Journal of Polymer Research

, 20:258 | Cite as

Specific features of creep and tribological behavior of polyimide-carbon nanotubes nanocomposite films: effect of the nanotubes functionalization

  • Iosif Gofman
  • Baode Zhang
  • Wanchen Zang
  • Yu Zhang
  • Guangliang Song
  • Chunhai Chen
  • Yao Li
Original Paper


The nanocomposite films were synthesized based on the thermally stable benzoxazole-containing aromatic polyimide. The multi-walled carbon nanotubes in the concentrations from 0.25 to 1.0 wt.% were introduced in the matrix polymer as a nanofiller. Two types of nanotubes were used: the pristine nanotubes and those containing COOH-groups attached to the nanotubes’ surface. The impacts of the nanoparticles on the mechanical properties of the films in both single extension and creep conditions, and on the tribological properties of the material in the polymer/steel friction couple were tested. The positive actions of the COOH-containing nanotubes on both the mechanical properties and the tribological behavior of the studied materials were evidenced. These effects can be caused by the formation of the tightly packed nanocomposite structure in which the H-bonds are formed between CO- groups of the imide cycles of the polymer chains and COOH-groups of the nanotubes. The COOH-pretreatment hinders the aggregation processes of the nanotubes if their concentration in the composite films is less than ~1 wt. %.


Nanocomposites Carbon nanotubes Functionalization Creep Tribological behavior 



The financial support provided by Russian Foundation for Basic Research (project No. 13- 03–00547) is acknowledged.


  1. 1.
    Hussain F (2006) J Compos Mater 40:1511–1575CrossRefGoogle Scholar
  2. 2.
    Kasgöz H, Durmus A (2008) Polym Adv Technol 19:838–845CrossRefGoogle Scholar
  3. 3.
    Bessonov MI, Koton MM, Kudryavtsev VV, Laius LA (1987) Polyimides—thermally stable polymers. Plenum Publishing Corp, New YorkGoogle Scholar
  4. 4.
    Garboczi EJ, Snyder KA, Douglas JF, Thorpe MF (1995) Phys Rev E 52:819–828CrossRefGoogle Scholar
  5. 5.
    Iijima S (1991) Nature 354:56–58CrossRefGoogle Scholar
  6. 6.
    Fang C, Zhao J, Jia J, Zhang Z, Zhang X, Li Q (2010) Appl Phys Lett 97:181906CrossRefGoogle Scholar
  7. 7.
    Zhu BK, Xie S-H, Xu Z-K, Xu Y-Y (2006) Compos Sci Technol 66:548–554CrossRefGoogle Scholar
  8. 8.
    So H, Cho J, Sahoo N (2007) Eur Polym J 43:3750–3756CrossRefGoogle Scholar
  9. 9.
    Thuau D, Koutsos V, Cheung R (2009) J Vacuum Sci & Technol B: Microelectron and Nanometer Struct 27:3139–3144Google Scholar
  10. 10.
    Lebron-Colon M, Meador MA, Gaier JR, Sola F, Scheiman DA, McCorkle LS (2010) ACS Appl Mater Interfaces 2:669–676CrossRefGoogle Scholar
  11. 11.
    Zhang B, Bershtein VA, Sukhanova TE, Zang W, Li Y, Chen C, Egorova LM, Gofman IV, Gubanova GN, Volkov AY, Vylegzhanina ME, Yakushev PN (2012) J Macromol Sci Phys 51:1794–1814CrossRefGoogle Scholar
  12. 12.
    Kim SW, Kim T, Kim YS, Choi HS, Lim HJ, Yang SJ, Park CR (2012) Carbon 50:3–33CrossRefGoogle Scholar
  13. 13.
    Assali M, Leal MP, Fernández I, Romero-Gomez P, Baati R, Khiar N (2010) Nano Res 3:764–778CrossRefGoogle Scholar
  14. 14.
    Yang Z, Chen X, Chen C, Li W, Zhang H, Xu L, Yi B (2007) Polym Compos 28:36–41CrossRefGoogle Scholar
  15. 15.
    Hatui G, Das CK (2013) J Polym Res 20:77CrossRefGoogle Scholar
  16. 16.
    Gofman IV, Svetlichnyi VM, Yudin VE, Dobrodumov AV, Didenko AL, Abalov IV, Korytkova EN, Egorov AI, Gusarov VV (2007) Russ J Gen Chem 77:1158–1166CrossRefGoogle Scholar
  17. 17.
    Delozier DM, Orwoll RA, Cahoon JF, Johnston NJ, Smith JG Jr, Connell JW (2002) Polymer 43:813–822CrossRefGoogle Scholar
  18. 18.
    Gofman IV, Abalov IV, Tiranov VG, Yudin VE (2013) Polym Sci A 55:313–319CrossRefGoogle Scholar
  19. 19.
    Myshkin NK, Kim CK, Petrokovets MI (1997) Introduction to tribology. CMG Publishers, SeoulGoogle Scholar
  20. 20.
    Hertz H (1882) Mathematik 92:156–171Google Scholar

Copyright information

© Springer Science+Business Media Dordrecht 2013

Authors and Affiliations

  1. 1.Institute of Macromolecular CompoundsRussian Academy of SciencesSt.-PetersburgRussia
  2. 2.Center for Composite MaterialsHarbin Institute of TechnologyHarbinPeople’s Republic of China
  3. 3.Alan G. MacDiarmid InstituteJilin UniversityChangchunPeople’s Republic of China

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