid hydrolysis treatment. Carbohydr Polym. https://doi.org/10.1016/j.carbpol.2021.117789

    Article  PubMed  Google Scholar 

  37. Harini K, Ramya K, Sukumar M (2018) Extraction of nano cellulose fibers from the banana peel and bract for production of acetyl and lauroyl cellulose. Carbohydr Polym 201:329–339. https://doi.org/10.1016/j.carbpol.2018.08.081

    Article  CAS  PubMed  Google Scholar 

  38. Harini K, Chandra Mohan C (2020) Isolation and characterization of micro and nanocrystalline cellulose fibers from the walnut shell, corncob and sugarcane bagasse. Int J Biol Macromol 163:1375–1383. https://doi.org/10.1016/j.ijbiomac.2020.07.239

    Article  CAS  PubMed  Google Scholar 

  39. Kian LK, Saba N, Jawaid M, Fouad H (2020) Characterization of microcrystalline cellulose extracted from olive fiber. Int J Biol Macromol 156:347–353. https://doi.org/10.1016/j.ijbiomac.2020.04.015

    Article  CAS  PubMed  Google Scholar 

  40. Shanmugarajah B, Chew IML, Mubarak NM et al (2019) Valorization of palm oil agro-waste into cellulose biosorbents for highly effective textile effluent remediation. J Clean Prod 210:697–709. https://doi.org/10.1016/j.jclepro.2018.10.342

    Article  CAS  Google Scholar 

  41. Rahman MS, Mondal MIH, Yeasmin MS et al (2020) Conversion of lignocellulosic corn agro-waste into cellulose derivative and its potential application as pharmaceutical excipient. Processes. https://doi.org/10.3390/PR8060711

    Article  Google Scholar 

  42. Ganguly P, Sengupta S, Das P, Bhowal A (2020) Valorization of food waste: Extraction of cellulose, lignin and their application in energy use and water treatment. Fuel 280:118581. https://doi.org/10.1016/j.fuel.2020.118581

    Article  CAS  Google Scholar 

  43. Thomas SK, Parameswaranpillai J, Krishnasamy S et al (2021) A comprehensive review on cellulose, chitin, and starch as fillers in natural rubber biocomposites. Carbohydr Polym Technol Appl 2:100095. https://doi.org/10.1016/j.carpta.2021.100095

    Article  CAS  Google Scholar 

  44. Van NTT, Gaspillo PA, Thanh HG et al (2022) Cellulose from the banana stem: optimization of extraction by response surface methodology (RSM) and charaterization. Heliyon. https://doi.org/10.1016/j.heliyon.2022.e11845

    Article  PubMed  PubMed Central  Google Scholar 

  45. Fouad H, Kian LK, Jawaid M et al (2020) Characterization of microcrystalline cellulose isolated from conocarpus fiber. Polymers (Basel) 12:1–11. https://doi.org/10.3390/polym12122926

    Article  CAS  Google Scholar 

  46. Kalpana VP, Perarasu VT (2020) Analysis on cellulose extraction from hybrid biomass for improved crystallinity. J Mol Struct 1217:128350. https://doi.org/10.1016/j.molstruc.2020.128350

    Article  CAS  Google Scholar 

  47. Sainorudin MH, Mohammad M, Kadir NHA et al (2018) Characterization of several microcrystalline cellulose (Mcc)-based agricultural wastes via x-ray diffraction method. Solid State Phenomena 280(SSP):340–345. https://doi.org/10.4028/www.scientific.net/SSP.280.340

  48. Suyambulingam I, Divakaran D, Siengchin S (2023) Comprehensive characterization of novel Borassus flabellifer flower biomass based microcrystalline cellulose reinforced with polylactic acid (PLA) biofilm for futuristic applications. Biomass Convers Biorefin. https://doi.org/10.1007/s13399-023-04030-1

    Article  Google Scholar 

  49. Divakaran D, Suyambulingam I, Sanjay MR et al (2024) International Journal of Biological Macromolecules Isolation and characterization of microcrystalline cellulose from an agro-waste tamarind ( Tamarindus indica ) seeds and its suitability investigation for biofilm formulation. Int J Biol Macromol 254:127687. https://doi.org/10.1016/j.ijbiomac.2023.127687

