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Preparation of metal-polymer nanocomposites by chemical reduction of metal ions: functions of polymer matrices

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Abstract

This review summarizes the latest advances in the preparation of metal-polymer nanocomposites by chemical reduction of metal ions in polymer matrices that are classified according to their functions as stabilizing agents, templates and reducing agents. Particular attention is paid to various factors affecting the size and morphology of particles, the composition and structure of metal-polymer nanocomposites. Problems and prospects of development of metal-polymer nanocomposites obtained by chemical reduction of metal ions are considered.

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Abbreviations

AA :

acrylic acid

AM :

acrylamide

AFM :

atomic force microscopy

APS :

ammonium persulfate

-b-:

-block-

BCP :

block copolymer

COF :

covalent organic framework

COL :

conjugated oligomer

CP :

conjugated polymer

CTAB :

cetyltrimethylammonium bromide

DB :

degree of branching

DEN :

dendrimer-encapsulated nanoparticle

DLS :

dynamic light scattering

DMF:

dimethyl formamide

DP :

degree of polymerization

DVB :

divinylbenzeve

ETMA :

2,3-epithiopropyl methacrylate

EDX :

energy-dispersive X-ray spectroscopy

FESEM :

field-emission scanning electron micrograph

-g-:

-grafted-

G :

dendrimer generation

GD :

glycerodendrimer

GMA :

glycidyl methacrylate

HAADF-STEM :

high-angle annular dark-field scanning transmission electron microscopy

HBPG :

hyperbranched polyglycidol

HIPE :

high internal phase emulsion

HRTEM :

high-resolution transmission electron microscopy

LSPR :

localized surface plasmon resonance

MAA :

methacrylic acid

MMA :

methyl methacrylate

MPN :

metal-polymer nanocomposite

MR :

molar ratio

NC :

nanocluster

NIPAM :

N-isopropylacrylamide

NP :

nanoparticle

NR :

nanorod

NS :

nanosphere

PAA :

poly(acrylic acid)

PAAm :

polyacrylamide

РAМAМ :

polyamidoamine

PANI :

polyaniline

PCL :

poly(ε-caprolactone)

PCMS :

poly(p-chloromethylstyrene)

PDA :

polydopamine

PEG :

polyethylene glycol

PEGMA :

poly(ethylene glycol) methyl ether methacrylate

PEI :

poly(ethylene imine)

PEO :

poly(ethylene oxide)

PGMA :

poly(glycidyl methacrylate)

PIL :

poly(ionic liquid)

PMAA :

poly(methacrylic acid)

PMMA :

poly(methyl methacrylate)

PNIPAM :

poly(N-isopropylacrylamide)

PP :

polypropylene

PPI :

polypropyleneimine

PPO :

poly(propylene oxide)

PPy :

polypyrrole

PS :

polystyrene

PSS :

poly(styrene sulfonate)

PT :

polythiophene

PVA :

polyvinyl alcohol

PVC:

polyvinyl chloride

P2VP:

poly-2-vinylpyridine

P4VP :

poly-4-vinylpyridine

PVP :

polyvinylpyrrolidone

RAFT :

reversible addition fragmentation chain transfer

SAED :

selected area electron diffraction

SAM :

self-assembled monolayer

SAXS :

small-angle X-ray scattering

SDS :

sodium dodecyl sulfate

SEM :

scanning electron microscope

SERS :

surface-enhanced Raman scattering

St :

styrene

TEM :

transmission electron microscopy

TETA :

triethylenetetramine

THF :

tetrahydrofuran

TTC :

trithiocarbonate

4-VP :

4-vinylpyridine

XANES :

X-ray absorption near edge structure

XPS :

X-ray photoelectron spectroscopy

XRD :

X-ray diffraction

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Authors and Affiliations

  1. Laboratory of Metallopolymers, The Institute of Problems of Chemical Physics RAS, Chernogolovka, Moscow Region, Russian Federation

    Gulzhian I. Dzhardimalieva

  2. Department of Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation

    Igor E. Uflyand

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  1. Gulzhian I. Dzhardimalieva
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Correspondence to Igor E. Uflyand.

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Dzhardimalieva, G.I., Uflyand, I.E. Preparation of metal-polymer nanocomposites by chemical reduction of metal ions: functions of polymer matrices. J Polym Res 25, 255 (2018). https://doi.org/10.1007/s10965-018-1646-8

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