Abstract
Polyurethane bicomponent coatings have been modified by formulation with different amount (2–6% by weight) of organophilic nanoclays according to a solution blending procedure. The clays (indicated as 72T and 30B) differ each other in the nature and polarity of the organic quaternary ammonium salt. After application and curing the coatings were characterized by X-rays diffraction (XRD), contact angle measurements, atomic force microscopy (AFM), dynamic-mechanical analysis, tensile tests. The presence of clay additives enhances both modulus and strength of coating materials, and shows some effect also on surface hydrophobicity. The more polar 30B clay seems to form more homogeneous and smoother surfaces, and also a higher coating toughness is retained. Solvent swelling measurements were carried out in toluene allowing the estimate of the extent of clay exfoliation in the material. These measurements along with XRD result suggest that only a partial delamination was achieved.
Similar content being viewed by others
References
Koo JH (2006) Polymer Nanocomposites: processing, characterization and applications. Mc Graw-Hill, New York
Alexandre M, Dubois P (2000) Mater Sci Eng Res 28:1
Ray SS, Okamoto M (2003) Progr Polym Sci 28:1539
Chozhan CK, Alagar M, Sharmila RJ, Gnanasundaram P (2007) J Polym Res 14:319
Sadhu S, Bhowmick AK (2004) J Polym Sci B Polym Phys 42:1573
Lopez-Manchado MA, Herrero B, Arroyo M (2003) Polym Int 52:1070
Baer DR, Burrows PE, El-Azab AA (2003) Progr Org Coat 47:342
Deffar D, Teng G, Soucek MD (2001) Macromol Mater Eng 286:204
Uyama H, Kuwabara M, Tsujimoto T, Nakano M, Usuki A, Kobayashi S (2004) Macromol Biosci 4:354
Jiratumnukul N, Pruthipaitoon S, Pitsaroup T (2006) J Appl Polym Sci 102:2639
Chen C, Khobaib M, Curliss D (2003) Progr Org Coat 47:376
Yeh JM, Huang HY, Chen CL, Su WF, Yu YH (2006) Surf Coat Technol 200:2753
Chen-Yang YE, Yang HC, Li GJ, Li YK (2004) J Polym Res 11:275
Uhl FM, Davuluri SP, Wong SC, Webster DC (2004) Polymer 45:6175
Fogelstrom L, Antoni P, Malstrom E, Hult A (2006) Progr Org Coat 55:284
Uhl F, Webster DC, Davuluri SP, Wong SC (2006) Eur Polym J 42:2596
Van Olphen H (1977) An introduction to clay colloid chemistry. Wiley, New York
Wu S (1971) J Polym Sci C34:19
Tennis HR, Hunter DL, Chang D, Kim S, White JL, Cho JW, Paul DR (2001) Polymer 42:9513
Chan CM (1994) Polymer surface modification and characterization. Hanser, Munich
Ma M, Hill RM (2006) Curr Opin Colloid Interf Sci 11:193
Extrand CW (1998) J Colloid Interf Sci 207:11
Bueche F (1965) In: Kraus G (ed) Reinforcement of elastomers. Interscience, New York, p 1
Crank J (1975) The mathematics of diffusion, 2nd edn. Clarendon, Oxford
Singh A, Mukherjee M (2005) Macromolecules 38:8795
Vogt BD, Soles CL, Lee HJ, Lin EK, Wu WI (2004) Langmuir 20:1453
Lan T, Kaviratna PD, Pinnavaia TJ (1994) Chem Mater 6:573
Lebaron PC, Wang Z, Pinnavaia TJ (1999) Appl Clay Sci 15:11
Maiti M, Bhowmick AK (2006) J Appl Polym Sci 8:2418
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Turri, S., Alborghetti, L. & Levi, M. Formulation and properties of a model two-component nanocomposite coating from organophilic nanoclays. J Polym Res 15, 365–372 (2008). https://doi.org/10.1007/s10965-008-9180-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10965-008-9180-8