    Article  CAS  PubMed  Google Scholar 

  50. Rantheesh J, Indran S, Raja S et al (2023) Isolation and characterization of novel micro cellulose from Azadirachta indica A. Juss agro-industrial residual waste oil cake for futuristic applications. Biomass Conv Bioref 13:4393–4411. https://doi.org/10.1007/s13399-022-03467-0

    Article  CAS  Google Scholar 

  51. Baruah J, Deka RC, Kalita E (2020) Greener production of microcrystalline cellulose (MCC) from Saccharum spontaneum (Kans grass): Statistical optimization. Int J Biol Macromol 154:672–682. https://doi.org/10.1016/j.ijbiomac.2020.03.158

    Article  CAS  PubMed  Google Scholar 

  52. Nabili A, Fattoum A, Passas R, Elaloui E (2016) Extraction and characterization of cellulose from date palm seeds (Phoenix dactylifera L.). Cellul Chem Technol 50:1015–1023

    CAS  Google Scholar 

  53. Xiao W, Niu B, Yu M et al (2021) Fabrication of foam-like oil sorbent from polylactic acid and Calotropis gigantea fiber for effective oil absorption. J Clean Prod 278:123507. https://doi.org/10.1016/j.jclepro.2020.123507

    Article  CAS  Google Scholar 

  54. Athirah Abdullah N, Hanif Sainorudin M, Asim N et al (2020) Extraction of microcrystalline cellulose from two different agriculture waste via chemical treatment. IOP Conf Ser Mater Sci Eng. https://doi.org/10.1088/1757-899X/739/1/012017

    Article  Google Scholar 

  55. Sivamurugan P, Selvam R, Pandian M et al (2022) Extraction of novel biosilica from finger millet husk and its coconut rachilla-reinforced epoxy biocomposite: mechanical, thermal, and hydrophobic behaviour. Biomass Convers Biorefin. https://doi.org/10.1007/s13399-022-03342-y

    Article  Google Scholar 

  56. Sumesh KR, Kavimani V, Rajeshkumar G et al (2022) Mechanical, water absorption and wear characteristics of novel polymeric composites: Impact of hybrid natural fibers and oil cake filler addition. J Ind Text 51:5910S-5937S

    Article  CAS  Google Scholar 

  57. Igathinathane C, Pordesimo LO, Columbus EP et al (2009) Sieveless particle size distribution analysis of particulate materials through computer vision. Comput Electron Agric 66:147–158. https://doi.org/10.1016/j.compag.2009.01.005

    Article  Google Scholar 

  58. Collazo-Bigliardi S, Ortega-Toro R, Chiralt Boix A (2018) Isolation and characterisation of microcrystalline cellulose and cellulose nanocrystals from coffee husk and comparative study with rice husk. Carbohydr Polym 191:205–215. https://doi.org/10.1016/j.carbpol.2018.03.022

    Article  CAS  PubMed  Google Scholar 

  59. Queirós CSGP, Cardoso S, Lourenço A et al (2020) Characterization of walnut, almond, and pine nut shells regarding chemical composition and extract composition. Biomass Convers Biorefin 10:175–188. https://doi.org/10.1007/s13399-019-00424-2

    Article  CAS  Google Scholar 

  60. Senthil Muthu Kumar T, Rajini N, Obi Reddy K et al (2018) All-cellulose composite films with cellulose matrix and Napier grass cellulose fibril fillers. Int J Biol Macromol 112:1310–1315. https://doi.org/10.1016/j.ijbiomac.2018.01.167

    Article  CAS  PubMed  Google Scholar 

  61. Reddy KO, Uma Maheswari C, Muzenda E et al (2016) Extraction and characterization of cellulose from pretreated ficus (peepal tree) leaf fibers. J Nat Fibers 13:54–64. https://doi.org/10.1080/15440478.2014.984055

    Article  CAS  Google Scholar 

  62. de Moreira BR, A, Cruz VH, Barbosa Júnior MR, et al (2022) Agro-residual biomass and disposable protective face mask: a merger for converting waste to plastic-fiber fuel via an integrative carbonization-pelletization framework. Biomass Convers Biorefin. https://doi.org/10.1007/s13399-022-03285-4

    Article  PubMed  PubMed Central  Google Scholar 

  63. Narayanasamy P, Balasundar P, Senthil S et al (2020) Characterization of a novel natural cellulosic fiber from Calotropis gigantea fruit bunch for ecofriendly polymer composites. Int J Biol Macromol 150:793–801. https://doi.org/10.1016/j.ijbiomac.2020.02.134

