Skip to main content

Advertisement

Log in

Improvement of mechanical toughness of polypropylene by laminating with elastomer

  • ORIGINAL PAPER
  • Published:
Journal of Polymer Research Aims and scope Submit manuscript

Abstract

We used three-point bending tests to investigate the effects of elastomer lamination on the failure mode of bar-shaped products using isotactic polypropylene (PP). When a thermoplastic elastomer sheet was laminated on PP, which was prepared by double-shot injection molding, the specimen showed high mechanical toughness without signs of stress whitening. Although rubbery materials have low tensile moduli, their bulk moduli are comparable to those of plastics. Therefore, the laminated elastomer, located inside of the bending deformation, prohibits sharp bending angles during the deformation. Consequently, craze formation, which is the origin of stress whitening and leads to brittle fracture, hardly occurs.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. Isayev A, Hung KM (2009) Co-injection molding of polymers, in injection molding, Eds. Kamal, M.; Isayev, A.; Liu, S. Chap. 21. Hanser, Munich

    Google Scholar 

  2. Kazmer RO (2016) Injection mold design engineering2nd edn. Hanser, Munich

    Book  Google Scholar 

  3. Geminger T, Jarka S (2016) Injection molding of multimaterial systems. In: Heim HP (ed) Specialized injection molding techniques, Chap. 4. Elsevier, Amsterdam

    Google Scholar 

  4. Arayachukiat S, Doan VA, Murakami T, Nobukawa S, Yamaguchi M (2015). J Appl Polym Sci 132:42008

    Article  Google Scholar 

  5. Sako T, Nobukawa S, Yamaguchi M (2015) Surface localization of poly(methyl methacrylate) in a miscible blend with polycarbonate. Polym J 47:576–579

    Article  CAS  Google Scholar 

  6. Sako T, Ito A, Yamaguchi M (2017) Surface segregation during injection molding of polycarbonate/poly(methyl methacrylate) blend. J Polym Res 24:89

    Article  Google Scholar 

  7. Yamaguchi M, Irie Y, Phulkerd P, Hagihara H, Hirayama S, Sasaki S (2010) Plywood-like structure of injection-moulded polypropylene. Polymer 51:5983–5989

    Article  CAS  Google Scholar 

  8. Phulkerd P, Hirayama S, Nobukawa S, Inoue T, Yamaguchi M (2014) Structure and mechanical anisotropy of injection-molded polypropylene with a plywood structure. Polym J 46:226–233

    Article  CAS  Google Scholar 

  9. Mills NJ, Zhang PS (1989) The effects of contact conditions on impact tests on plastics. J Mater Sci 24:2099–2109

    Article  CAS  Google Scholar 

  10. Xie M, Zhang Y, Krasny MJ, Rhead A, Bowen C, Arafa M (2018) Energy harvesting from coupled bending-twisting oscillations in carbon-fibre reinforced polymer laminates. Mech. Sys. Sign. Proc 107:429–438

    Article  Google Scholar 

  11. Fedorko G, Molnar V, Honus S, Belusko M, Tomaskova M (2018) Influence of selected characteristics on failures of the conveyor belt cover layer material. Eng. Failure Anal 94:145–156

    Article  Google Scholar 

  12. Han J, Lv J, Zhan X, Huang R, Xu X (2016). Bioresources 11:6677–6691

    CAS  Google Scholar 

  13. Staab GH (2016) Laminar Composites 2nd edn. Elsevier, Amsterdam

    Chapter  Google Scholar 

  14. Kausch H, Polymer H (1986) Fracture 2nd edn. Berlin, Springer-Verlag

  15. Narisawa I, Kuriyama T, Ojima K (1991) Crazing and shear deformation of polymer alloys. Macromol Symp 41:87–107

    Article  CAS  Google Scholar 

  16. Lazzeri A, Bucknall CB (2000) Recent developments in the modeling of dilatational yielding in toughened plastics, in toughening of plastics, Eds., Pearson, R. A.; Sue, H. J.; Yee, A. F. Chap. 2. American Chemical Society, Washington DC

    Google Scholar 

  17. Argon AS (2013) The physics of deformation and fracture of polymers. Chap.12. Cambridge Univ. Press, Cambridge

    Book  Google Scholar 

  18. Kinloch AJ, Young GJ (2013) Fracture behavior of polymers. Springer, Berlin

    Google Scholar 

  19. Tenma M, Yamaguchi M (2007) Structure and properties of injection-molded polypropylene with sorbitol-based clarifier. Polym Eng Sci 47:1441–1446

    Article  CAS  Google Scholar 

  20. Felekoglu B (2014). Civ Eng 58:279–291

    Google Scholar 

  21. Folkes MJ, Hardwick ST (1990) The mechanical properties of glass/polypropylene multilayer laminates. J Mater Sci 25:2598–2606

    Article  CAS  Google Scholar 

  22. Bucknall CB, Smith RR (1965) Stress-whitening in high-impact polystyrenes. Polymer 6:437–446

    Article  CAS  Google Scholar 

  23. Brown N, Ward IM (1983) The influence of morphology and molecular weight on ductile-brittle transitions in linear polyethylene. J Mater Sci 18:1405–1420

    Article  CAS  Google Scholar 

  24. Chiu HT, Shiau YG, Chiu WM, Syau SS (1995) Toughening isotactic polypropylene and propylene-ethylene block copolymer with styrene-ethylene butylene-styrene triblock copolymer. J Polym Res 2:21–29

    Article  CAS  Google Scholar 

  25. Liu Y, Kennard CHL, Truss RW, Calos NJ (1997) Characterization of stress-whitening of tensile yielded isotactic polypropylene. Polymer 38:2797–2805

    Article  CAS  Google Scholar 

  26. Yamaguchi M, Nitta K (1999) Optical and acoustical investigation for plastic deformation of isotactic polypropylene/ethylene-1-hexene copolymer blends. Polym Eng Sci 39:833–840

    Article  CAS  Google Scholar 

  27. Hegde RR, Bhat GS, Spruiell JE, Benson R (2013) Structure and properties of polypropylene-nanoclay composites. J Polym Res 20:323–335

    Article  Google Scholar 

  28. van Krevelen DW, Te Nijenhuis K (2009) Properties of Polymers4th edn. Elsevier, Amsterdam

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Masayuki Yamaguchi.

Additional information

Publisher’s note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Hachisuka, R., Kobayashi, T. & Yamaguchi, M. Improvement of mechanical toughness of polypropylene by laminating with elastomer. J Polym Res 26, 246 (2019). https://doi.org/10.1007/s10965-019-1910-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10965-019-1910-6

Keywords

Navigation