Dry–wet spinning of temperature-sensitive PVDF hollow-fiber membranes at different bore fluid flow rates

  • Xiang Shen
  • Yiping Zhao
  • Qiang Zhang
  • Li Chen
Original Paper


In this work, dry–wet spinning was conducted to fabricate poly(vinylidene fluoride)-g-poly(N-isopropylacrylamide) (PVDF-g-PNIPAAm) copolymer hollow-fiber membranes. The effect of the bore fluid flow rate (BFFR) on the structure and performance of each hollow-fiber membrane was investigated by X-ray photoelectron spectroscopy (XPS), field emission scan electronic microscopy (FESEM), pore-size measurements, mechanical property evaluations, and a filtration experiment. It was found that the grafted PNIPAAm chains aggregated on the inner surface of the fiber membrane due to the effect of the bore fluid. When the permeation temperature was increased from 20 to 45 °C, a drastic reduction in the pure-water flux and a remarkable increase in the retention of bovine serum albumin (BSA) were observed at around 32 °C, indicating that the as-prepared fiber membranes exhibit excellent temperature sensitivity. Pore-size measurements confirmed that both the mean pore size and the porosity increase with increasing BFFR, endowing the fiber membranes with high pure-water fluxes and low retentions of BSA.


Poly(vinylidene fluoride) Poly(N-isopropylacrylamide) Hollow-fiber membrane Temperature-sensitive Bore fluid flow rate 



This work was financially supported by the National Natural Science Foundation of China (grant no. 21174103), the Project of Science and Technical Development of China (grant no. 2007AA03Z533), the Key Grant Project of the Chinese Ministry of Education (grant no. 209005), and the Science and Technical Development Foundation of Colleges and Universities, Tianjin, China (grant no. 20071214).


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Copyright information

© Springer Science+Business Media Dordrecht 2013

Authors and Affiliations

  1. 1.State Key Laboratory of Hollow Fiber Membrane Materials and Membrane Processes, School of Materials Science and EngineeringTianjin Polytechnic UniversityTianjinPeople’s Republic of China

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