    Article  CAS  PubMed  Google Scholar 

  64. Moreno G, Ramirez K, Esquivel M, Jimenez G (2019) Biocomposite films of polylactic acid reinforced with microcrystalline cellulose from pineapple leaf fibers. J Renew Mater 7:9–20. https://doi.org/10.32604/jrm.2019.00017

    Article  CAS  Google Scholar 

  65. Katakojwala R, Mohan SV (2020) Microcrystalline cellulose production from sugarcane bagasse: Sustainable process development and life cycle assessment. J Clean Prod 249:119342. https://doi.org/10.1016/j.jclepro.2019.119342

    Article  CAS  Google Scholar 

  66. Ilyas RA, Sapuan SM, Ibrahim R et al (2019) Effect of sugar palm nanofibrillated cellulose concentrations on morphological, mechanical and physical properties of biodegradable films based on agro-waste sugar palm (Arenga pinnata (Wurmb.) Merr) starch. J Market Res 8:4819–4830. https://doi.org/10.1016/j.jmrt.2019.08.028

    Article  CAS  Google Scholar 

  67. Bhandari K, Roy P, Bhattacharyya AR, Maulik SR (2020) Synthesis and characterization of microcrystalline cellulose from jute stick. Indian J Fibre Text Res 45:464–469. https://doi.org/10.56042/ijftr.v45i4.30460

    Article  CAS  Google Scholar 

  68. Siddhanta AK, Prasad K, Meena R et al (2009) Profiling of cellulose content in Indian seaweed species. Bioresour Technol 100:6669–6673. https://doi.org/10.1016/j.biortech.2009.07.047

    Article  CAS  PubMed  Google Scholar 

  69. Sun X, Lu C, Liu Y et al (2014) Melt-processed poly (vinyl alcohol) composites filled with microcrystalline cellulose from waste cotton fabrics. Carbohydr Polym 101:642–649

    Article  CAS  PubMed  Google Scholar 

  70. Pinheiro Bruni G, de Oliveira JP, Gómez-Mascaraque LG et al (2020) Electrospun β-carotene–loaded SPI:PVA fiber mats produced by emulsion-electrospinning as bioactive coatings for food packaging. Food Packag Shelf Life 23:100426. https://doi.org/10.1016/j.fpsl.2019.100426

    Article  Google Scholar 

  71. Rajashekar V, Rao EU, Srinivas P (2012) Biological activities and medicinal properties of Gokhru (Pedalium murex L.). Asian Pac J Trop Biomed 2:581–585. https://doi.org/10.1016/S2221-1691(12)60101-4

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  72. Cao Y, Zandi Y, Rahimi A et al (2021) A new intelligence fuzzy-based hybrid metaheuristic algorithm for analyzing the application of tea waste in concrete as natural fiber. Comput Electron Agric. https://doi.org/10.1016/j.compag.2021.106420

    Article  Google Scholar 

  73. Adel AM, Abd El-Wahab ZH, Ibrahim AA, Al-Shemy MT (2011) Characterization of microcrystalline cellulose prepared from lignocellulosic materials. Part II: Physicochemical properties Carbohydr Polym 83:676–687. https://doi.org/10.1016/j.carbpol.2010.08.039

    Article  CAS  Google Scholar 

  74. Beroual M, Boumaza L, Mehelli O et al (2021) Physicochemical properties and thermal stability of microcrystalline cellulose isolated from esparto grass using different delignification approaches. J Polym Environ 29:130–142. https://doi.org/10.1007/s10924-020-01858-w

    Article  CAS  Google Scholar 

  75. Thilagashanthi T, Gunasekaran K, Satyanarayanan KS (2021) Microstructural pore analysis using SEM and ImageJ on the absorption of treated coconut shell aggregate. J Clean Prod 324:129217. https://doi.org/10.1016/j.jclepro.2021.129217

    Article  CAS  Google Scholar 

  76. Sarmin SN, Jawaid M, Mahmoud MH et al (2022) Mechanical and physical properties analysis of olive biomass and bamboo reinforced epoxy-based hybrid composites. Biomass Convers Biorefin. https://doi.org/10.1007/s13399-022-02872-9

    Article  Google Scholar 

  77. Kalita RD, Nath Y, Ochubiojo ME, Buragohain AK (2013) Extraction and characterization of microcrystalline cellulose from fodder grass; Setaria glauca (L) P. Beauv, and its potential as a drug delivery vehicle for isoniazid, a first line antituberculosis drug. Colloids Surf B Biointerfaces 108:85–89

    Article  CAS  PubMed  Google Scholar 

  78. Baruah J, Bardhan P, Mukherjee AK et al (2022) Integrated pretreatment of banana agrowastes: Structural characterization and enhancement of enzymatic hydrolysis of cellulose obtained from banana peduncle. Int J Biol Macromol 201:298–307. https://doi.org/10.1016/j.ijbiomac.2021.12.179

    Article  CAS  PubMed  Google Scholar 

  79. Hamdan MA, Ramli NA, Othman NA et al (2019) Characterization and property investigation of microcrystalline cellulose (MCC) and carboxymethyl cellulose (CMC) filler on the carrageenan-based biocomposite film. Mater Today Proc 42:56–62. https://doi.org/10.1016/j.matpr.2020.09.304

    Article  CAS  Google Scholar 

  80. Thiangtham S, Runt J, Saito N, Manuspiya H (2020) Fabrication of biocomposite membrane with microcrystalline cellulose (MCC) extracted from sugarcane bagasse by phase inversion method. Cellulose 27:1367–1384. https://doi.org/10.1007/s10570-019-02866-3

    Article  CAS  Google Scholar 

  81. Nagarajan KJ, Balaji AN, Basha KS et al (2020) Effect of agro waste α-cellulosic micro filler on mechanical and thermal behavior of epoxy composites. Int J Biol Macromol 152:327–339. https://doi.org/10.1016/j.ijbiomac.2020.02.255

    Article  CAS  PubMed  Google Scholar 

  82. Tarchoun AF, Trache D, Klapötke TM et al (2019) Ecofriendly isolation and characterization of microcrystalline cellulose from giant reed using various acidic media. Cellulose 26:7635–7651. https://doi.org/10.1007/s10570-019-02672-x

    Article  CAS  Google Scholar 

  83. Joe MS, Sudherson DPS, Suyambulingam I et al (2023) Extraction and characterization of novel biomass–based cellulosic plant fiber from Ficus benjamina L. stem for a potential polymeric composite reinforcement. Biomass Conv Bioref 13:14225–14239. https://doi.org/10.1007/s13399-023-03759-z

    Article  CAS  Google Scholar 

  84. Sunesh NP, Indran S, Divya D, Suchart S (2022) Isolation and characterization of novel agrowaste-based cellulosic micro fillers from Borassus flabellifer flower for polymer composite reinforcement. Polym Compos 43:6476–6488

    Article  CAS  Google Scholar 

  85. Porzio L, Arena C, Lorenti M et al (2020) Long-term response of Dictyota dichotoma var, intricata (C, Agardh) Greville (Phaeophyceae) to ocean acidification: Insights from high pCO2 vents. Sci Total Environ 731:138896. https://doi.org/10.1016/j.scitotenv.2020.138896

    Article  CAS  PubMed  Google Scholar 

  86. Divakaran D, Suyambulingam I, Sanjay MR et al (2024) Isolation and characterization of microcrystalline cellulose from an agro-waste tamarind (Tamarindus indica) seeds and its suitability investigation for biofilm formulation. Int J Biol Macromol 254:127687. https://doi.org/10.1016/j.ijbiomac.2023.127687

    Article  CAS  PubMed  Google Scholar 

  87. Asem M, Nawawi WMFW, Jimat DN (2018) Evaluation of water absorption of polyvinyl alcohol-starch biocomposite reinforced with sugarcane bagasse nanofibre: Optimization using Two-Level Factorial Design. IOP Conf Ser Mater Sci Eng. https://doi.org/10.1088/1757-899X/368/1/012005

    Article  Google Scholar 

  88. Zhao T, Chen Z, Lin X et al (2018) Preparation and characterization of microcrystalline cellulose (MCC) from tea waste. Carbohydr Polym 184:164–170. https://doi.org/10.1016/j.carbpol.2017.12.024

    Article  CAS  PubMed  Google Scholar 

  89. Dastjerdi S, Naeijian F, Akgöz B, Civalek Ö (2021) On the mechanical analysis of microcrystalline cellulose sheets. Int J Eng Sci 166:103500. https://doi.org/10.1016/j.ijengsci.2021.103500

    Article  Google Scholar 

  90. Atabaki F, Bastam NN, Hafizi-Atabak HR et al (2020) Synthesis and characterization of new energetic plasticizers: Benzoyl-terminated poly(epichlorohydrin) modified by phenylhydrazine and its derivatives. Cent Eur J Energ Mater 17:323–343. https://doi.org/10.22211/cejem/127514

    Article  CAS  Google Scholar 

  91. Ibáñez-García A, Martínez-García A, Ferrándiz-Bou S (2021) Influence of almond shell content and particle size on mechanical properties of starch-based biocomposites. Waste Biomass Valorization 12:5823–5836. https://doi.org/10.1007/s12649-020-01330-9

    Article  CAS  Google Scholar 

  92. Sanjeewa KKA, Kang N, Ahn G et al (2018) Bioactive potentials of sulfated polysaccharides isolated from brown seaweed Sargassum spp in related to human health applications: A review. Food Hydrocoll 81:200–208. https://doi.org/10.1016/j.foodhyd.2018.02.040

    Article  CAS  Google Scholar 

  93. Renugadevi K, Devan PK, Thomas T (2019) Fabrication of Calotropis Gigantea fibre reinforced compression spring for light weight applications. Compos B Eng 172:281–289. https://doi.org/10.1016/j.compositesb.2019.05.037

    Article  CAS  Google Scholar 

  94. Chen B, Li L, Hu Y et al (2022) Fluorescence turn-on immunoassay of endocrine diethyl phthalate in daily supplies using red fluorescent carbon dots. Microchem J 178:107350. https://doi.org/10.1016/j.microc.2022.107350

    Article  CAS  Google Scholar 

  95. Pracella M, Haque MMU, Puglia D (2014) Morphology and properties tuning of PLA/cellulose nanocrystals bio-nanocomposites by means of reactive functionalization and blending with PVAc. Polymer (Guildf) 55:3720–3728. https://doi.org/10.1016/j.polymer.2014.06.071

    Article  CAS  Google Scholar 

  96. Sturm DJ, Bachner J, Renninger D et al (2021) Corrigendum to “A cluster randomized trial to evaluate need-supportive teaching in physical education on physical activity of sixth-grade girls: A mixed method study” [Psychology of Sport & Exercise 54 (2021) 101902] (Psychology of Sport & Exercise (2021). Psychol Sport Exerc 57:102035. https://doi.org/10.1016/j.psychsport.2021.102035

    Article  Google Scholar 

  97. Xiao X, Lu S, Qi B et al (2014) Enhancing the thermal and mechanical properties of epoxy resins by addition of a hyperbranched aromatic polyamide grown on microcrystalline cellulose fibers. RSC Adv 4:14928–14935

    Article  CAS  Google Scholar 

  98. Trivedi N, Gupta V, Kumar M et al (2011) An alkali-halotolerant cellulase from Bacillus flexus isolated from green seaweed Ulva lactuca. Carbohydr Polym 83:891–897. https://doi.org/10.1016/j.carbpol.2010.08.069

    Article  CAS  Google Scholar 

  99. Lu JH, Chen C, Huang C, Lee DJ (2020) Glucose fermentation with biochar-amended consortium: microbial consortium shift. Bioengineered 11:272–280. https://doi.org/10.1080/21655979.2020.1735668

    Article  CAS  PubMed  PubMed Central  Google Scholar 

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Acknowledgements

The authors extend their appreciation to the Deanship of Scientific Research at Imam Mohammad Ibn Saud Islamic University (IMSIU), Saudi Arabia, for supporting and funding this research work through Grand No. IMSIU-RG23050.

Funding

The authors extend their appreciation to the Deanship of Scientific Research at Imam Mohammad Ibn Saud Islamic University (IMSIU), Saudi Arabia, for supporting and funding this research work through Grand No. IMSIU-RG23050.

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Murugesan Palaniappan and Srinivas Tadepalli: Conducted all the experimental works and written original manuscript. All other Authors: Supported for data analysis and review the final draft.

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Palaniappan, M., Palanisamy, S., Khan, R. et al. Synthesis and suitability characterization of microcrystalline cellulose from Citrus x sinensis sweet orange peel fruit waste-based biomass for polymer composite applications. J Polym Res 31, 105 (2024). https://doi.org/10.1007/s10965-024-03946-0

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